Mordenite

(Na2,Ca,K2)4(Al8Si40)O96 · 28H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mor
Discovered
1864
Also known as
  • Arduinite
  • Ptilolite
  • Steelite

History

Mordenite takes its name from a place, not a Greek root. In 1864 the chemist Henry How described it and named it after Morden, a small community on the Bay of Fundy shore in Nova Scotia, Canada, where the first specimens were found.

That first find sat in volcanic rock. Mordenite belongs to the zeolites — a family of minerals built around an open, cage-like framework of silicon, aluminium and oxygen that traps water and loose ions inside its pores. It is one of the six most abundant zeolites, and it forms readily where water has worked on volcanic rock such as rhyolite, andesite and basalt.

Industrial & practical applications

Most of mordenite's industrial value comes not from the mineral dug out of the ground but from a synthetic version grown in a factory. Like all zeolites, it is full of tiny, uniform pores. That makes it act as a sorbent and a molecular sieve — a material that traps molecules small enough to fit its pores and turns away the rest.

The synthetic form earns its keep in oil refining. There it works as a catalyst — a substance that speeds a chemical reaction without being consumed — for the acid-catalyzed isomerisation of alkanes and aromatics, the reshuffling of hydrocarbon molecules into more useful shapes.

Natural mordenite is mined in bulk in a coarser form. It comes from zeolitic tuff, a soft rock made of compacted volcanic ash. Sedimentary deposits are quarried in quantity in Bulgaria, Hungary, Japan and the United States. The tuff is dried and crushed into a range of low-tech products: adsorbents that soak up oil and chemical spills and animal wastes, animal feed supplements, water treatment media, sports turf and slow-release fertilizer.
Japanese output of this raw material has been estimated at 150,000 tons a year.

The same sieving trick separates gases. Plants built on mordenite-rich tuffs pull high-grade oxygen from ordinary air using pressure-swing generators, which cycle pressure to load and unload the sieve. Full-scale plants of this kind have run in Japan since the end of the 1960s.

Where it forms, where it's found

Geological setting

Basalt.

Veins and amygdaloids in igneous rocks.

Type locality
Morden
  1. Kings Co.
  2. Nova Scotia
  3. Canada

45.1036°, -64.9497°

376recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · yellowish · pinkish
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (100); distinct on (010).

Fracture
Irregular/Uneven
Density
2.12 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 76 – 104° · 2V calc = 78 – 88°
Refractive index
1.472 – 1.487
Surface relief
Low
Principal indices
nα 1.472 – 1.483 · nβ 1.475 – 1.485 · nγ 1.477 – 1.487
Dispersion
none
Extinction
X = c; Y = a; Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.0045
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]45 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation45 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 18.16 Å · b = 20.45 Å · c = 7.54 Å
Ratio a:b:c
1 : 1.126 : 0.415
Z
4
Morphology

Prismatic crystals, acicular to fine fibrous, radiating groups, cottony aggregates, compact, porcelaneous.

Type-locality form

Rounded masses to about 5 cm, blotched with green celadonite. White, yellowish or pink, sometimes with a thin yellowish crust. With a very fine fibrous structure.

Comment

Point Group: mm2 or 2/m 2/m 2/m:; Space Group: Cmc21 or Cmcm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen12415.9991983.876
49.15%
14SiSiliconSilicon4028.0851123.400
27.83%
19KPotassiumPotassium839.098312.784
7.75%
13AlAluminiumAluminium826.982215.856
5.35%
11NaSodiumSodium822.990183.920
4.55%
20CaCalciumCalcium440.078160.312
3.97%
1HHydrogenHydrogen561.00856.448
1.40%
Total4036.596100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg

Synonyms

  • Arduinite
  • Ptilolite
  • Steelite

In other languages

German
Mordenit
Spanish
Mordenita
Italian
mordenite
Japanese
モルデナイト
Chinese
丝光沸石
Simplified Chinese
丝光沸石
Traditional Chinese
絲光沸石
Russian
Морденит

Classification

Strunz
10th ed.

9.GD.35

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GDChains of 6-membered rings – tabular zeolitesGroup
  • 9.GD.35MordeniteSpecies
Dana
8th ed.

77.01.06.01

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.06Mordenite and related speciesGroup
  • 77.01.06.01MordeniteSpecies
CIM

16.10.15

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.10Aluminosilicates of Ca and alkalisGroup
  • 16.10.15MordeniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Matýsek, D., Jirásek, J., Pour, O.: Mordenit z hornin těšínitové asociace v Podbeskydí (Morava, Česká republika). Acta Musei Moraviae, Scientiae Geologicae, 2024, 109(1), 71-82.
  2. 1864How, Henry (1864) XI.—On mordenite, a new mineral from the trap of Nova Scotia. Journal of the Chemical Society, 17. 100-104 doi:10.1039/js8641700100DOI: 10.1039/js8641700100
  3. 1886Cross, C.W., Eakins, L.G. (1886). On ptilolite, a new mineral [from Jefferson County, Colorado]. American Journal of Science, 3(188), 117-121. (as ptilolite)
  4. 1890Pirsson, L.V. (1890) On mordenite. American Journal of Science, 3rd Series: 40(237): 232-237.
  5. 1892Cross, W., Eakins, L.G. (1892). ART. XIII.--A new occurrence of Ptilolite. American Journal of Science, 44(260), 96.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mordenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mordenite-2779},
  note      = {Accessed 2026-05-11}
}