Natrochalcite

NaCu2(SO4)2(OH) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nch
Also known as
  • Natrochalciet

Where it forms, where it's found

Geological setting

Oxidation zone of a copper deposit in an arid environment.

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Bright green · green in transmitted light.
Streak
Greenish white
Cleavage
Perfect

On (001), perfect.

Density
3.47 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 36° · 2V calc = 38°
Refractive index
1.649 – 1.714
Surface relief
High
Principal indices
nα 1.649 · nβ 1.655 · nγ 1.714
Dispersion
r < v strong
Michel-Lévy diagramhighlighted lineδ = 0.0650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]650 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation650 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 8.809(1) Å · b = 6.187(1) Å · c = 7.509(1) Å
Cell angles
β = 118.74(1) °
Ratio a:b:c
1 : 0.702 : 0.852
Z
2
Morphology

Crystals pyramidal (111). (110) commonly well-developed, but faces of the remaining forms are usually small and often not present in their full complement; cross-fiber veinlets.

Twinning

Contact and interpenetrating.

Type-locality form

Clusters of crystals and twin groups to 1.5 cm. Single crystals and fibrous or acicular aggregates to 4 cm. Solid crusts to 2 cm thick.

Comment

Synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
42.41%
29CuCopperCopper263.546127.092
33.69%
16SSulfurSulfur232.06064.120
17.00%
11NaSodiumSodium122.99022.990
6.10%
1HHydrogenHydrogen31.0083.024
0.80%
Total377.216100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Natrochalciet

In other languages

German
Natrochalcit
Spanish
Natrocalcocita
Italian
Natrocalcite · Natrochalcite

Classification

Strunz
10th ed.

7.DF.15

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.15NatrochalciteSpecies
Dana
8th ed.

31.08.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.08(AB)3(XO4)2Zq·xH2OType
  • 31.08.01— unnamed intermediate level —Group
  • 31.08.01.01NatrochalciteSpecies
CIM

25.2.12

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.12NatrochalciteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1908Palache, C., Warren, C.H. (1908) Kröhnkite, natrochalcite (a new mineral), and other sulphates from Chile. American Journal Of Science, S. 4 Vol. 26. 342-348
  2. 1908Palache, Ch.; Warren, C. H. (1908) Kröhnkit, Natrochalcit (ein neues Mineral) und andere Sulfate aus Chile. Zeitschrift für Kristallographie, 45 (1-6). 529-538 doi:10.1524/zkri.1908.45.1.529DOI: 10.1524/zkri.1908.45.1.529
  3. 1939Palache, C. (1939) Kroehnkite and natrochalcite from Chile. American Journal of Science, 237 (7) 447-455 doi:10.2475/ajs.237.7.447DOI: 10.2475/ajs.237.7.447
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1958Rumanova, I.M., Volodina, G.F. (1958) The crystal structure of natrochalcite, NaCu2OH(SO4)2•H2O = Na(SO4)2(Cu2OH•H2O). Doklady Akademii Nauk SSSR: 123: 78–81. (in Russian)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrochalcite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrochalcite-2853},
  note      = {Accessed 2026-05-11}
}