Where it forms, where it's found
- Geological setting
Oxidation zone of a copper deposit in an arid environment.
- Type locality
- Chuquicamata Mine
- Chuquicamata District
- Calama
- El Loa Province
- Antofagasta
- Chile
-22.2894°, -68.9011°
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 36° · 2V calc = 38°
- Refractive index
- 1.649 – 1.714
- Surface relief
- High
- Principal indices
- nα 1.649 · nβ 1.655 · nγ 1.714
- Dispersion
- r < v strong
Crystallography
- Space group
- C2/m
- Cell parameters
- a = 8.809(1) Å · b = 6.187(1) Å · c = 7.509(1) Å
- Cell angles
- β = 118.74(1) °
- Ratio a:b:c
- 1 : 0.702 : 0.852
- Z
- 2
- Morphology
Crystals pyramidal (111). (110) commonly well-developed, but faces of the remaining forms are usually small and often not present in their full complement; cross-fiber veinlets.
- Twinning
Contact and interpenetrating.
- Type-locality form
Clusters of crystals and twin groups to 1.5 cm. Single crystals and fibrous or acicular aggregates to 4 cm. Solid crusts to 2 cm thick.
- Comment
Synthetic
Chemical composition
Synonyms
- Natrochalciet
In other languages
- German
- Natrochalcit
- Spanish
- Natrocalcocita
- Italian
- Natrocalcite · Natrochalcite
Classification
7.DF.15
- 7SulfatesClass
- 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
- 7.DFWith large and medium-sized cationsGroup
- 7.DF.15NatrochalciteSpecies
31.08.01.01
- 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
- 31.08(AB)3(XO4)2Zq·xH2OType
- 31.08.01— unnamed intermediate level —Group
- 31.08.01.01NatrochalciteSpecies
25.2.12
- 25SulphatesClass
- 25.2Sulphates of Cu and AgGroup
- 25.2.12NatrochalciteSpecies
Group, growth & confusion
- AlumolukrahniteCaCu2+Al(AsO4)2(OH)(H2O)Mineral—
CabalzariteCaMg2(AsO4)2 · 2H2OMineral—
CobaltlotharmeyeriteCaCo2(AsO4)2 · 2H2OMineral—- CobalttsumcoritePbCo2(AsO4)2 · 2H2OMineral—
FerrilotharmeyeriteCaZnFe3+(AsO4)2(OH) · H2OMineral—
GartrellitePbCuFe3+(AsO4)2(OH) · H2OMineral—
HelmutwinkleritePbZn2(AsO4)2 · 2H2OMineral—- KaliochalciteKCu2(SO4)2[(OH)(H2O)]Mineral—
- KrettnichitePbMn3+2(VO4)2(OH)2Mineral—
LotharmeyeriteCaZn2(AsO4)2 · 2H2OMineral—
Literature, links & citation
- 1908Palache, C., Warren, C.H. (1908) Kröhnkite, natrochalcite (a new mineral), and other sulphates from Chile. American Journal Of Science, S. 4 Vol. 26. 342-348
- 1908Palache, Ch.; Warren, C. H. (1908) Kröhnkit, Natrochalcit (ein neues Mineral) und andere Sulfate aus Chile. Zeitschrift für Kristallographie, 45 (1-6). 529-538 doi:10.1524/zkri.1908.45.1.529DOI: 10.1524/zkri.1908.45.1.529
- 1939Palache, C. (1939) Kroehnkite and natrochalcite from Chile. American Journal of Science, 237 (7) 447-455 doi:10.2475/ajs.237.7.447DOI: 10.2475/ajs.237.7.447
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
- 1958Rumanova, I.M., Volodina, G.F. (1958) The crystal structure of natrochalcite, NaCu2OH(SO4)2•H2O = Na(SO4)2(Cu2OH•H2O). Doklady Akademii Nauk SSSR: 123: 78–81. (in Russian)
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Natrochalcite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/natrochalcite-2853},
note = {Accessed 2026-05-11}
}