Nepheline

Na3K(Al4Si4O16)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nph
Discovered
1801
Also known as
  • Beudantina
  • Beudantine
  • Beudantite (of Covelli)
  • +15 more

History

Drop a clear crystal of nepheline into strong acid and it clouds over within moments. That small trick of chemistry gave the mineral its name. When René Just Haüy described it in 1801, he reached for the Greek nephele — cloud — to capture exactly this behaviour.

The cloudiness is not a stain but a transformation. Acid dissolves part of the crystal and leaves behind a gel of silica, the milky haze that fogs the once-clear stone. The reaction is reliable enough that mineralogists still use it in the field to tell nepheline apart from look-alikes.

A second name attached itself to a coarser, greasy-looking form. In 1809 the German chemist Martin Heinrich Klaproth called this variety elaeolite, from the Greek words for oil and stone, after its oily sheen and translucence. The two names describe the same species; elaeolite is simply the massive, lustrous habit rather than clear crystals.

Industrial & practical applications

Almost nothing industrial is done with a single crystal of nepheline. The value lies in the rock that carries it — nepheline syenite, a coarse-grained igneous rock rich in nepheline and feldspar but free of quartz. Quarried and ground, that rock is what reaches the factory floor.

Its biggest job is to replace feldspar in glass and ceramics, where it acts as a flux — a material that lowers the melting point of the batch. Nepheline syenite suits this better than ordinary feldspar because it runs higher in alkali and aluminium and lower in iron and silica. Glassmakers prize its high alumina content and demand very little iron — typical specifications call for more than 23 percent alumina and under 0.1 percent iron oxide. The iron-free grade is the one that lets glass stay clear.

The same low-iron, high-alumina chemistry makes the ground rock a useful filler. It is added to paints, plastics, foam rubber and coatings, and finds further use in refractories and pigments.

In Russia the picture differs. Nepheline recovered as a by-product of apatite mining on the Kola Peninsula feeds ceramics, leather, rubber, textiles, wood and the oil industry. Nepheline from the Kiya-Shaltyr deposit in the Kemerovo Region is processed as a raw material for aluminium manufacturing.

Canada and Norway are the largest producers of nepheline syenite. In 1994 they mined 600,000 and 330,000 tonnes respectively.

Where it forms, where it's found

Geological setting

Characteristic of alkaline igneous rocks.

Type locality
Mount Somma
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
1,374recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Opaque
Colour
Colourless · white · grey · yellowish

Coloured by inclusions as well.

Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

Poor on (1010), (0001)

Fracture
Sub-Conchoidal
Density
2.55 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.526 – 1.546
Surface relief
Moderate
Principal indices
nω 1.529 – 1.546 · nε 1.526 – 1.542
Michel-Lévy diagramhighlighted lineδ = 0.0035
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]35 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation35 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#104
Cell parameters
a = 9.993(2) Å · c = 8.374(3) Å
Z
8
Morphology

Stout prisms, granular, compact, massive.

Twinning

On (1010), (3365), (1122).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
43.81%
14SiSiliconSilicon428.085112.340
19.23%
13AlAluminiumAluminium426.982107.928
18.47%
11NaSodiumSodium322.99068.970
11.80%
19KPotassiumPotassium139.09839.098
6.69%
Total584.320100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Ca
  • H2O

Synonyms

  • Beudantina
  • Beudantine
  • Beudantite (of Covelli)
  • Carolinit
  • Carolinita
  • Carolinite
  • Cavolinit
  • Cavolinita
  • Cavolinite
  • Fatstone
  • Fettstein
  • Gieseckit
  • Nephelien
  • Nephelit
  • Nephelita
  • Nephelite
  • Oelstein
  • Sommite

In other languages

French
Na3KAl4Si4O16 · néphéline · néphélite
German
Eläolith · Fettstein · Nephelin
Spanish
nefelina
Italian
nefelina
Portuguese
nefelina
Japanese
カスミ石 · ネフェリン · 霞石
Chinese
霞石
Russian
Нефелин
Arabic
نيفليت · نيفيلين

Classification

Strunz
10th ed.

9.FA.05

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FATektosilicates without additional non-tetrahedral anionsGroup
  • 9.FA.05NephelineSpecies
Dana
8th ed.

76.02.01.02

  • 76Tectosilicates Al-si FrameworkClass
  • 76.02Al-Si Framework Feldspathoids and related speciesType
  • 76.02.01Nepheline groupGroup
  • 76.02.01.02NephelineSpecies
CIM

16.4.1

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.4Aluminosilicates of Na and KGroup
  • 16.4.1NephelineSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Goychuk, O.F., Lepekha, S.V., Konopleva, N.G., Tsvetov, N.S., Savchenko, Ye.E., Panikorovskii, T.L., Lyalina, L.M. (2023): Incorporation of water into nepheline from rocks of the Khibiny alkaline massif. Atti della sessione scientifica Fersman del GI KSC RAS, 20, 330-335.
  2. 1801Haüy, René Just (1801) Traité de Minéralogie (1st ed.) Vol. 3. Chez Louis, Paris.
  3. 1810Klaproth, M. H. (1810) CCI. Chemische Untersuchung des Elaeoliths. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 5. Rottmann. p.176-179.
  4. 1912Schaller, W. T. (1912) Die chemische Zusammensetzung des Nephelins. Zeitschrift für Kristallographie, 50 (1-6). 343-346 doi:10.1524/zkri.1912.50.1.343DOI: 10.1524/zkri.1912.50.1.343
  5. 1931Bannister, F. A.; Hey, M. H. (1931) A chemical, optical, and X-ray study of nepheline and kaliophilite. Mineralogical Magazine and Journal of the Mineralogical Society, 22 (134). 569-608 doi:10.1180/minmag.1931.02.134.03 DOI: 10.1180/minmag.1931.02.134.03
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nepheline — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nepheline-2880},
  note      = {Accessed 2026-05-11}
}