Ribbeite

Mn2+5(SiO4)2(OH)2
IMA status
  • Approved
IMA symbol
Rib
Discovered
1985
IMA approved
1985
Also known as
  • IMA1985-045
  • Ribbeiet

Where it forms, where it's found

Geological setting

Ribbeite occurs as pinkish lenses up to 5 cm thick and 20 cm long within a 20-m-wide zone of tectonically intercalated manganese and iron ores. Locally within the stope environs, the complexly deformed manganese andiron ores assume the attitude of a vertically plunging cylindroidal fold in which ribbeite has a preferential association with carbonate-silicate facies within the manganese ores. The lenses are derived by tectonic transposition and boudinaging of the original sedimentary protore layering. The area containing ribbeite measured only ca. 40 cm across as exposed on the stope back. Ribbeite can be regarded as a scarce mineral. The transposed layering is transgressed by an abundance of veinlets of a proposed new manganese hydroxy-carbonate that clearly postdate the major tectonism but are themselves slightly deformed. Of interest also is the occurrence of manganosite as a constituent (to 5olo by volume) of some hausmannite-pyrochroite-barite-calcite layers within the Mn ores but not immediately associated with the ribbeite-alleghanyite layers. The manganosite is altering to pyrochroite and hausmannite and occurs as ragged emerald-green relicts up to 2 cm in diameter. The textural evidence strongly suggests that manganosite was a syngenetic precursor of the hausmannite ores.

Type locality
Kombat Mine
  1. Kombat
  2. Otavi Constituency
  3. Otjozondjupa Region
  4. Namibia

-19.7081°, 17.7033°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pink
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.90 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83° · 2V calc = 84°
Refractive index
1.78 – 1.808
Surface relief
High
Principal indices
nα 1.780 · nβ 1.792 · nγ 1.808
Birefringence
0.028
Pleochroism
Visible

X, Y colorless; Z light pink

Dispersion
r > v distinct
UV response
Not fluorescent in UV
Notes

Z > X - Y; X = b, Y = a, Z = c

Michel-Lévy diagramhighlighted lineδ = 0.0280
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]280 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation280 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 4.799 Å · b = 10.742 Å · c = 15.70 Å
Ratio a:b:c
1 : 2.238 : 3.272
Z
4
Morphology

Anhedral

Type-locality form

Fine-grained, anhedral granular aggregates of crystals approximately 0.5 mm in diameter with a typical granulitic texture.

Comment

Space group either Pbnm or Pbn21

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese554.938274.690
55.73%
8OOxygenOxygen1015.999159.990
32.46%
14SiSiliconSilicon228.08556.170
11.40%
1HHydrogenHydrogen21.0082.016
0.41%
Total492.866100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Ca
  • H2O

Synonyms

  • IMA1985-045
  • Ribbeiet

In other languages

German
IMA 1985-045 · Ribbeit
Italian
Ribbeite

Classification

Strunz
10th ed.

9.AF.65

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AFNesosilicates with additional anions; cations in [4], [5] and/or only [6] coordinationGroup
  • 9.AF.65RibbeiteSpecies
Dana
8th ed.

52.03.2b.04

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.03Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] coordination onlyType
  • 52.03.2b— unnamed intermediate level —Group
  • 52.03.2b.04RibbeiteSpecies
CIM

14.17.5

  • 14Silicates not Containing AluminumClass
  • 14.17Silicates of MnGroup
  • 14.17.5RibbeiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1987Peacor, Donald R., Dunn, Pete J., Su, Shu-Chun, Innes, John (1987) Ribbeite, a polymorph of alleghanyite and member of the leucophoenicite group from the Kombat mine, Namibia. American Mineralogist, 72 (1-2) 213-216
  2. 1993Freed, Robert L., Rouse, Roland C., Peacor, Donald R. (1993) Ribbeite, a second example of edge-sharing silicate tetrahedra in the leucophoenicite group. American Mineralogist, 78 (1-2) 190-194
  3. 2001(2001) Ribbeite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2002Brusnitsyn, A. I., Chukanov, N. V. (2002): Ribbeite and alleghanyite from the Yuzhno-Faisulinskoe manganese ore deposit (southern Urals). Zapiski Vserossiiskogo Mineralogicheskogo Obshchestva 131, 98-111 (in Russian).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ribbeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ribbeite-3411},
  note      = {Accessed 2026-05-11}
}