Robertsite

Ca2Mn3+3O2(PO4)3 · 3H2O
IMA status
  • Approved
IMA symbol
Rbt
Discovered
1973
IMA approved
1973
Also known as
  • IMA1973-024
  • Robertsiet

Where it forms, where it's found

Geological setting

Late stage mineralization in granite pegmatites.

Type locality
Tip Top Mine
  1. Fourmile
  2. Custer Mining District
  3. Custer County
  4. South Dakota
  5. USA

43.7156°, -103.6694°

40recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Red · red-brown · deep red · bronzy brown · black
Streak
Red-brown
Tenacity
waxy
Cleavage
Very Good

(100)

Fracture
Micaceous
Density
3.13 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 8°
Refractive index
1.775 – 1.82
Surface relief
High
Principal indices
nα 1.775 · nβ 1.820 · nγ 1.820
Birefringence
0.045
Pleochroism
Strong

X pale red to pink Y,Z deep red brown

Dispersion
relatively weak
Extinction
X ~ ⊥ {100}
UV response
nonfluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Bb
Cell parameters
a = 17.3400(9) Å · b = 19.4464(10) Å · c = 11.2787(6) Å
Cell angles
β = 96.634(3) °
Ratio a:b:c
1 : 1.121 : 0.650
Unit cell volume
3777.7 ų
Z
12
Morphology

Frequently earthy in coatings. Not rarely scaly or in densely packed crystals in subparallel groupings. Crystals frequently show corrugations and deep striations or notches.

Twinning

Multiple rotation twins (π/3) perpendicular to (100)

Comment

A non-standard cell chosen, cfr Andrade et al. (2012)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
44.16%
25MnManganeseManganese354.938164.814
26.76%
15PPhosphorusPhosphorus330.97492.922
15.09%
20CaCalciumCalcium240.07880.156
13.01%
1HHydrogenHydrogen61.0086.048
0.98%
Total615.923100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1973-024
  • Robertsiet

In other languages

French
robertsite
German
Robertsit
Spanish
Robertsita
Italian
Robertsite

Classification

Strunz
10th ed.

8.DH.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.30RobertsiteSpecies
Dana
8th ed.

42.08.04.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.04Mitridatite GroupGroup
  • 42.08.04.02RobertsiteSpecies
CIM

19.12.6

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.6RobertsiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
3 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1974Moore, Paul Brian, Ito, J. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist, 59 (1-2) 48-59
  2. 1988Van Kauwenbergh, S.J., Cooper-Fleck, M., Williams, M.R. (1988) The occurrence of robertsite in a sedimentary phosphate ore from Thailand. Mineralogical Magazine: 52: 505-508.
  3. 1989Jambor, John L., Burke, Ernst A. J. (1989) New Mineral Names. American Mineralogist, 74 (11-12) 1399-1404
  4. 2005(2005) Robertsite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2012Andrade, M.B., Morrison, S.M., Di Domizio, A.J., Feinglos, M.N., Downs, R.T. (2012) Robertsite, Ca^3Mn#3+#^4(PO^4)^3O^2.3H^2O. Acta Crystallographica: E68: i74-i75.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Robertsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/robertsite-3431},
  note      = {Accessed 2026-05-11}
}