Mitridatite

Ca2Fe3+3O2(PO4)3 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mit
Discovered
1914
Also known as
  • Calcium ferri-phosphate
  • Mithridatite
  • Mitridatiet

Where it forms, where it's found

Geological setting

Oolitic sedimentary iron ores.

Late stage mineralization in granite pegmatites.

Type locality
Kamysh-Burun Trough
  1. Kerchenskoe deposit
  2. Kerchenskyi iron ore basin
  3. Kerch Peninsula
  4. Crimea
  5. Ukraine

45.2953°, 36.3677°

133recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Earthy · Resinous
Transparency
Translucent
Colour
Greenish-yellow · olive green · brownish-green · etc.
Streak
pale green
Tenacity
brittle
Cleavage
Very Good

(100) observed on crystals from Gap Lode Pegmatite, South Dakota

Fracture
Irregular/Uneven
Density
3.25 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 5 – 10°
Refractive index
1.785 – 1.85
Surface relief
Very high
Principal indices
nα 1.785 · nβ 1.85 · nγ 1.85
Birefringence
0.065
Pleochroism

X=greenish yellow Y, Z = deep greenish brown

Dispersion
extreme
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]650 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation650 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 17.53 Å · b = 19.35 Å · c = 11.25 Å
Cell angles
β = 95.92 °
Ratio a:b:c
1 : 1.104 : 0.642
Z
12
Morphology

Massive, as nodules, crusts, and veinlets. Earthy and powdery or friable to dense and gum-like. Rare crystals are pseudohexagonal, usually platy and with rounded edges.

Twinning

Similar to robertsite, multiple rotation (π/3) perpendicular to (100)

Type-locality form

Earthy and compact masses of material. Pseudomorphs after other phosphate minerals.

Comment

A2/a non-standard setting

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
43.96%
26FeIronIron355.845167.535
27.08%
15PPhosphorusPhosphorus330.97492.922
15.02%
20CaCalciumCalcium240.07880.156
12.96%
1HHydrogenHydrogen61.0086.048
0.98%
Total618.644100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calcium ferri-phosphate
  • Mithridatite
  • Mitridatiet

In other languages

German
Mitridatit
Spanish
Mitridatita
Italian
mitridatite
Russian
Митридатит

Classification

Strunz
10th ed.

8.DH.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.30MitridatiteSpecies
Dana
8th ed.

42.08.04.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.04Mitridatite GroupGroup
  • 42.08.04.01MitridatiteSpecies
CIM

19.14.17

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.17MitridatiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1910Popov, S.P. (1910) Mineraly rudnykh plastov Kerchenskogo i Tamanskogo poluostrovov [Minerals of ore layers of the Kerch and Taman peninsulas]. Trudy Geologicheskogo Muzeya Akademii nauk SSSR: 99-198.
  2. 1914Dvoichenko, P.A. (1914) The minerals of Crimea. Zapiski Krymskogo Obshchestva Estestvoispytatelei (Proceeding of the Crimea Society of Naturalistes): 4: 104-155 (114).
  3. 1936Efremov (1936) Mem. Soc. russe min.: 65: 225 (as Calcium ferri-phosphate).
  4. 1937Chukhrov, F.V. (1937) Transactions of the Lomonossov Institute, Bulletin de Académy des sciences de l'Union des Républiques Soviétiques Socialistes, Ser. Min.,no. 10: 131, 139.
  5. 1945Sidorenko (1945) Comptes rendus de l’académie des sciences de l’U.R.S.S.: 48: 53.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mitridatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mitridatite-2728},
  note      = {Accessed 2026-05-11}
}