Willhendersonite

KCa(Si3Al3)O12 · 5H2O
IMA status
  • Approved
IMA symbol
Whd
Discovered
1984
Also known as
  • Willhendersoniet

Where it forms, where it's found

Geological setting

Quaternary basic potassic lavas.

Type locality
Vispi Quarry
  1. San Venanzo
  2. Terni Province
  3. Umbria
  4. Italy

42.8623°, 12.2656°

15recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless · white
Streak
White
Tenacity
very brittle
Cleavage
Perfect

(100) (010) (001)

Density
2.10 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 87° · 2V calc = 88°
Refractive index
1.505 – 1.517
Surface relief
Moderate
Principal indices
nα 1.505 · nβ 1.511 · nγ 1.517
Birefringence
0.012
Dispersion
strong
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.206(2) Å · b = 9.216(2) Å · c = 9.500(4) Å
Cell angles
α = 92.34(3) ° · β = 92.70(3) ° · γ = 90.12(3) °
Ratio a:b:c
1 : 1.001 : 1.032
Unit cell volume
808 ų
Z
2
Twinning

Complex, by rotation about [111]; reflection across (001); by rotation about [1_10] or reflection across (1_10)

Type-locality form

"Trellis-like" twinned aggregates, and as tabular crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
51.66%
14SiSiliconSilicon328.08584.255
16.00%
13AlAluminiumAluminium326.98280.946
15.38%
20CaCalciumCalcium140.07840.078
7.61%
19KPotassiumPotassium139.09839.098
7.43%
1HHydrogenHydrogen101.00810.080
1.92%
Total526.440100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na

Synonyms

  • Willhendersoniet

In other languages

German
IMA 1981-030 · Willhendersonit
Italian
willhendersonite
Chinese
板沸石

Classification

Strunz
10th ed.

9.GD.10

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GDChains of 6-membered rings – tabular zeolitesGroup
  • 9.GD.10WillhendersoniteSpecies
Dana
8th ed.

77.01.02.03

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.02Chabazite and related speciesGroup
  • 77.01.02.03WillhendersoniteSpecies
CIM

16.10.13

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.10Aluminosilicates of Ca and alkalisGroup
  • 16.10.13WillhendersoniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Tillmanns, E., Fischer, R. (1982) Über ein neues Zeolith-Mineral mit geordnetem Chabasit-Gerüst. Zeitschrift für Kristallographie, 159, 125-126.
  2. 1981Tillmanns, E., Fischer, R. (1981) Crystal structure of a new zeolite mineral. Acta Crystallographica Section A Foundations of Crystallography, 37. 186 doi:10.1107/s0108767381094002DOI: 10.1107/s0108767381094002
  3. 1984Peacor, Donald R., Dunn, Pete J., Simmons, William B., Tillmanns, Ekkehart, Fischer, Reinhard X. (1984) Willhendersonite, a new zeolite isostructural with chabazite. American Mineralogist, 69 (1-2) 186-189
  4. 1984Tillmanns, E., Fischer, R.X., Baur, W.H. (1984) Chabazite-type framework in the new zeolite willhendersonite, KCaAl3Si3O]2.5H2O. Neues Jahrbuch für Mineralogie, Monatshefte: 1984: 547-558.
  5. 1987Sieber, N. H. W., Fischer, R. X., Tillmanns, E. (1987) Displacive transitions in willhendersonite, a zeolite with a flexible chabazite-type framework. Acta Crystallographica Section A Foundations of Crystallography, 43. doi:10.1107/s0108767387083107DOI: 10.1107/s0108767387083107
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Willhendersonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/willhendersonite-4294},
  note      = {Accessed 2026-05-11}
}