Aenigmatite

Na4[Fe2+10Ti2]O4[Si12O36]
IMA status
  • Approved
  • Grandfathered
IMA symbol
Aen
Discovered
1865
Also known as
  • Cossyrite
  • Cosyrit
  • Cosyrita
  • +5 more

Where it forms, where it's found

Geological setting

A primary constituent in sodium-rich alkalic volcanics, pegmatites, and other silica-poor igneous rocks.

Type locality
Kangerluarsuk Fjord
  1. Ilímaussaq complex
  2. Kujalleq
  3. Greenland

60.8759°, -45.8737°

272recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent · Opaque
Colour
Velvet-black

In thin section, reddish brown to black.

Streak
Reddish brown
Tenacity
brittle
Cleavage
Distinct/Good

(010) (100)

Fracture
Irregular/Uneven

Optical

Optical type
Biaxial (+) · 2V measured = 27 – 55° · 2V calc = 56 – 60°
Refractive index
1.78 – 1.9
Surface relief
Very high
Principal indices
nα 1.78 – 1.8 · nβ 1.8 – 1.82 · nγ 1.87 – 1.9
Dispersion
single
Extinction
Y = b; Z ∧ c = 45°.
Michel-Lévy diagramhighlighted lineδ = 0.0950
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]950 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation950 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 10.415(1) Å · b = 10.840(1) Å · c = 8.931(1) Å
Cell angles
α = 105.107(4) ° · β = 96.610(5) ° · γ = 125.398(4) °
Ratio a:b:c
1 : 1.041 : 0.858
Unit cell volume
746.8 ų
Morphology

Crystals, prismatic after[001], to 10 cm; as irregular segregations.

Twinning

By rotation (011) or about [010] of the pseudomonoclinic cell; polysynthetic.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4015.999639.960
37.14%
26FeIronIron1055.845558.450
32.41%
14SiSiliconSilicon1228.085337.020
19.56%
22TiTitaniumTitanium247.86795.734
5.55%
11NaSodiumSodium422.99091.960
5.34%
Total1723.124100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Mn
  • Mg
  • Ca
  • K
  • Cl

Synonyms

  • Cossyrite
  • Cosyrit
  • Cosyrita
  • Cosyrite
  • Enigmatitt
  • Kölbingit
  • Kölbingita
  • Kölbingite

In other languages

French
Aenigmatite
German
Aenigmatit
Spanish
Enigmatita
Italian
aenigmatite · enigmatite
Chinese
钛硅铁钠石
Russian
Энигматит
Arabic
أينيجماتايت · أينيغماتيت

Classification

Strunz
10th ed.

9.DH.40

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DHInosilicates with 4-periodic single chains, Si4O12Group
  • 9.DH.40AenigmatiteSpecies
Dana
8th ed.

69.02.1a.01

  • 69Inosilicates Chains with Side Branches or LoopsClass
  • 69.02Chains with Side Branches or Loops with P>2Type
  • 69.02.1a— unnamed intermediate level —Group
  • 69.02.1a.01AenigmatiteSpecies
CIM

14.9.34

  • 14Silicates not Containing AluminumClass
  • 14.9Silicates of TiGroup
  • 14.9.34AenigmatiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
8 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1865Breithaupt, August (1865) 29. Kölbingit. Ainigmatit, in Mineralogische Studien. Berg - und hüttenmännische Zeitung. Mit besonderer Brücksichtigung der Mineralogie und Geologie, 24 (47). 397-398
  2. 1881Foerstner, H. (1881) Ueber Cossyrit, ein Mineral aus den Liparitlaven der Insel Pantellaria. Zeitschrift für Kristallographie, 5 (4). 348 doi:10.1524/zkri.1881.5.4.348DOI: 10.1524/zkri.1881.5.4.348
  3. 1964Fleischer, Michael (1964) New Mineral Names. American Mineralogist, 49 (5-6) 816-821
  4. 1964Kelsey, C. H., McKie, Duncan (1964) The unit-cell of aenigmatite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 986-1001 doi:10.1180/minmag.1964.033.266.06 DOI: 10.1180/minmag.1964.033.266.06
  5. 1971Cannillo, E., Mazzi, F ., Fang, J. H., Robinson, Paul D., Ohya, and Y. (1971) The crystal structure of aenigmatite. American Mineralogist, 56 (3-4) 427-446
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Aenigmatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/aenigmatite-33},
  note      = {Accessed 2026-05-11}
}