Hedenbergite

CaFe2+Si2O6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hd
Discovered
1819
Also known as
  • Edenbergite
  • Funkit
  • Funkita
  • +4 more

Where it forms, where it's found

Geological setting

Metamorphosed iron formations, Fe-Mn skarns, alkalic granites, xenoliths in kimberlite.

Type locality
Mormorsgruvan
  1. Tunaberg Cu-Co Ore Field
  2. Tunaberg
  3. Nyköping
  4. Södermanland County
  5. Sweden

58.6390°, 16.8340°

885recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105.5 – 6.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Opaque
Colour
Brownish green · black
Streak
White, grey
Tenacity
brittle
Cleavage
Distinct/Good

Good on (110)

Fracture
Irregular/Uneven · Conchoidal
Density
3.56 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58 – 63° · 2V calc = 56 – 72°
Refractive index
1.699 – 1.757
Surface relief
High
Principal indices
nα 1.699 – 1.739 · nβ 1.705 – 1.745 · nγ 1.728 – 1.757
Pleochroism
Weak

X= pale green, bluish green Y= green, bluish green Z= green, yellow green

Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0235
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]235 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation235 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 9.85 Å · b = 9.01 Å · c = 5.25 Å
Cell angles
β = 104.82 °
Ratio a:b:c
1 : 0.915 : 0.533
Z
4
Morphology

Short prismatic crystals, columnar or acicular aggregates, granular, lamellar, massive.

Twinning

Simple and polysynthetic on (100) (010).

Parting
(100)(010)
Epitaxy

Hedenbergite whiskers epitaxial on babingtonite (Nagashima and Nishio-Hamane, 2018).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
38.69%
14SiSiliconSilicon228.08556.170
22.64%
26FeIronIron155.84555.845
22.51%
20CaCalciumCalcium140.07840.078
16.16%
Total248.087100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Zn
  • Ti
  • Al
  • Mg
  • Na
  • K

Synonyms

  • Edenbergite
  • Funkit
  • Funkita
  • Funkite
  • Lodulit
  • Lodulita
  • Lodulite

In other languages

French
CaFe2+Si2O6 · Hédenbergite
German
Hedenbergit
Spanish
Hedenbergita
Italian
Edenbergite · Hedenbergite
Japanese
ヘデンバージャイト · 灰鉄輝石
Chinese
鈣鐵輝石 · 钙铁辉石
Simplified Chinese
钙铁辉石
Traditional Chinese
鈣鐵輝石
Russian
Геденбергит

Classification

Strunz
10th ed.

9.DA.15

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DAInosilicates with 2-periodic single chains, Si2O6; pyroxene familyGroup
  • 9.DA.15HedenbergiteSpecies
Dana
8th ed.

65.01.3a.02

  • 65Inosilicates Single-width, Unbranched Chains, (w=1)Class
  • 65.01Single-Width Unbranched Chains, W=1 with chains P=2Type
  • 65.01.3a— unnamed intermediate level —Group
  • 65.01.3a.02HedenbergiteSpecies
CIM

14.22.1

  • 14Silicates not Containing AluminumClass
  • 14.22Silicates of Fe and CaGroup
  • 14.22.1HedenbergiteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Hedenberg, A.L. in Afhandlingar i Fysic, Kemi och Mineralogi. Utgifne af W. Hisinger och J. Berzelius. (Stockholm, 1806-18),Vol 2, p. 164
  2. 1819Berzelius, J. J. (1819) Nouveau Système de minéralogie. Méquignon-Marvis.
  3. 1951Poldervaart, A., Hess, H. H. (1951) Pyroxenes in the Crystallization of Basaltic Magma. The Journal of Geology, 59 (5) 472-489 doi:10.1086/625891DOI: 10.1086/625891
  4. 1966Smith, J. V. (1966) X-Ray-Emission Microanalysis of Rock-Forming Minerals: VI. Clinopyroxenes near the Diopside-Hedenbergite Join. The Journal of Geology, 74 (4) 463-477 doi:10.1086/627178DOI: 10.1086/627178
  5. 1969Clark, J.R., Appleman, D.E., and Papike, J.J. (1969) Crystal-chemical characterization of clinopyroxenes based on eight new structure refinements. MSA Special Paper: 2: 31-50.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hedenbergite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hedenbergite-1842},
  note      = {Accessed 2026-05-11}
}