Brackebuschite

Pb2Mn3+(VO4)2(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bbs
Discovered
1880
Also known as
  • Brackebuschiet

Where it forms, where it's found

Geological setting

Oxidized hydrothermal veins in a Pb-Zn deposit.

Type locality
Venus Mine
  1. Venus Pb-Zn deposit
  2. El Guaico mining district
  3. Ciénaga del Coro District
  4. Minas Department
  5. Córdoba Province
  6. Argentina

-30.9711°, -65.1967°

13recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Dark brown to black · reddish brown in transmitted light.
Streak
Yellow
Tenacity
brittle
Cleavage
None Observed
Fracture
Sub-Conchoidal
Density
6.05 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 82 – 88°
Refractive index
2.28 – 2.49
Surface relief
Very high
Principal indices
nα 2.28 · nβ 2.36 – 2.38 · nγ 2.48 – 2.49
Birefringence
0.21
Pleochroism
Visible

X = Nearly colourless Y = Dark reddish brown Z = Reddish brown

Dispersion
r > v strong
Extinction
X^a = 20°; Y=b
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.2100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2100 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2100 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 8.88 Å · b = 6.155 Å · c = 7.681 Å
Cell angles
β = 111.5 °
Ratio a:b:c
1 : 0.693 : 0.865
Z
2
Morphology

Crystals commonly acicular, elongated and striated parallel [010]; may be lathlike or wedge-shaped, flattened on (001), with (100), (001), (011), (102), (103), and others, perhaops without terminal faces; sprays, dendritic, botryoidal.

Type-locality form

Dark brown elongated crystals

Comment

β = 111.5 - 111.833; parameters from the refinement of Lafuente & Downs (2016): a=7.64920, b=6.12620, c=8.9241, β=112.1950

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
57.86%
8OOxygenOxygen915.999143.991
20.10%
23VVanadiumVanadium250.942101.884
14.23%
25MnManganeseManganese154.93854.938
7.67%
1HHydrogenHydrogen11.0081.008
0.14%
Total716.221100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brackebuschiet

In other languages

German
Brackebuschit
Spanish
Brackebuschita
Italian
brackebuschite
Chinese
水钒锰铅矿

Classification

Strunz
10th ed.

8.BG.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BGWith medium-sized and large cations, (OH, etc.):RO4 = 0.5:1Group
  • 8.BG.05BrackebuschiteSpecies
Dana
8th ed.

40.02.08.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.02AB2(XO4)2·xH2OType
  • 40.02.08Brackebushite GroupGroup
  • 40.02.08.01BrackebuschiteSpecies
CIM

21.4.18

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.4Vanadates of U, Mn, Fe or NiGroup
  • 21.4.18BrackebuschiteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. 1880Rammelsberg (1880) Zeitschrift der Deutsche geologische Gesellschaft, Berlin: 32: 711 (cites Doering).
  2. 1883Doering (1883) Bol. ac. cienc. Córdoba: 5: 501.
  3. 1934Larsen, E.S.; Berman, H. (1934) The microscopic determination of the nonopaque minerals. Bulletin of the US Geological Survey Vol. 848. US Geological Survey p.1-266. doi:10.3133/b848 DOI: 10.3133/b848
  4. 1948Berry, L. G., Graham, A. R. (1948) X-ray measurements on brackebuschite and hematolite. American Mineralogist, 33 (7-8) 489-495
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brackebuschite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brackebuschite-749},
  note      = {Accessed 2026-05-11}
}