Brazilianite

NaAl3(PO4)2(OH)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bzl
Discovered
1945
Also known as
  • Brazilianit
  • Brazilianite (of Pough and Henderson)

Where it forms, where it's found

Geological setting

Granite pegmatite.

Phosphate zones in granitic pegmatites. Metamorphosed sedimentary deposits.

Type locality
Córrego Frio mine
  1. Linópolis
  2. Divino das Laranjeiras
  3. Minas Gerais
  4. Brazil

-18.6694°, -41.4704°

61recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Chartreuse yellow · pale yellow · yellow green · colourless · coloured varieties are colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Good on (010)

Fracture
Conchoidal
Density
2.98 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 71 – 75° · 2V calc = 72 – 76°
Refractive index
1.602 – 1.623
Surface relief
Moderate
Principal indices
nα 1.602 · nβ 1.609 · nγ 1.621 – 1.623
Birefringence
0.020
Pleochroism
Non-pleochroic
Dispersion
r < v perceptible
Extinction
Y = b; X ∧ c = –20°.
UV response
Not fluorescent,
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.229(6) Å · b = 10.142(5) Å · c = 7.098(4) Å
Cell angles
β = 97.7 °
Ratio a:b:c
1 : 0.903 : 0.632
Z
4
Morphology

Typically short prismatic, spearhead shaped, elongated [100], with large (011) and (111). Also may exhibit (010), (110), (301), and (101). May also occur as radially-fibrous or globular aggregates. Forms include: (001), (010), (100), (340), (110), (210), (310), (610), (011), (101), (101), (201), (301), (113), (111), (111), (211), (121).

Type-locality form

Large, form-rich, euhedral crystals.

Comment

Space group P21/n.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
53.05%
13AlAluminiumAluminium326.98280.946
22.37%
15PPhosphorusPhosphorus230.97461.948
17.12%
11NaSodiumSodium122.99022.990
6.35%
1HHydrogenHydrogen41.0084.032
1.11%
Total361.904100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Brazilianit
  • Brazilianite (of Pough and Henderson)

In other languages

French
brazilianite
German
Brasilianit
Spanish
brasilianita
Italian
brasilianite
Portuguese
brasilianita · brasilianite
Japanese
ブラジリアナイト · ブラジル石
Chinese
巴西石
Russian
бразилианит

Classification

Strunz
10th ed.

8.BK.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BKWith medium-sized and large cations, (OH, etc.):RO4 = 2:1, 2.5:1Group
  • 8.BK.05BrazilianiteSpecies
Dana
8th ed.

41.05.07.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.07— unnamed intermediate level —Group
  • 41.05.07.01BrazilianiteSpecies
CIM

19.8.2

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.2BrazilianiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1945Pough, Frederick H., Henderson, Edward P. (1945) Brazilianite, a new phosphate mineral. American Mineralogist, 30 (9-10) 572-582
  2. 1946Hurlbut, Cornelius S. (1946) Additional data on brazilianite. American Mineralogist, 31 (9-10) 507
  3. 1948Frondel, Clifford, Lindberg, Marie Louise (1948) Second occurrence of brazilianite. American Mineralogist, 33 (3-4) 135-141
  4. 1949Pecora, William T., Fahey, Joseph J. (1949) The Corrego Frio pegmatite, Minas Gerais: scorzalite and souzalite, two new phosphate minerals. American Mineralogist, 34 (1-2) 83-93
  5. 1949Federico, M. (1949) Ricerche cristallografiche ed ottiche sulla Brasilianite. Periodico di Mineralogia – Roma: 33-39.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brazilianite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brazilianite-760},
  note      = {Accessed 2026-05-11}
}