Whitlockite

Ca9Mg(PO3OH)(PO4)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wht
Discovered
1940
Also known as
  • Bobdownsite
  • Pyrophosphorite
  • Whitlockiet

Where it forms, where it's found

Geological setting

Pegmatite

Pegmatites; phosphate-rock deposits.

Type locality
Palermo No. 1 Mine
  1. Groton
  2. Grafton County
  3. New Hampshire
  4. USA

43.7513°, -71.8896°

116recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · grey-white · light pink · light yellow · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.12 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.626 – 1.629
Surface relief
Moderate
Principal indices
nω 1.629 · nε 1.626
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#85
Cell parameters
a = 10.33 Å · c = 37.103(5) Å
Z
3
Morphology

Crystals exhibit rhombohedral development; rarely tabular (0001). Coarse-granular to earthy. Cave pearls.

Type-locality form

Occurs as coarse granular masses with small open cavities lined with crystals. The crystals range in size from about 1 mm to 1.5 cm along the c-axis with an embedded crystal measuring about 3 cm. The crystals usually are simple rhombohedra.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2815.999447.972
42.63%
20CaCalciumCalcium940.078360.702
34.33%
15PPhosphorusPhosphorus730.974216.818
20.63%
12MgMagnesiumMagnesium124.30524.305
2.31%
1HHydrogenHydrogen11.0081.008
0.10%
Total1050.805100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bobdownsite
  • Pyrophosphorite
  • Whitlockiet

In other languages

French
Whitlockite
German
Whitlockit
Spanish
Whitlockita
Italian
Whitlockite
Japanese
ウィットロカイト · ウィットロッカイト
Chinese
白磷鈣礦 · 白磷钙矿
Russian
Витлокит

Classification

Strunz
10th ed.

8.AC.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.45WhitlockiteSpecies
Dana
8th ed.

38.03.04.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.03(AB)3(XO4)2Type
  • 38.03.04Whitlockite groupGroup
  • 38.03.04.01WhitlockiteSpecies
CIM

19.4.8

  • 19PhosphatesClass
  • 19.4Phosphates of CaGroup
  • 19.4.8WhitlockiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1865Julien, A.A. (1865) On metabrushite, zeugite, ornithite, and other minerals of the Key of Sombrero, W.I.. American Journal of Science: 40: 367-379. (as Zeugite)
  2. 1878Shepard, C.U., Jr. (1878) On a new mineral, pyrophosporite: an anhydrous pyrophosphate of lime from the West Indies. American Journal of Science: 15: 49-51. (as Pyrophosphorite)
  3. 1940American Mineralogical Society, Program and Abstracts (1940): 7.
  4. 1941Frondel, Clifford (1941) Whitlockite: a new calcium phosphate, Ca3(PO4)2. American Mineralogist, 26 (3) 145-152
  5. 1943Frondel, Clifford (1943) Mineralogy of the calcium phosphates in insular phosphate rock. American Mineralogist, 28 (4) 215-232
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whitlockite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whitlockite-4280},
  note      = {Accessed 2026-05-11}
}