Cannizzarite

Pb8Bi10S23
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cnz
Discovered
1924
Also known as
  • Cannizzariet

Where it forms, where it's found

Geological setting

Deep fumarolic activity.

Fumaroles; sulfide veinlets in greisen (Shumilovsk); common associated minerals concern the latter

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

40recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
White to silvery gray

Iridescent tarnish.

Tenacity
malleable
Cleavage

Somewhat malleable and elastic, prone to twisting and bending.

Density
6.7 g/cm³

Optical

Anisotropism
Strong from blue to gray
Tropism
Anisotropic
Reflectance R%
(49.2,51.3) 400, (49.8,52.4) 420, (50.4,53.5) 440, (50.7,53.7) 460, (50.6,53.3) 480, (50.2,52.8) 500, (49.7,52.2) 520, (49.2,51.6) 540, (48.6,51.0) 560, (48.2,50.4) 580, (47.8,50.0) 600, (47.5,49.5) 620, (47.3,49.2) 640, (47.2,49.0) 660, (47.2,49.0) 680, (47.2,49.2) 700
Reflected-light panel
48.8 %anisotropic · dual curve
Specimen sRGB 242, 172, 98
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong from blue to gray

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 38.86(3) Å · b = 4.090(3) Å · c = 39.83(3) Å
Cell angles
β = 102.30(3) °
Ratio a:b:c
1 : 0.105 : 1.025
Morphology

Thin laths, felted masses, stellate groups. Crystals to 2 mm.

Twinning

Stellate trillings and simple V-shaped twins.

Type-locality form

Very thin single laths, up to 2 mm, often warped but also found straight; may have frayed ends; also as felted masses and stellate groups.

Comment

(Cd,In)-rich cannizzarite has a 15.4172(9), b 4.0582(2), c 20.8071(12) Å, β 98.031(2)°, V 1289.05(12) Å3 (Borisov et al., 2012). Previously assumed to be a = 4.13, b = 4.13, c = 15.48 Å, beta 99° (Graham et al., 1953).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth10208.9802089.800
46.60%
82PbLeadLead8207.2001657.600
36.96%
16SSulfurSulfur2332.060737.380
16.44%
Total4484.780100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Se
  • Ag
  • Sb
  • Te

Synonyms

  • Cannizzariet

In other languages

German
Cannizzarit
Italian
Cannizzarite
Chinese
卡辉铋铅矿

Classification

Strunz
10th ed.

2.JB.20

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.20CannizzariteSpecies
Dana
8th ed.

03.06.05.01

  • 03SulfosaltsClass
  • 03.062 < ø < 2.49Type
  • 03.06.05— unnamed intermediate level —Group
  • 03.06.05.01CannizzariteSpecies
CIM

5.6.25

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.25CannizzariteSpecies

Group, growth & confusion

Often grow together
10 minerals

Literature, links & citation

Citations
  1. 1924Zambonini, F., de Fiore, O., Carobbi, G. (1924) Su un solfobismutito di piombo di Vulcano (Isole Eolie). Annali dell'Osservatorio Vesuviano: 1: 31-36.
  2. 1925Zambonini, F., de Fiore, O., Carobbi, G. (1925) Su un sulfobismutito di piombo di Vulcano (Isole Eolie). Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 31: 24-29.
  3. 1926Foshag, W.F. (1926) New mineral names. American Mineralogist: 11: 194-194.
  4. 1938Wolfe, C. W. (1938) Cannizzarite and bismuthinite from Vulcano. American Mineralogist, 23 (11) 790-798
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cannizzarite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cannizzarite-883},
  note      = {Accessed 2026-05-11}
}