Arsenopyrite

FeAsS
IMA status
  • Approved
  • Grandfathered
IMA symbol
Apy
Discovered
1847
Also known as
  • Agujillas
  • Arsenical Iron
  • Arsenical Pyrite
  • +20 more

History

Long before chemists settled on the name arsenopyrite, German miners called this brassy iron-arsenic sulfide mispickel — a word of German origin that still surfaces in older mineralogical literature.

The modern name was coined in 1847 by the mineralogist Ernst Friedrich Glocker, as a contraction of arsenical pyrite. Pyrite is the familiar iron sulfide the mineral visibly resembles; the arsenical prefix flagged the arsenic that distinguishes it. The new term was also a near-direct translation of the older German arsenkies, which had long sat alongside mispickel in mining and assay manuals. Both earlier names predate Glocker's coinage, and the mineral itself had been recognised and worked under them well before 1847.

Industrial & practical applications

Arsenopyrite is, on paper, a principal ore of arsenic — its formula carries 46% arsenic by mass. In practice, very little of today's arsenic comes from mining it. The metal is recovered primarily from the smelter dust of copper, gold, and lead refineries. There it concentrates as an unwanted impurity in ores worked for other metals. When arsenopyrite is roasted in air the arsenic sublimes off as arsenic(III) oxide, leaving iron oxides behind — but the same product falls out of copper smelting at much larger scale.

That leaves arsenopyrite's most consequential modern role outside the arsenic trade entirely. The mineral often hosts gold, locked inside its crystal structure so tightly that conventional cyanide leaching cannot reach it. Such ores are called refractory. Recovering the gold requires a pre-oxidation step that breaks the arsenopyrite apart before cyanidation. Three methods are in industrial use: roasting in air, pressure oxidation in an autoclave, and bio-oxidation by acidophilic bacteria that metabolise the sulfide. Each releases the gold; each also concentrates arsenic into a waste stream that has to be stabilised, not vented. For modern gold producers working refractory ore, arsenopyrite is the obstacle the whole flow sheet is designed around.

Where it forms, where it's found

Geological setting

High-temperature gold-quartz or tin hydrothermal veins, pegmatites, contact metamorphic rocks, gneisses, schists.

9,268recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic.
Transparency
Opaque
Colour
Silver-white to steel-gray · may have a slight yellow appearance

Tarnished material common, some iridescent

Streak
Gray-black
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (001); (010) in traces

Fracture
Irregular/Uneven
Density
6.07 g/cm³

Optical

Pleochroism
Weak

White or bluish tint, faint reddish yellow

Optical colour
White with faint yellow tint
Anisotropism
Strong red-violet
Tropism
Anisotropic
Reflectance R%
(50.3, 51.8) 400, (50.3, 51.8) 420, (51.3, 51.8) 440, (50.6, 51.8) 460, (51.0, 51.9) 480, (51.4, 51.9) 500, (51.8, 51.9) 520, (52.2, 51.9) 540, (52.5, 51.9) 560, (53.0, 51.8) 580, (53.4, 51.6) 600, (53.6, 51.5) 620, (53.6, 51.3) 640, (53.6, 51.3) 660, (53.4, 51.2) 680, (53.2, 51.0) 700
Luminescence
None
UV response
Not fluorescent
Reflected-light panel
52.2 %anisotropic · dual curve
Specimen sRGB 255, 177, 97
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong red-violet
Reflected colour
White with faint yellow tint

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 5.7612(8) Å · b = 5.6841(7) Å · c = 5.7674(8) Å
Cell angles
β = 111.721(8) °
Ratio a:b:c
1 : 0.987 : 1.001
Unit cell volume
175.46 ų
Z
4
Morphology

Flat tabular to blocky (sometimes pseudo-octahedral or rhombic) to prismatic.

Twinning

Common on (100) and (001). Contact or penetration on (101), on (012) trillings or cruciform.

Comment

Cell parameters from Bindi et al. (2012), using stoichiometric crystals. Pseudo-orthorhombic, face-centred cell: ~5.7, ~6.4, ~9.6 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic174.92274.922
46.01%
26FeIronIron155.84555.845
34.30%
16SSulfurSulfur132.06032.060
19.69%
Total162.827100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Au
  • Co
  • Sn
  • Ni
  • Sb
  • Bi
  • Cu
  • Pb

Synonyms

  • Agujillas
  • Arsenical Iron
  • Arsenical Pyrite
  • Arsenical Pyrites
  • Arsenikkies
  • Arsenikstein
  • Arsenkies
  • Arsenkis
  • Arsenomarcasit
  • Arsenomarcasita
  • Arsenomarcasite
  • Arsenomarkasit
  • Dalarnit
  • Dalarnite
  • Hüttraucherz
  • Mispickel
  • Mispiquel
  • Mistpuckel
  • Pirita de Arsénico
  • Plinian
  • Rauschgelbkies
  • Thalheimit
  • Thalheimite

In other languages

French
Arsenomarcasite · Arsénopyrite · Dalarnite · Delarnite · Hoffamnnite · Mispickel · Pyrite arsenicale · Thaleimite
German
Arsenikstein · Arsenkies · Arsenomarkasit · Arsenopyrit · Dalarnit · Giftkies · Glanzarsenikkies · Mispickel · Mißpickel · Mistpuckel · Rauschgelbkies · Thalheimit
Spanish
arsenopirita · mispiquel
Italian
Arsenopirite · Arsenopyrite
Portuguese
arsenopirita · Arsenopirite
Japanese
硫ヒ鉄鉱 · 硫砒鉄鉱
Chinese
毒砂 · 砷黃鐵礦
Simplified Chinese
砷黄铁矿
Traditional Chinese
砷黃鐵礦
Russian
арсенопирит · Миспикель · Мышьяковый колчедан · Тальгеймит
Arabic
أرسينوبيريت · ارسينوبيريت

Classification

Strunz
10th ed.

2.EB.20

  • 2Sulfides and SulfosaltsClass
  • 2.EMetal Sulfides, M: S <= 1:2Division
  • 2.EBM:S = 1:2, with Fe, Co, Ni, PGE, etc.Group
  • 2.EB.20ArsenopyriteSpecies
Dana
8th ed.

02.12.04.01

  • 02SulfidesClass
  • 02.12AmBnXp, with (m+n):p = 1:2Type
  • 02.12.04Arsenopyrite Group (Monoclinic: P21/c (Pseudo-orthorhombic))Group
  • 02.12.04.01ArsenopyriteSpecies
CIM

3.9.12

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.9Sulphides etc. of FeGroup
  • 3.9.12ArsenopyriteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
17 minerals

Literature, links & citation

Citations
  1. 1884Renard, A. (1884) Sur les pseudocristaux de quartz affectant la forme de la pyrite arsénicale. Bulletin de l'Académie royale de Belgique, 3e série, 8, 324.
  2. 1936Buerger, M. J. (1936) A Systematic Method of Investigating Superstructures, Applied to the Arsenopyrite Crystal Structural Type. Zeitschrift für Kristallographie, 94 (1). 425-439 doi:10.1524/zkri.1936.94.1.425DOI: 10.1524/zkri.1936.94.1.425
  3. 1936Buerger, M. J. (1936) The Symmetry and Crystal Structure of the Minerals of the Arsenopyrite Group. Zeitschrift für Kristallographie, 95 (1-6). 83-113 doi:10.1524/zkri.1936.95.1.83 DOI: 10.1524/zkri.1936.95.1.83
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1960Clark, Lloyd A. (1960) The Fe-As-S system - Phase relations and applications. Economic Geology, 55 (7). 1345-1381 doi:10.2113/gsecongeo.55.7.1345DOI: 10.2113/gsecongeo.55.7.1345
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arsenopyrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arsenopyrite-305},
  note      = {Accessed 2026-05-11}
}