Chiyokoite

Ca3Si(CO3)[B(OH)4]O(OH)5 · 12H2O
IMA status
  • Approved
IMA symbol
Cyo
Also known as
  • Chiyokoiet

Where it forms, where it's found

Geological setting

Low-temperature hydrothermally altered, boron-bearing, low-Fe calc-silicate skarn.

Type locality
Fuka mine
  1. Fuka
  2. Bitchū
  3. Takahashi City
  4. Okayama Prefecture
  5. Japan

34.7882°, 133.4429°

1recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Pink to colorless
Streak
White
Cleavage
Distinct/Good

(1010) and (0001) good

Fracture
Step-Like
Density
1.85 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.492 – 1.523
Surface relief
Moderate
Principal indices
nω 1.523 · nε 1.492
Pleochroism
Non-pleochroic
UV response
Non fluorescent
Notes

Rectangular grains have straight extinction, and most of them have negative elongation. Some grains are of hexagonal shape; these are isotropic and show an interference figure perpendicular to the optical axis.

Michel-Lévy diagramhighlighted lineδ = 0.0310
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]310 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation310 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63
Cell parameters
a = 11.0119(5) Å · c = 10.5252(6) Å
Unit cell volume
1105.3 ų
Morphology

The major forms are the hexagonal prism (1010) and monohedra (0001) and (0001). Narrow faces of the hexagonal pyramid {h0il} are observed on some crystals.

Type-locality form

Hexagonal prismatic crystals up to 30 µm long and up to 20 µm thick. Clusters which form friable nests up to 1 cm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2515.999399.975
66.18%
20CaCalciumCalcium340.078120.234
19.89%
1HHydrogenHydrogen331.00833.264
5.50%
14SiSiliconSilicon128.08528.085
4.65%
6CCarbonCarbon112.01112.011
1.99%
5BBoronBoron110.81010.810
1.79%
Total604.379100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chiyokoiet

In other languages

German
Chiyokoit · IMA 2019-054

Classification

Strunz
10th ed.

7.DG.15

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DGWith large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3Group
  • 7.DG.15ChiyokoiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2019Pekov, I. V., Zubkova, N. V., Agakhanov, A. A., Belakovskiy, D. I., Vigasina, M. F., Yapaskurt, V. O., Britvin, S. N., Turchkova, A. G., Sidorov, E. G., Pushcharovsky, D. Y. (2019) CNMNC Newsletter No. 52, New minerals and nomenclature modifications approved in 2019. Mineralogical Magazine, 83 (6) 887-893 doi:10.1180/mgm.2019.73DOI: 10.1180/mgm.2019.73
  2. 2020Lykova, Inna, Chukanov, Nikita V., Pekov, Igor V., Yapaskurt, Vasiliy O., Pautov, Leonid A., Karpenko, Vladimir Yu., Belakovskiy, Dmitry I., Varlamov, Dmitry A., Britvin, Sergey N., Scheidl, Katharina S. (2020) Chiyokoite, Ca3Si(CO3)[B(OH)4]O(OH)5·12H2O, a new ettringite-group mineral from the Fuka mine, Okayama Prefecture, Japan. The Canadian Mineralogist, 58 (5) 653-662 doi:10.3749/canmin.2000030DOI: 10.3749/canmin.2000030
  3. 2021Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 59. European Journal of Mineralogy, 33 (1) 139-143 doi:10.5194/ejm-33-139-2021 DOI: 10.5194/ejm-33-139-2021
  4. 2022(2022) Chiyokoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chiyokoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chiyokoite-54035},
  note      = {Accessed 2026-05-11}
}