Kottenheimite

Ca3Si(SO4)2(OH)6 · 12H2O
IMA status
  • Approved
IMA symbol
Khm
IMA approved
2011
Also known as
  • IMA2011-038
  • Kottenheimiet

Where it forms, where it's found

Geological setting

Late hydrothermal assemblage related to alkali olivine basalt.

Type locality
Caspar quarry
  1. Ettringen
  2. Vordereifel
  3. Mayen-Koblenz
  4. Rhineland-Palatinate
  5. Germany

50.3525°, 7.2335°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless · white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
1.92 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.477 – 1.49
Surface relief
Low
Principal indices
nω 1.490 · nε 1.477
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#108
Cell parameters
a = 11.1548(3) Å · c = 10.5702(3) Å
Unit cell volume
1139.04 ų
Z
2
Type-locality form

Snow-white radiating and random aggregates of hair-like subparallel clusters to 0.2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
63.16%
20CaCalciumCalcium340.078120.234
18.25%
16SSulfurSulfur232.06064.120
9.74%
1HHydrogenHydrogen301.00830.240
4.59%
14SiSiliconSilicon128.08528.085
4.26%
Total658.653100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-038
  • Kottenheimiet

In other languages

German
IMA 2011-038 · Kottenheimit
Italian
kottenheimite

Classification

Strunz
10th ed.

7.DG.15

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DGWith large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3Group
  • 7.DG.15KottenheimiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  2. 2012Chukanov, N. V., Britvin, S. N., Van, K. V., Mockel, S., Zadov, A. E. (2012) Kottenheimite, Ca3Si(OH)6(SO4)2·12H2O, a new member of the ettringite group from the Eifel area, Germany. The Canadian Mineralogist, 50 (1) 55-63 doi:10.3749/canmin.50.1.55 DOI: 10.3749/canmin.50.1.55
  3. 2014(2014) Kottenheimite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2018Campostrini, Italo, Di Domenico, Dario, Demartin, Francesco., Russo, Massimo. (2018) Kottenheimite,Ca3Si(SO4)2(OH)6 .12H2 0, della cava Montenero di Onano (Viterbo,Lazio): secondo ritrovamento mondiale. [Kottenheimite, Ca3Si(SO4) 2(OH)6∙12H2O, from the Montenero quarry of Onano (Viterbo, Lazio): second world discovery]. Micro (Associazione Micromineralogica Italiana), 16 (1). 38-43
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kottenheimite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kottenheimite-42534},
  note      = {Accessed 2026-05-11}
}