Hafnon

Hf(SiO4)
IMA status
  • Approved
IMA symbol
Haf
Discovered
1974
Also known as
  • IMA1974-018

Where it forms, where it's found

Geological setting

Heavy mineral concentrates from a tantalum-bearing granitic pegmatite.

weathered pegmatite (Mt. Holland)

Type locality
Muiâne pegmatite (Muiâne mine
  1. Emdal mines)
  2. Muiane-Naipa group
  3. Gilé District
  4. Zambezia Province
  5. Mozambique

-15.7375°, 38.2528°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789107.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Red-orange · brown-yellow · colourless (rare)
Density
6.97 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.93 – 2.03
Surface relief
Very high
Principal indices
nω 1.93 – 1.97 · nε 1.98 – 2.03
Michel-Lévy diagramhighlighted lineδ = 0.0550
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]550 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation550 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#178
Cell parameters
a = 6.5725(7) Å · c = 5.9632(4) Å
Z
4
Morphology

Crystals euhedral to irregular. Often zoned with zircon.

Type-locality form

Zones in transparent, orange red colored, grain-zized fragments of euhedral zircon crystals with a high density.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
72HfHafniumHafnium1178.490178.490
65.97%
8OOxygenOxygen415.99963.996
23.65%
14SiSiliconSilicon128.08528.085
10.38%
Total270.571100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zr

Synonyms

  • IMA1974-018

In other languages

French
Hafnon
German
Hafnon · IMA 1974-018
Spanish
Hafnón
Italian
hafnon
Japanese
ハフノン
Russian
гафнон

Classification

Strunz
10th ed.

9.AD.30

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.ADNesosilicates without additional anions; cations in [6] and/or greater coordinationGroup
  • 9.AD.30HafnonSpecies
Dana
8th ed.

51.05.02.02

  • 51Nesosilicates Insular Sio4 Groups OnlyClass
  • 51.05Insular SiO4 Groups Only with cations in >[6] coordinationType
  • 51.05.02Zircon groupGroup
  • 51.05.02.02HafnonSpecies
CIM

14.10.2

  • 14Silicates not Containing AluminumClass
  • 14.10Silicates of Zr or HfGroup
  • 14.10.2HafnonSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1967Salt, D.J., Hornung, G. (1967) Synthesis and X-ray study of hafnium silicate. Journal of the American Ceramic Society: 50: 549-550.
  2. 1969Ramakrishnan, S.S., Gokhale, K.V.G.K., Subbarao, E.C. (1969) Solid solubility in the system zircon - hafnon. Materials Research Bulletin, 4 (5). 323-327 doi:10.1016/0025-5408(69)90036-1DOI: 10.1016/0025-5408(69)90036-1
  3. 1970Ramakrishnan, S.S., Subbarao, E.C., Gokhale, K.V.G.K. (1970) Effect of solid solution of thermal stability of zircon. Materials Research Bulletin, 5 (11). 965-972 doi:10.1016/0025-5408(70)90147-9DOI: 10.1016/0025-5408(70)90147-9
  4. 1973Vasquez, A., Rogers, J. D., Maciel, A., & Fraga, E. R. (1973). Nuclear quadrupole interaction in Hafnon. Revista Brasileira de Física, 3(2). http://sbfisica.org.br/bjp/download/v03/v03a20.pdf
  5. 1974Neves, J. M. Correia, Nunes, J. E. Lopes, Sahama, Th. G. (1974) High hafnium members of the zircon-hafnon series from the granite pegmatites of Zambézia, Mozambique. Contributions to Mineralogy and Petrology, 48 (1) 73-80 doi:10.1007/bf00399111DOI: 10.1007/bf00399111
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hafnon — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hafnon-1792},
  note      = {Accessed 2026-05-11}
}