Hectorite

Na0.3(Mg,Li)3Si4O10(F,OH)2 · nH2O
IMA status
  • Approved
  • Grandfathered
  • Questionable
IMA symbol
Htr
Discovered
1941
Also known as
  • Fluorhectorite
  • Ghassoulit
  • Ghassoulita
  • +2 more

Where it forms, where it's found

Geological setting

bentonite deposit,

Type locality
Hector Bentonite Mine No. 1
  1. Hector
  2. San Bernardino County
  3. California
  4. USA
28recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White · cream · pale brown · mottled
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
2.3 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.49 – 1.52
Surface relief
Moderate
Principal indices
nα 1.49 · nβ 1.50 · nγ 1.52
Dispersion
none
Notes

2V(meas.) = Small

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.25 Å · b = 9.18 Å · c = 16.0 Å
Cell angles
β = 99 °
Ratio a:b:c
1 : 1.749 : 3.048

Chemical composition

Impurities
  • Ti
  • Al
  • Fe
  • Ca
  • K
  • Cl

Synonyms

  • Fluorhectorite
  • Ghassoulit
  • Ghassoulita
  • Hectoriet
  • Hectorite (of Strese and Hofmann)

In other languages

French
Hectorite
German
Hectorit
Italian
Hectorite
Japanese
ヘクトライト
Chinese
鋰蒙脫石 · 鋰蒙脫石黏土
Arabic
الهكتوريت · هكتوريت

Classification

Strunz
10th ed.

9.EC.45

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.45HectoriteSpecies
Dana
8th ed.

71.03.1b.04

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.03Sheets of 6-membered rings with 2:1 claysType
  • 71.03.1b— unnamed intermediate level —Group
  • 71.03.1b.04HectoriteSpecies
CIM

17.1.1

  • 17Silicates Containing other AnionsClass
  • 17.1Silicates with fluoride (not containing Al)Group
  • 17.1.1HectoriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1941Strese, V.H., Hofmann, U. (1941) Synthese von Magnesiumsilikat-Gelen mit zweidimensional regelmäßiger Struktur. Zeitschrift für Anorganische und Allgemeine Chemie: 247: 65-94.
  2. 1944Fleischer, M. (1944) New mineral names. American Mineralogist, 29 (1-2). 73-74
  3. 1966Oberlin, A., Mering, J. (1966) Observations sur l’hectorite (etude en microscopie et diffraction electroniques). Societe Francais de Mineralogie et Crystallographie Bulletin: 89: 29-40.
  4. 1970Chaussidon, J. (1970) Stretching Frequencies of Structural Hydroxyls of Hectorite and K-Depleted Phlogopite as Influenced by Interlayer Cation and Hydration. Clays and Clay Minerals, 18 (3) 139-149 doi:10.1346/ccmn.1970.0180303DOI: 10.1346/ccmn.1970.0180303
  5. 1987Weiss, C.A., Altaner, S.P., Kirkpatrick, J. (1987) High-resolution 29Si NMR spectroscopy of 2:1 layer silicates: Correlations among chemical shift, structural distortions, and chemical variations. American Mineralogist: 72: 935-942.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hectorite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hectorite-1841},
  note      = {Accessed 2026-05-11}
}