Where it forms, where it's found
- Geological setting
Alteration product of volcanic tuffs and ash. Late-hydrothermal formation in various rocks.
- Type locality
- Montmorillon
- Vienne
- Nouvelle-Aquitaine
- France
Physical
Optical
- Optical type
- Biaxial (-) · 2V measured = 5 – 30° · 2V calc = 24°
- Refractive index
- 1.485 – 1.55
- Surface relief
- Moderate
- Principal indices
- nα 1.485 – 1.535 · nβ 1.504 – 1.550 · nγ 1.505 – 1.550
- Birefringence
- 0.02
- Pleochroism
- Visible
X= colorless to pale brown, yellow green Y= dark brown to yellow-green, olive-green, pale yellow Z= brown to olive-green, pale yellow
- Dispersion
- none
- UV response
- Usually not fluorescent, except by mixtures with autunite, etc.
- Notes
Usually not pleochroic; pleochroism dependent on chemical substitution
Crystallography
- Space group
- C2/m
- Cell parameters
- a = 5.17 Å · b = 8.94 Å · c = 9.95 Å
- Cell angles
- β = 99.54 °
- Ratio a:b:c
- 1 : 1.729 : 1.925
- Z
- 1
- Morphology
Scaly crystals, clayey, compact, massive
- Type-locality form
Compact earthy massive mineral.
Chemical composition
- Impurities
- Fe
- K
Synonyms
- Amagorsite
- Daunialite
- Fullererde
- Giliabit
- Goumbrine
- Gumbrine
- Montmorijonito
- Stolpenit
- Stolpenite
- Walkerite (of Dana)
- Walkthon
In other languages
- French
- Montmorillonite · Terre de sommière · Terre de Sommières
- German
- Bleicherde · Fullererde · Montmorillonit
- Spanish
- Montmorillonita
- Italian
- montmorillonite
- Portuguese
- montmorillonita · Montmorillonite · Montmorilonita
- Japanese
- モンモリロナイト · モンモリロン石 · 酸性白土
- Chinese
- 蒙脫石 · 蒙脱石
- Traditional Chinese
- 蒙脫石
- Russian
- Монтмориллонит · Наноглина
- Arabic
- المونتموريلونيت · مونتموريلونايت · مونتموريلونيت
Classification
9.EC.40
- 9SilicatesClass
- 9.EPhyllosilicatesDivision
- 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
- 9.EC.40MontmorilloniteSpecies
71.03.1a.02
- 71Phyllosilicates Sheets of Six-membered RingsClass
- 71.03Sheets of 6-membered rings with 2:1 claysType
- 71.03.1a— unnamed intermediate level —Group
- 71.03.1a.02MontmorilloniteSpecies
16.7.9
- 16Silicates Containing Aluminum and other MetalsClass
- 16.7Aluminosilicates of MgGroup
- 16.7.9MontmorilloniteSpecies
Group, growth & confusion
Beidellite(Na,Ca)0.3Al2(Si,Al)4O10(OH)2 · nH2OMineral—
FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3(Si,Al)4O10(OH)2 · 4H2OMineral—
HectoriteNa0.3(Mg,Li)3Si4O10(F,OH)2 · nH2OMineral—
NontroniteNa0.3Fe3+2(Si,Al)4O10(OH)2 · nH2OMineral—- Saliotite(Li,Na)Al3(Si3Al)O10(OH)5Mineral—
Saponite(Ca,Na)0.3(Mg,Fe)3(Si,Al)4O10(OH)2 · 4H2OMineral—
SauconiteNa0.3Zn3(Si,Al)4O10(OH)2 · 4H2OMineral—
Stevensite(Ca,Na)xMg3-ySi4O10(OH)2Mineral—
SwineforditeCa0.2(Li,Al,Mg,Fe)3(Si,Al)4O10(OH,F)2 · nH2OMineral—
VolkonskoiteCa0.3(Cr,Mg)2(Si,Al)4O10(OH)2 · 4H2OMineral—
Literature, links & citation
- 1847Mauduyt, L. (1847) Un mot sur un morceau de quartz d'une variété particulière, ainsi que sur une substance minérale trouvée dans le département de la Vienne. Bulletin de la Société Géologique de France: 4: 168-170.
- 1937Clark, G. L.; Grim, R. E.; Bradley, W. F. (1937) A Study of the Behavior of Montmorillonite upon Wetting. Zeitschrift für Kristallographie, 97 (1-6). 216-222 doi:10.1524/zkri.1937.97.1.216DOI: 10.1524/zkri.1937.97.1.216
- 1938Hofmann, Ulrich; Maegdefrau, Edmund (1938) Die Kristallstruktur des Montmorillonits. Zeitschrift für Kristallographie, 98 (1-6). 299-323 doi:10.1524/zkri.1938.98.1.299DOI: 10.1524/zkri.1938.98.1.299
- 1940Grim, R. E.; Bradley, W. F. (1940) Investigation of the effect of heat on the clay minerals illite and montmorillonite. Journal of the American Ceramic Society, 23 (8). 242-248 doi:10.1111/j.1151-2916.1940.tb14263.xDOI: 10.1111/j.1151-2916.1940.tb14263.x
- 1943Ross, C.S., Hendricks, S.B. (1943) Minerals of the Montmorillonite Group: Their Origin and Relation to Soils and Clays. United States Geological Survey, Professional paper 205-B: 79 pgs.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Montmorillonite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/montmorillonite-2821},
note = {Accessed 2026-05-11}
}



