Montmorillonite

(Na,Ca)0.3(Al,Mg)2Si4O10(OH)2 · nH2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mnt
Discovered
1847
Also known as
  • Amagorsite
  • Daunialite
  • Fullererde
  • +8 more

Where it forms, where it's found

Geological setting

Alteration product of volcanic tuffs and ash. Late-hydrothermal formation in various rocks.

Type locality
Montmorillon
  1. Vienne
  2. Nouvelle-Aquitaine
  3. France
1,511recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White · buff · yellow · green · rarely pale pink to red

Pink to red coloration is due to high valance Mn

Streak
white
Cleavage
Perfect

on (001)

Fracture
Irregular/Uneven
Density
2 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 5 – 30° · 2V calc = 24°
Refractive index
1.485 – 1.55
Surface relief
Moderate
Principal indices
nα 1.485 – 1.535 · nβ 1.504 – 1.550 · nγ 1.505 – 1.550
Birefringence
0.02
Pleochroism
Visible

X= colorless to pale brown, yellow green Y= dark brown to yellow-green, olive-green, pale yellow Z= brown to olive-green, pale yellow

Dispersion
none
UV response
Usually not fluorescent, except by mixtures with autunite, etc.
Notes

Usually not pleochroic; pleochroism dependent on chemical substitution

Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.17 Å · b = 8.94 Å · c = 9.95 Å
Cell angles
β = 99.54 °
Ratio a:b:c
1 : 1.729 : 1.925
Z
1
Morphology

Scaly crystals, clayey, compact, massive

Type-locality form

Compact earthy massive mineral.

Crystal structure

Chemical composition

Impurities
  • Fe
  • K

Synonyms

  • Amagorsite
  • Daunialite
  • Fullererde
  • Giliabit
  • Goumbrine
  • Gumbrine
  • Montmorijonito
  • Stolpenit
  • Stolpenite
  • Walkerite (of Dana)
  • Walkthon

In other languages

French
Montmorillonite · Terre de sommière · Terre de Sommières
German
Bleicherde · Fullererde · Montmorillonit
Spanish
Montmorillonita
Italian
montmorillonite
Portuguese
montmorillonita · Montmorillonite · Montmorilonita
Japanese
モンモリロナイト · モンモリロン石 · 酸性白土
Chinese
蒙脫石 · 蒙脱石
Traditional Chinese
蒙脫石
Russian
Монтмориллонит · Наноглина
Arabic
المونتموريلونيت · مونتموريلونايت · مونتموريلونيت

Classification

Strunz
10th ed.

9.EC.40

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.40MontmorilloniteSpecies
Dana
8th ed.

71.03.1a.02

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.03Sheets of 6-membered rings with 2:1 claysType
  • 71.03.1a— unnamed intermediate level —Group
  • 71.03.1a.02MontmorilloniteSpecies
CIM

16.7.9

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.7Aluminosilicates of MgGroup
  • 16.7.9MontmorilloniteSpecies

Group, growth & confusion

Often grow together
5 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1847Mauduyt, L. (1847) Un mot sur un morceau de quartz d'une variété particulière, ainsi que sur une substance minérale trouvée dans le département de la Vienne. Bulletin de la Société Géologique de France: 4: 168-170.
  2. 1937Clark, G. L.; Grim, R. E.; Bradley, W. F. (1937) A Study of the Behavior of Montmorillonite upon Wetting. Zeitschrift für Kristallographie, 97 (1-6). 216-222 doi:10.1524/zkri.1937.97.1.216DOI: 10.1524/zkri.1937.97.1.216
  3. 1938Hofmann, Ulrich; Maegdefrau, Edmund (1938) Die Kristallstruktur des Montmorillonits. Zeitschrift für Kristallographie, 98 (1-6). 299-323 doi:10.1524/zkri.1938.98.1.299DOI: 10.1524/zkri.1938.98.1.299
  4. 1940Grim, R. E.; Bradley, W. F. (1940) Investigation of the effect of heat on the clay minerals illite and montmorillonite. Journal of the American Ceramic Society, 23 (8). 242-248 doi:10.1111/j.1151-2916.1940.tb14263.xDOI: 10.1111/j.1151-2916.1940.tb14263.x
  5. 1943Ross, C.S., Hendricks, S.B. (1943) Minerals of the Montmorillonite Group: Their Origin and Relation to Soils and Clays. United States Geological Survey, Professional paper 205-B: 79 pgs.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Montmorillonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/montmorillonite-2821},
  note      = {Accessed 2026-05-11}
}