Volkonskoite

Ca0.3(Cr,Mg)2(Si,Al)4O10(OH)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vkn
Discovered
1831
Also known as
  • Volkonskoiet
  • Wolchonskoit
  • Wolchonskoita
  • +1 more

Where it forms, where it's found

Geological setting

Weathering product of serpentine, epigenetic mineral in clastic sedimentary rocks.

Type locality
Efimyatskaya Mt
  1. Efimyata Village
  2. Chastinsky District
  3. Perm Krai
  4. Russia

57.4017°, 54.7467°

22recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Blue-green · dark green · grass-green
Tenacity
brittle
Fracture
Conchoidal
Density
2.11 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 62 – 84°
Refractive index
1.551 – 1.569
Surface relief
Moderate
Principal indices
nα 1.551 – 1.560 · nβ 1.569 · nγ 1.564
Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0085
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]85 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation85 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Morphology

Fine scaly to fibrous, massive.

Comment

Point Group: n.d.; Space Group: n.d. Z = n.d

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
39.32%
14SiSiliconSilicon428.085112.340
17.26%
13AlAluminiumAluminium426.982107.928
16.58%
24CrChromiumChromium251.996103.992
15.97%
12MgMagnesiumMagnesium224.30548.610
7.47%
20CaCalciumCalcium0.340.07812.023
1.85%
1HHydrogenHydrogen101.00810.080
1.55%
Total650.957100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Mn
  • Na
  • K
  • C
  • P

Synonyms

  • Volkonskoiet
  • Wolchonskoit
  • Wolchonskoita
  • Wolchonskoite

In other languages

German
Volkonskoit · Wolchonskoit
Spanish
Volkonskoíta
Italian
Volkonskoite
Chinese
铬绿脱石
Russian
волконскоит · гекторит · монтмориллонит хромистый

Classification

Strunz
10th ed.

9.EC.40

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.40VolkonskoiteSpecies
Dana
8th ed.

71.03.1a.04

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.03Sheets of 6-membered rings with 2:1 claysType
  • 71.03.1a— unnamed intermediate level —Group
  • 71.03.1a.04VolkonskoiteSpecies
CIM

16.15.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.15Aluminosilicates of V and CrGroup
  • 16.15.6VolkonskoiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1831Kämmerer, A. (1831) Mittheilungen an den Geheimen Rath v. Leonhard gerichtet. Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefaktenkunde: 2: 420-420.
  2. 1987Foord, Eugene E. (1987) Reassessment of the Volkonskoite-Chromian Smectite Nomenclature Problem. Clays and Clay Minerals, 35 (2) 139-149 doi:10.1346/ccmn.1987.0350206DOI: 10.1346/ccmn.1987.0350206
  3. 1988Jambor, John L.; Bladh, Kenneth W.; Ercit, T. Scott; Grice, Joel D.; Grew, Edward S. (1988) New mineral names. American Mineralogist, 73 (7-8). 927-935
  4. 1996Kossovskaya, A.G., Gomon’kov, A.V., Gor’kova, N.V., Shchepetova, Ye.V. (1996) New data on the composition and genesis of volkonskoite. Litologiya i Poleznyye Iskopayemyye: 1996(2): 146–156. (in Russian)
  5. 1997Jambor, J.L., Grew, E.S., Roberts, A.C. (1997) New mineral names. American Mineralogist: 82: 820-823.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Volkonskoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/volkonskoite-4201},
  note      = {Accessed 2026-05-11}
}