Hübnerite

Mn2+(WO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hbr
Also known as
  • Blumit (of Liebe)
  • Huebnerit
  • Huebnerite
  • +5 more

History

Hübnerite carries a man's name, though it has worn two of them. Before it was hübnerite, it was megabasite — the name the German mineralogist A. Breithaupt gave it in 1852.

The name we use today arrived in 1865. Eugene N. Riotte, a German émigré from Elberfeld, described the mineral from veins in Nevada. He named it for Adolph Hübner, a German mining engineer and metallurgist from Freiberg, in Saxony. Riotte first announced the name in an English-language newspaper, which had no umlaut to give. That is why the spelling hubnerite still survives alongside hübnerite today.

The first specimens came from the Erie and Enterprise veins of the Mammoth district, in Nye County, Nevada. From the start, the mineral sat inside a family. Hübnerite is the manganese end of a pair. The same crystal structure can also host iron, and where iron wins out the mineral becomes ferberite instead. The two ends, with every blend between them, make up the wolframite series — long one of the workhorses of tungsten mining.

Industrial & practical applications

Hübnerite is mined for one reason: the tungsten locked inside it. It is counted among the principal ores of tungsten, the dense, hard metal that makes the mineral worth digging for. It is not the only such ore, nor the leading one. Tungsten comes mainly from two minerals — scheelite, a calcium tungstate, and wolframite, the iron–manganese series of which hübnerite is the manganese end. Hübnerite is a real but local contributor, worked where its veins are rich enough to pay.

What the smelter wants is the tungsten itself, and roughly half of all tungsten goes into one material: tungsten carbide. This is the wear-resistant cemented carbide, also called hardmetal — a tungsten-carbon compound bonded with metal that survives where ordinary steel wears away. It arms the cutting tools, drill bits and dies of the metalworking, mining and construction trades.

The rest is spread across metals and electronics. Tungsten hardens high-speed and specialty steels, and goes into superalloys for turbine blades and heavy alloys for armaments and counterweights. Drawn into fine wire, it becomes the electrodes, contacts and filaments of lighting, welding and electronic equipment.

One country dominates the whole chain. China leads the world not only in mining tungsten but in exporting and consuming its products.

Where it forms, where it's found

Geological setting

High-temperature hydrothermal veins and pneumatolytically altered greisens; granite pegmatites and sedimentary alluvial deposits.

Type locality
Erie and Enterprize veins
  1. Ellsworth Mine
  2. Ellsworth
  3. Ellsworth Mining District (Mammoth Mining District)
  4. Nye County
  5. Nevada
  6. USA
473recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous to admantine-submetallic.
Transparency
Transparent · Translucent
Colour
Yellow-brown · reddish-brown · blackish brown · black · red (rare)
Streak
Greenish-grey, yellow to reddish-brown
Tenacity
brittle
Cleavage
Perfect

Perfect on (010)

Fracture
Irregular/Uneven
Density
7.12 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 73° · 2V calc = 73°
Refractive index
2.17 – 2.32
Surface relief
Very high
Principal indices
nα 2.17 – 2.2 · nβ 2.22 · nγ 2.3 – 2.32
Pleochroism
Visible

X = Yellow to green, orange-red Y = Yellowish brown to greenish yellow, red-orange to red Z = Green, brick red to red

Dispersion
relatively strong
Extinction
Orientation: X = b; Z ∧ c = 17°–21°.
Optical colour
White to gray
Anisotropism
Distinct
Internal reflections
Deep blood red
Tropism
Anisotropic
Reflectance R%
(17.1,19.8) 400, (16.3,19.3) 420, (15.5,18.8) 440, (15.1,18.3) 460, (14.6,17.5) 480, (14.4,17.2) 500, (14.2,17.0) 520, (13.9,16.7) 540, (13.8,16.5) 560, (13.7,16.3) 580, (13.6,16.2) 600, (13.5,16.1) 620, (13.5,16.0) 640, (13.4,15.9) 660, (13.4,15.8) 680, (13.3,15.7) 700
Luminescence
Nonfluorescent
Notes

Absorption: Z > Y > X.

Reflected-light panel
14.3 %anisotropic · dual curve
Specimen sRGB 138, 96, 55
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct
Reflected colour
White to gray
Internal reflections
Deep blood red

Crystallography

Crystal system
Monoclinic
Space group
#12
Cell parameters
a = 4.8238(7) Å · b = 5.7504(10) Å · c = 4.9901(8) Å
Cell angles
β = 91.18(1) °
Ratio a:b:c
1 : 1.192 : 1.034
Z
2
Morphology

Crystals commonly prismatic and striated [001]; also tabular, to bladed, flatened (100) and exhibit numerous forms, including (010), (110), (100), (310), (112), (001), (102) and (011). Radiating groups or in parallel configuration.

Twinning

Common as simple contact twins on (100), rarely on (001); as interpenetrant twins, lamellar.

Parting
On (100) and (102)
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
74WTungstenTungsten1183.840183.840
60.72%
8OOxygenOxygen415.99963.996
21.14%
25MnManganeseManganese154.93854.938
18.14%
Total302.774100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Blumit (of Liebe)
  • Huebnerit
  • Huebnerite
  • Manganese tungstate
  • Manganowolframit
  • Manganowolframita
  • Manganowolframite
  • Megabasit

In other languages

French
Hübnérite · Huebnerite · Manganowolframite
German
Hübnerit
Spanish
Hübnerita · Huebnerita
Italian
hübnerite
Japanese
マンガン重石
Chinese
鎢錳礦 · 钨锰矿

Classification

Strunz
10th ed.

4.DB.30

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DBWith medium-sized cations; chains of edge-sharing octahedraGroup
  • 4.DB.30HübneriteSpecies
Dana
8th ed.

48.01.01.01

  • 48Anhydrous Molybdates and TungstatesClass
  • 48.01AXO4Type
  • 48.01.01Wolframite seriesGroup
  • 48.01.01.01HübneriteSpecies
CIM

27.4.13

  • 27Sulphites, Chromates, Molybdates and TungstatesClass
  • 27.4TungstatesGroup
  • 27.4.13HübneriteSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
6 minerals

Literature, links & citation

Citations
  1. NOTE: See also: Wolframite references.
  2. 1852Breithaupt (1852) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig (merged into Glückauf): 11: 189 (as Megabasit).
  3. 1863Liebe (1863) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Heidelberg, Stuttgart: 652 (as Blumit).
  4. 1865Credner (1865) Berg.- und hüttenmännisches Zeitung, Freiberg, Leipzig (merged into Glückauf): 24: 370.
  5. 1865Riotte (1865) Reese River Reveille, Austin, Nevada.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hübnerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hubnerite-1940},
  note      = {Accessed 2026-05-11}
}