Kaolinite

Al2Si2O5(OH)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kln
Also known as

History

The name comes from a hill. Kaolinite — the white clay mineral behind porcelain — is named after Kao-ling, a ridge in southern China that was mined for the raw material for centuries. The Chinese term means "high ridge".

Long before chemists had a name for the mineral itself, the clay it forms was prized for making fine porcelain. The clay took the place name of its source. In 1637 the Chinese scholar Song Yingxing recorded the name for the type locality, Kaoling, meaning high ridge.

The word reached Europe through the porcelain trade. It was borrowed into English in 1727, from the 1712 French reports of the Jesuit missionary François Xavier d'Entrecolles. He had described how the kilns at Jingdezhen made their porcelain. For two centuries "kaolin" named the clay, not a single mineral.

The mineral species itself was formalised later. In 1867 the American chemists Samuel William Johnson and James Manning Blake published On Kaolinite and pholerite in the American Journal of Science, separating the clay's dominant pure mineral and giving it the standard mineralogical name with the -ite suffix. That distinction still holds today: kaolinite is the mineral species; kaolin is the rock — the workable clay, also called china clay — that kaolinite dominates.

Industrial & practical applications

Open a glossy magazine and you are holding kaolinite. About 40 percent of all mined kaolin goes into the filling and coating of paper. As a filler, the clay is mixed into the cellulose fibre and becomes part of the sheet, giving it body, colour, opacity, and printability.
As a coating, it is spread with an adhesive across the paper's surface for gloss, opacity, and sharper printing. For coating, the clay is ground so finely that most particles are under two micrometres across — about a fortieth of the width of a human hair. Coating can make up a quarter of a sheet's weight; filler, about a sixth.

The second great use is ceramics. Kaolin fires white and melts only at high temperatures. That suits it to whiteware — the everyday name for china — along with porcelain and refractories, the heat-resistant materials that line furnaces. In a whiteware body the clay is blended with roughly equal amounts of silica and feldspar, plus a smaller share of a plastic, light-burning clay called ball clay. Kaolin can account for up to half the raw material in a whiteware mix.

The same fine white particles work as a cheap, inert filler elsewhere. Kaolin is mixed into rubber to improve its mechanical strength and resistance to abrasion. In paints it serves as an extender and a flattening agent, the additive that dulls an otherwise glossy finish. It is also a filler in plastics.

Medicine and cosmetics take the purest grades. Kaolin-based preparations are used to treat diarrhea. A kaolinite-derived material is woven into gauze to speed blood clotting. The United States Naval Medical Research Institute reported its successful use this way in 2008. In cosmetics the clay is a filler in facial masks and soap.

Paper, ceramics, and paint dominate the market: in 2016 they took 36, 31, and 7 percent of demand, the rest spread across other uses. Global kaolin production was estimated at about 45 million tonnes in 2021.

Where it forms, where it's found

Geological setting

A primary constiuent of clay beds formed by the decomposition of feldspar-bearing rocks.

Type locality
Gaoling Mine (Kauling Mine)
  1. Gaoling village
  2. Ehu town
  3. Fuliang Co.
  4. Jingdezhen
  5. Jiangxi
  6. China
5,660recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
White to cream and pale-yellow · also often stained various hues · tans and browns being common.
Streak
White, or paler than the sample.
Tenacity
sectile
Cleavage
Perfect

on (001).

Fracture
Irregular/Uneven · Conchoidal · Sub-Conchoidal · Micaceous
Density
2.68 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 24 – 50° · 2V calc = 44°
Refractive index
1.553 – 1.57
Surface relief
Moderate
Principal indices
nα 1.553 – 1.563 · nβ 1.559 – 1.569 · nγ 1.560 – 1.570
Birefringence
0.017
Pleochroism
Non-pleochroic
Dispersion
none
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 5.13 Å · b = 8.89 Å · c = 7.25 Å
Cell angles
α = 90 ° · β = 104.5 ° · γ = 89.8 °
Ratio a:b:c
1 : 1.733 : 1.413
Z
1
Morphology

Visible crystals extremely rare, typically 2-5 nanometer range, but may be up to 1.5 mm across. Platy, pseudohexagonal. Fibers and spheres have been observed using SEM imaging.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
55.78%
14SiSiliconSilicon228.08556.170
21.76%
13AlAluminiumAluminium226.98253.964
20.90%
1HHydrogenHydrogen41.0084.032
1.56%
Total258.157100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mg
  • Na
  • K
  • Ti
  • Ca
  • H2O

Synonyms

  • Ancudit
  • Ancudita
  • Ancudite
  • Cao lanh
  • Carnat
  • Clayite (of Mellor)
  • Cleît
  • Cleîte
  • Collyrinum
  • Collyrum
  • Creniadit
  • Creniadite
  • Fire clay
  • Kaoliini
  • Leucargilla
  • Lohestit
  • Lohestite
  • Marga Porcellana
  • Myelin
  • Neokaolin
  • Pholerit
  • Porcelain Clay
  • Porcelain Earth
  • Porzellanerde

In other languages

French
1318-74-7 · Al2Si2O5(OH)4 · kaolinite
German
Kaolinit
Spanish
caolinita
Italian
caolinite · Kaolinite
Portuguese
Caulinita · caulinite
Japanese
カオリナイト · カオリン石 · 高陵土 · 高陵石
Chinese
瓷土 · 觀音土 · 观音土 · 高岭土 · 高嶺石
Simplified Chinese
高岭石
Traditional Chinese
高嶺石
Russian
каолинит
Arabic
كاؤولين · كاولين · كاولينيت
Hindi
चीनी मिट्टी

Classification

Strunz
10th ed.

9.ED.05

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EDPhyllosilicates with kaolinite layers composed of tetrahedral and octahedral netsGroup
  • 9.ED.05KaoliniteSpecies
CIM

15.8

  • 15Silicates of AluminumClass
  • 15.8— unnamed intermediate level —Group
  • 15.8KaoliniteSpecies

Group, growth & confusion

Often grow together
6 minerals
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. Daou, I., Mocuta, C., Lecomte-Nana, G.L., Tessier-Doyen, N., Peyratout, C., Guinebretière, R., Thiaudière, D. (2023): Dehydroxylation of Kaolinite and Halloysite-Rich Samples: An In Situ Study of the Texture and Structural Evolutions. Minerals, 13, 1418.
  2. 1930Ross, C.S., Kerr, P.F. (1930) The kaolin minerals. USGS Professional Paper 165-E: 151-176.
  3. 1932Gruner, John W. (1932) The Crystal Structure of Kaolinite. Zeitschrift für Kristallographie, 83 (1). 75-88 doi:10.1524/zkri.1932.83.1.75DOI: 10.1524/zkri.1932.83.1.75
  4. 1932Schoep, A. (1932) Sur une forme curieuse de la kaolinite trouvée dans la houille. Bulletin de la Société belge de Géologie, 42, 271.
  5. 1959BRINDLEY, G. W.; NAKAHIRA, M. (1959) The Kaolinite-Mullite Reaction Series: I, A Survey of Outstanding Problems. Journal of the American Ceramic Society, 42 (7). 311-314 doi:10.1111/j.1151-2916.1959.tb14314.xDOI: 10.1111/j.1151-2916.1959.tb14314.x
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kaolinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kaolinite-2156},
  note      = {Accessed 2026-05-11}
}