Löllingite

FeAs2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Also known as
  • Arseneisen
  • Arsenikeisen
  • Arsenosiderit
  • +21 more

History

Löllingite carries the name of a place rather than a person. It was first described in 1845, from a mining district called Lölling in Carinthia, a region of southern Austria, and took its name straight from that ground. The mineralogist credited with the description is Wilhelm Karl von Haidinger, and the original specimens came from the Wolfbau Mine in the Lölling district.

The mineral had a second name in its early years. Mineralogists once called it leucopyrite, a term now treated as an old synonym for löllingite.

Telling löllingite apart from another mineral has shaped its story from the start. It often sits alongside arsenopyrite — an iron mineral that also contains sulfur — and the two are hard to distinguish by eye. Both are steel-grey and metallic. The difference is chemical: löllingite is an iron arsenide, iron bonded to arsenic with no sulfur, while arsenopyrite carries sulfur as well. That hidden distinction is why a careful chemical test, rather than a glance, settled which mineral a given specimen actually was.

Industrial & practical applications

Löllingite is mostly a mineral for the cabinet and the laboratory, not the factory. Collectors prize its bright steel-grey crystals, and mineralogists study it as a textbook iron arsenide. No major industrial use is recorded for it on its own.

Where it does earn attention is underground, in complex cobalt-nickel-arsenic ore deposits. There it keeps company with the metals miners actually want. Such deposits are worked in Sweden, Ontario, Morocco, Norway and Germany. When minerals of the löllingite group form from hot mineral-laden water, they can take up traces of other metals — including so-called "invisible" gold. That is gold spread so finely through the crystal that no glint reveals it.

One practical note outweighs all of this for anyone handling a specimen. Löllingite is an arsenide, built around arsenic, so its dust and any residue should be treated with care and the hands washed after contact.

Where it forms, where it's found

Type locality
Wolf mine
  1. Lölling mining district
  2. Hüttenberger Erzberg
  3. Hüttenberg
  4. Sankt Veit an der Glan District
  5. Carinthia
  6. Austria
781recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Steel gray to silver white
Streak
Greyish black
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (010)(101)

Fracture
Sub-Conchoidal
Density
7.43 g/cm³

Optical

Anisotropism
Strong
Tropism
Anisotropic
Reflectance R%
(51.6,59.7) 400, (52.0,59.9) 420, (52.6,59.8) 440, (53.1,58.8) 460, (53.7,57.6) 480, (54.2,56.2) 500, (54.8,54.9) 520, (55.4,53.7) 540, (55.9,52.7) 560, (56.3,51.8) 580, (56.3,51.1) 600, (55.9,50.4) 620, (55.2,49.8) 640, (54.5,49.3) 660, (53.6,48.7) 680, (53.1,48.4) 700
UV response
Not fluorescent in ultraviolet light
Reflected-light panel
54.3 %anisotropic · dual curve
Specimen sRGB 255, 182, 98
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong

Crystallography

Crystal system
Orthorhombic
Space group
#73
Cell parameters
a = 5.300 Å · b = 5.983 Å · c = 2.882 Å
Ratio a:b:c
1 : 1.129 : 0.544
Z
2
Morphology

Prismatic, may be very similar to arsenopyrite.

Twinning

On (001), possibly trillings, polysynthetic on (101)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
72.85%
26FeIronIron155.84555.845
27.15%
Total205.689100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Bi

Synonyms

  • Arseneisen
  • Arsenikeisen
  • Arsenosiderit
  • Arsenosiderite
  • Asenosiderit
  • Asenosiderite
  • Axotomer Arsenikkies
  • Hüttenbergit
  • Hüttenbergite
  • Leucopurit
  • Leucopyrit
  • Leucopyrite
  • Leukopyrit
  • Loellingit
  • Loellingite
  • Mohsin
  • Mohsine
  • Pharmakopyrit
  • Pharmakopyrite
  • Prismatischer Arsenikalkies
  • Saetersbergit
  • Saetersbergite
  • Sätersbergit
  • Sätersbergite

In other languages

French
Arsenokrokit · Arsénosidérite · Geyérite · Guerite · Hüttenbergite · Leucopurite · Loellingite · Löllingite · Pharmakopyrite · Saetersbergite · Sätersbergite
German
Arseneisen · Eisenarsenid · Glaukopyrit · Löllingit
Spanish
Lollingita
Italian
Löllingite
Japanese
砒鉄鉱
Chinese
斜方砷铁矿
Russian
Лёллингит · Мышьяковистый колчедан
Arabic
لولينغيت

Classification

Strunz
10th ed.

2.EB.15a

  • 2Sulfides and SulfosaltsClass
  • 2.EMetal Sulfides, M: S <= 1:2Division
  • 2.EBM:S = 1:2, with Fe, Co, Ni, PGE, etc.Group
  • 2.EB.15aLöllingiteSpecies
Dana
8th ed.

02.12.02.09

  • 02SulfidesClass
  • 02.12AmBnXp, with (m+n):p = 1:2Type
  • 02.12.02Marcasite Group (Orthorhombic: Pnnm)Group
  • 02.12.02.09LöllingiteSpecies
CIM

3.9.11

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.9Sulphides etc. of FeGroup
  • 3.9.11LöllingiteSpecies

Group, growth & confusion

In the same group
11 members
Often grow together
4 minerals

Literature, links & citation

Citations
  1. Zeitschrift für Kristallographie: 32: 165-187.
  2. 1845Haidinger, W. (1845) Zweite Klasse: Geogenide. XIII. Ordnung. Kiese II. Arsenikkies. Lölingit.. in Handbuch der Bestimmenden Mineralogie, Bei Braumüller and Seidel (Wien): 559-562.
  3. 1884Hillebrand, W.F. (1884) On an interesting variety of löllingite and other minerals. American Journal of Science: 27: 343-358.
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1962Clark, Lloyd A. (1962) X-ray method for rapid determination of sulphur and cobalt in loellingite. The Canadian Mineralogist, 7 (2). 306-311
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Löllingite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lollingite-2426},
  note      = {Accessed 2026-05-11}
}