Marcasite

FeS2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mrc
Discovered
1845
Also known as
  • Alasanit
  • Alasanita
  • Alasanite
  • +25 more

History

For most of its written life, the word marcasite did not mean what it means now. It was a catch-all for any pale brassy iron sulfide a miner dug out of the ground. The modern, narrower definition arrived late — only in 1845.

The word itself comes from Arabic. In medieval and early-modern Europe, it was applied indiscriminately to pyrite and other metallic bronze-coloured minerals. Pyrite and marcasite were, for most readers and writers of the time, the same thing under different lights.

The confusion runs through the surviving sources. In 1665, Walter Pope described "marcasites" in the mercury ores of the Idria Mine, in the Julian Alps of what is now Slovenia. The mine did contain both minerals — metallic golden specks of marcasite alongside golden pyrite — but Pope had no way to tell them apart. Over a century later, in 1771, Johnathan Hill was still using marcasite as a loose term for any massive pyrites or mundic.

The split came from Wilhelm Karl von Haidinger, who in 1845 fixed marcasite to one specific mineral: the orthorhombic polymorph of iron disulfide (FeS₂). Orthorhombic means built on three perpendicular axes of unequal length — a different scaffold from pyrite's cube. Same atoms, different shape.

The old meaning never quite died. The Victorian and Edwardian fashion for marcasite jewellery — small faceted stones set in mourning brooches and rings — predates Haidinger's definition. It uses the older sense of the word: the pale brassy gems in those pieces are almost always pyrite. True marcasite is too brittle to cut and too unstable to wear. Specimens in mineral cabinets are notorious for falling apart over time. The sulfur oxidises in damp air and combines with water to produce iron sulfate and sulfuric acid.

Industrial & practical applications

Marcasite has no significant industrial use today. The same instability that makes specimens crumble in mineral cabinets rules it out of any application that requires it to last. In moist air, the sulfur oxidises and combines with water to produce iron sulfate and sulfuric acid. Storage below 60 percent humidity slows the reaction but does not stop it.

Where pyrite, its cubic cousin with the same FeS₂ formula, finds a handful of niche uses, marcasite stays on the shelf. Demand comes from mineral collectors and museums, drawn to the distinctive cockscomb and spear-shaped crystal habits marcasite produces.

Where it forms, where it's found

Geological setting

Most frequently found in sedimentary rocks and coal beds, as a replacement mineral forming fossils, it is a mineral of low-temperature, near-surface, environments, forming from acid solutions. Pyrite, the more stable form of FeS2, forms under conditions of higher temperatures and lower acidity or alkaline environments.

5,785recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789106 – 6.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Pale brass-yellow · tin-white on fresh exposures.
Streak
Dark-gray to black.
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (101). (110) in traces.

Fracture
Conchoidal · Sub-Conchoidal
Density
4.887 g/cm³

Optical

Pleochroism
Strong

Creamy white, light yellowish white, white with rose-brown tint.

Anisotropism
Strong yellow to light green to dark green
Tropism
Anisotropic
Reflectance R%
(40.4,44.5) 400, (41.9,45.4) 420, (43.4,47.3) 440, (44.3,50.1) 460, (45.2,52.8) 480, (46.3,54.8) 500, (47.7,56.1) 520, (48.9,56.3) 540, (49.5,55.9) 560, (49.6,55.2) 580, (49.5,54.8) 600, (49.2,54.8) 620, (48.7,53.8) 640, (47.9,52.9) 660, (47.2,51.9) 680, (46.6,51.2) 700
UV response
Not fluorescent in ultraviolet light
Reflected-light panel
46.6 %anisotropic · dual curve
Specimen sRGB 247, 172, 89
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong yellow to light green to dark green

Crystallography

Crystal system
Orthorhombic
Space group
Pnnm
Cell parameters
a = 4.436 Å · b = 5.414 Å · c = 3.381 Å
Ratio a:b:c
1 : 1.220 : 0.762
Z
2
Morphology

Crystals usually tabular on (010), also pyramidal, faces often curved, frequently twinned; also stalactic, globular, or reniform with radiating internal structure.

Twinning

Common on (101), forming "swallowtail" contact twins; this may be repeated to form stellate fivelings. Less common on (011).

Epitaxy

Twinned prismatic marcasite crystals attached along pyrite octahedron edges from Rensselaer, Indiana (Brock and Slater, 1978). See also Rakovan et al. (1995).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur232.06064.120
53.45%
26FeIronIron155.84555.845
46.55%
Total119.965100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • As

Synonyms

  • Alasanit
  • Alasanita
  • Alasanite
  • Alazanit
  • Alazanita
  • Alazanite
  • Binarit
  • Binarita
  • Binarite
  • Binärkies
  • Hydropyrit
  • Hydropyrita
  • Hydropyrite
  • Kammkies
  • Lamellar pyrite
  • Lebererz (of Agricola)
  • Markasite
  • Maxy
  • Pirita Blanca
  • Poliopyrites
  • Prismatic Iron Pyrites
  • Radiated Pyrites
  • Spear Pyrites
  • Speerkies
  • Sperchise
  • Strahlkies
  • Weicheisenkies
  • Weisserkies

In other languages

French
Alasanite · Binarite · Binarkies · Cyrosite · Hydropyrite · Kausimkies · Kyrosite · Lonchandite · Marcasite · marcassite · Métalonchidite · Poliopyrites · Pyrite blanche · Pyrite crêtée · Pyrite lamelleuse · Pyrite rhomboïdale · Sperkise
German
Markasit
Spanish
marcasita · margajita · nicoya
Italian
marcasite
Portuguese
marcassita · Marcassite
Japanese
白鉄鉱
Chinese
白铁矿
Simplified Chinese
白铁矿
Traditional Chinese
白鐵礦
Russian
Лучистый колчедан · Марказит
Arabic
مرقشيت

Classification

Strunz
10th ed.

2.EB.10a

  • 2Sulfides and SulfosaltsClass
  • 2.EMetal Sulfides, M: S <= 1:2Division
  • 2.EBM:S = 1:2, with Fe, Co, Ni, PGE, etc.Group
  • 2.EB.10aMarcasiteSpecies
Dana
8th ed.

02.12.02.01

  • 02SulfidesClass
  • 02.12AmBnXp, with (m+n):p = 1:2Type
  • 02.12.02Marcasite Group (Orthorhombic: Pnnm)Group
  • 02.12.02.01MarcasiteSpecies
CIM

3.9.4

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.9Sulphides etc. of FeGroup
  • 3.9.4MarcasiteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
21 minerals
Commonly confused with
4 minerals

Literature, links & citation

Citations
  1. 1665Pope, Walter (1665) Extract of a letter, lately written from Venice by the learned Doctor Walter Pope, to the Reverend Dean of Rippon, Doctor John Wilkins, concerning the mines of mercury in Friuli; and a way of producing wind by the fall of water: Philosophical Transactions: May 30, 1665: 1(2): 21-26.
  2. 1931Buerger, M. J. (1931) The crystal structure of marcasite. American Mineralogist, 16 (9) 361-395
  3. 1932Bannister, F. A. (1932) The distinction of pyrite from marcasite in nodular growths. Mineralogical Magazine and Journal of the Mineralogical Society, 23 (138) 179-187 doi:10.1180/minmag.1932.023.138.04 DOI: 10.1180/minmag.1932.023.138.04
  4. 1934Buerger, M. J. (1934) The pyrite-marcasite relation. American Mineralogist, 19 (2) 37-61
  5. 1937Buerger, M. J. (1937) A common orientation and a classification for crystals based upon a marcasite-like packing. American Mineralogist, 22 (1) 48-56
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Marcasite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/marcasite-2571},
  note      = {Accessed 2026-05-11}
}