Dolomite

CaMg(CO3)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dol
Discovered
1791
Also known as
  • Bitterkalk
  • Bittersalzerde
  • Bitterspat (of Klaproth)
  • +33 more

History

The mountains came after the mineral. The Dolomite Mountains in northern Italy take their name from a pale carbonate rock first described in 1791. The rock was named after the man who studied it: the French geologist Déodat de Dolomieu.

A study of the Alps in 1789 and 1790 brought him to the carbonate stone that would carry his name. He had encountered it first in the buildings of old Rome, and later as samples collected in the Tyrolean Alps. The Genevan chemist Nicolas-Théodore de Saussure formally named it dolomite the following year. Some accounts place the formal naming a few months later, in March 1792.

Industrial & practical applications

In construction, dolomite is cut into ornamental stone and crushed into concrete aggregate. Where calcite limestone is uncommon or too costly, dolomite is sometimes used in its place. It serves there as a flux — material that helps the metal melt cleanly — for the smelting of iron and steel.

Industrial chemistry takes dolomite for the magnesium inside it. Calcined — heated until its carbonates break down — dolomite yields magnesium oxide. The same calcined ore feeds the Pidgeon process for the production of magnesium. It is also a source of magnesium for pharmaceutical applications. Large quantities of processed dolomite go into the production of float glass. That is the smooth, planar window glass made by floating molten glass on a bath of tin.

Agriculture and environmental care turn to dolomite for its slow release of magnesium and its buffering effect on acid soils. Dolomite and dolomitic limestone are added to soils and soilless potting mixes as a pH buffer and as a magnesium source. Pastures can be limed with dolomitic lime to raise their pH and to remedy magnesium deficiency. The same lime is used in environmental restoration and soil regeneration, raising pH in soils acidified by mining. Marine aquaria use dolomite gravel as a substrate that buffers the water against pH swings.

Two more roles round the list out. As a host rock, dolomite is an important petroleum reservoir. It also hosts the strata-bound Mississippi Valley-Type ore deposits — layered seams of lead, zinc, and copper inside carbonate rocks. As a high-temperature catalyst, calcined dolomite destroys tar in the gasification of biomass. That is the heating of wood, agricultural waste, or other plant matter to extract a fuel gas.

Where it forms, where it's found

Geological setting

An important sedimentary and metamorphic mineral found as the principal mineral in dolostones and metadolostones, and as an important mineral in limestones and marbles where calcite is the principal mineral present. Also found as a hydrothermal vein mineral, forming crystals in cavities; and found in serpentinites and similar rocks.

10,428recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colourless · white · gray · reddish-white · brownish-white · green (rarely) · or pink · colourless in transmitted light
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (1011).

Fracture
Sub-Conchoidal
Density
2.84 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.5 – 1.681
Surface relief
Moderate
Principal indices
nω 1.679 – 1.681 · nε 1.500 – 1.503
Birefringence
0.179
Extinction
Parallel
Luminescence
None
UV response
Some types fluoresce white, blue white, creamy yellow, etc. in either SW or LW UV. Manganoan varieties may fluoresce pale pink through intense red, but weaker in long wave.
Notes

Anomalously biaxial.

Michel-Lévy diagramhighlighted lineδ = 0.1790
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1790 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1790 nm
Order4th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
R-3
Cell parameters
a = 4.8012(1) Å · c = 16.002 Å
Z
3
Morphology

Crystals typically rhombohedral with (1011) or (4041) dominant, may also be prismatic (1120) terminated by rhombohedral faces; tabular (0001) with (1120); (1011) often striated horizontally or curved - "saddle" or "fingernail" habit. Also massive, coarse to fine granular, fibrous or pisolitic.

Twinning

On (0001), common with re-entrant angles around the middle edges; on (1010) common; on (1120), common, as complementary twins simulating holohedral symmetry; also as double twins by combination of this law and twins on (1010) or (0001). On (1011), rare. On (0221) as lamellae, especially in grains of dolomite marble.

Parting
Noted in lamellar twins on (0221). Twin gliding on (0221);
Translation gliding
translation gliding with T(0001), t[10_10].
Epitaxy

Growths of dolomite on calcite or vice versa, with parallel axes; also dolomite on rhodochrosite or siderite. Also occurs in oriented growths with antigorite (uncertain), and with chlorite [(0001) and (001) parallel].

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
52.06%
20CaCalciumCalcium140.07840.078
21.73%
12MgMagnesiumMagnesium124.30524.305
13.18%
6CCarbonCarbon212.01124.022
13.03%
Total184.399100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Co
  • Pb
  • Zn

Synonyms

  • Bitterkalk
  • Bittersalzerde
  • Bitterspat (of Klaproth)
  • Chaux carbonatée aluminifère
  • Compound Spar
  • Dolomie
  • Kalktalkspath
  • Kohlensauere Kalkerde
  • Magnesio-Calcite
  • Magnesiocalcit
  • Magnesiodolomit
  • Magnesiodolomita
  • Magnesiodolomite
  • Miemit
  • Miemita
  • Miemite
  • Muricalcit
  • Muricalcita
  • Muricalcite
  • Paratomes Kalk-Haloid
  • Pearl Spar
  • Perlspath
  • Picrite (of Brogniart)
  • Rauhkalk
  • Rautenspath
  • Rhomb Spar
  • Rhombenspat
  • Rhomboidalspath
  • Ridolfit
  • Ridolphite
  • Spath magnésien
  • Spath perlé
  • Taraspit
  • Taraspita
  • Tharandite
  • Wandstein

In other languages

French
brossite · CaMg(CO3)2 · chaux carbonatée magnésifère · dolomite · dolomite zincifère · magnésiodolomite · manganodolomite · miémite · plumbodolomite · protodolomite · sidérocalcite · spath magnésien · spath perlé · tharandite
German
Dolomit · Dolomitspat · Perlspat · Rautenspat
Spanish
dolomita
Italian
dolomite
Portuguese
dolomita · Dolomite
Japanese
ドロマイト · 白雲石 · 苦灰石
Chinese
白云石
Simplified Chinese
白云石
Traditional Chinese
白雲石
Russian
доломит · доломиты
Arabic
دولومايت · دولوميت · صخر الدولومايت · صخور الدولوميت
Hindi
डोलोमाइट

Classification

Strunz
10th ed.

5.AB.10

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.10DolomiteSpecies
Dana
8th ed.

14.02.01.01

  • 14Anhydrous Normal CarbonatesClass
  • 14.02AB(XO3)2Type
  • 14.02.01Dolomite Group (Trigonal: R-3)Group
  • 14.02.01.01DolomiteSpecies
CIM

11.4.6

  • 11CarbonatesClass
  • 11.4Carbonates of CaGroup
  • 11.4.6DolomiteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1792Delamétherie, J.C. (1792) New Edition of Mongez’s Sciagraphie (French translation of Bergmann’s Sciagraphia, with additions). 2 volumes, Paris: 1: 207 (as Spath magnésien).
  2. 1792Saussure, H. B. (1792, March) Observations et Mémoires sur la Physique, sur l'Histoire Naturelle et sur les Arts Vol. 40. Académie royale des sciences p.161-173.
  3. 1794Richard Kirwan (1794) Elements of Mineralogy - second edition Vol. 1. P. Elmsly, The Strand.
  4. 1802Klaproth, M. H. (1802) CX. Untenuchung des Miemits. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.292-296.
  5. 1812William Hyde Wollaston (1812) VIII. On the primitive crystals of carbonate of lime, bitter-spar, and iron-spar. Philosophical Transactions Of The Royal Society Of London, 102. 159-162 doi:10.1098/rstl.1812.0010DOI: 10.1098/rstl.1812.0010
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dolomite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dolomite-1304},
  note      = {Accessed 2026-05-11}
}