Natrolite

Na2(Si3Al2)O10 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ntr
Discovered
1803
Also known as
  • Apoanalcit
  • Apoanalcite
  • Ædelite (of Kirwan)
  • +23 more

History

Heat a small crystal of natrolite and a wisp of steam rises from the stone. That trick gave the whole family its name half a century before natrolite got its own.

In 1756 the Swedish mineralogist Axel Fredrik Cronstedt found that a fibrous mineral he was studying released a surprising amount of water when heated. He coined the term zeolite from the Greek roots for to boil and stone — a stone that boils. Natrolite is the textbook example of that behaviour: water sits loosely inside its open crystal framework and leaves when the temperature rises.

The mineral itself was named in 1803 by the German chemist Martin Heinrich Klaproth. He noticed the high sodium content of a sample from Hohentwiel, in the Hegau region of southern Germany, and built the name from natron — the old word for soda — and the same Greek lithos for stone. Mineralogists sometimes also call it needle stone or needle-zeolite, after the long slender form the crystals usually take.

One footnote of confusion: in 1812 the English chemist William Hyde Wollaston used the same name natrolite for a soda-bearing variety of scapolite. That second usage did not stick, and the name now belongs to Klaproth's zeolite alone.

Industrial & practical applications

Most of the world's zeolite work happens inside synthetic crystals grown in factories, not in mined natural ones. Natrolite is no exception. Its main modern footprint is in laboratories and in collectors' cabinets, not on production lines.

Its standout contribution sits in the history of chemistry. Natrolite was one of the first zeolites in which cation exchange was observed — the ability of the crystal to swap one sodium ion in its framework for a calcium or potassium ion from a passing solution, and back again. That property is the basis of every modern water softener and of much of industrial catalysis. The mineral does also see direct use as a softener, removing the calcium and magnesium that make water hard.

Beyond that the picture thins. Most commercially available natural zeolites belong to the mordenite, clinoptilolite or analcime families — not to natrolite. The mineral is mined in no notable quantity. Demand for it comes mainly from collectors, who prize the slender radiating sprays that grow inside basalt cavities, and from researchers who use its open structure as a model system for studying how cations move through silicate frameworks.

Where it forms, where it's found

Geological setting

Cavities in amygdaloidal basalts

Type locality
Hohentwiel
  1. Singen
  2. Konstanz
  3. Freiburg Region
  4. Baden-Württemberg
  5. Germany

47.7656°, 8.8194°

1,245recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White · colorless · red · yellow · brown · green · bluish
Streak
White
Tenacity
brittle
Cleavage
Perfect

on (110)

Fracture
Irregular/Uneven
Density
2.2 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58 – 64° · 2V calc = 48 – 62°
Refractive index
1.473 – 1.496
Surface relief
Low
Principal indices
nα 1.473 – 1.483 · nβ 1.476 – 1.486 · nγ 1.485 – 1.496
Dispersion
r < v weak
Extinction
X = a; Y = b; Z = c.
UV response
Commonly orange to yellow.
Michel-Lévy diagramhighlighted lineδ = 0.0125
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]125 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation125 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#23
Cell parameters
a = 18.2930(2) Å · b = 18.6430(5) Å · c = 6.5860(5) Å
Ratio a:b:c
1 : 1.019 : 0.360
Z
8
Morphology

Crystals short to long prismatic. From hairlike up to 1 meter in length and 10 cm wide. Common forms: (110), (100), (010), (111), (101), (331), (551) Other forms: (001), (610), (310), (740), (590), (120), (301), (601), (031), (221), (511), (311), (131), (391) and more.

Twinning

On (110), (011), (031).

Parting
on (010)
Comment

Data for chemically pure natrolite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
50.50%
14SiSiliconSilicon328.08584.255
22.16%
13AlAluminiumAluminium226.98253.964
14.19%
11NaSodiumSodium222.99045.980
12.09%
1HHydrogenHydrogen41.0084.032
1.06%
Total380.219100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • K

Synonyms

  • Ædelite (of Kirwan)
  • Apoanalcit
  • Apoanalcite
  • Brevicit
  • Cockalit
  • Cockalite
  • Crocalit
  • Crocalita
  • Crocalite
  • Epinatrolita
  • Epinatrolite
  • Epinatrolith
  • Höganit
  • Laubanite
  • Laubannite
  • Lehuntit
  • Lehuntite
  • Natrium-Mesotyp
  • Natronite (of ?)
  • Needlestone
  • Paleo-natrolith
  • Pink Larimar
  • Portite
  • Radiolite
  • Radyolith
  • Rhodatrolite

In other languages

French
Apoanalcite · Brevicite · Chondrikite · Crocalite · Édelite · Épimatrolite · Hösruite · Lehuntite · Mésotype · Mooraboolite · Natrolite · Savite · Zéolithe farineuse
German
Laubanit · Natrolith
Spanish
natrolita
Italian
natrolite
Japanese
ソーダ沸石
Chinese
鈉沸石 · 钠沸石
Simplified Chinese
钠沸石
Russian
Бергманит · Бергманнит · Мезотип · Натролит · Фаргит

Classification

Strunz
10th ed.

9.GA.05

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GAZeolites with T5O10 Units – The Fibrous ZeolitesGroup
  • 9.GA.05NatroliteSpecies
Dana
8th ed.

77.01.05.01

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.05Natrolite and related speciesGroup
  • 77.01.05.01NatroliteSpecies
CIM

16.2.5

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.2Aluminosilicates of NaGroup
  • 16.2.5NatroliteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1810Klaproth, M. H. (1810) CLXXIX. Chemische Untersuchung des Natroliths. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 5. Rottmann. p.44-49.
  2. 1916Phillips, Alexander H. (1916) Some new forms of natrolite. American Journal Of Science, S. 4 Vol. 42. 472-474
  3. 1932Hey, Max H. (1932) Studies on the zeolites. Part III. Natrolite and metanatrolite. Mineralogical Magazine, 23 (139) 243-289 doi:10.1180/minmag.1932.023.139.04 DOI: 10.1180/minmag.1932.023.139.04
  4. 1942Murdoch, Joseph (1942) Crystallographic notes: cristobalite, stephanite, natrolite. American Mineralogist, 27 (7) 500-506
  5. 1955Peng, C. J. (1955) Thermal analysis study of the natrolite group. American Mineralogist, 40 (9-10) 834-856
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrolite-2947},
  note      = {Accessed 2026-05-11}
}