Niocalite

Ca7Nb(Si2O7)2O3F
IMA status
  • Approved
  • Grandfathered
IMA symbol
Nio
Discovered
1956

Where it forms, where it's found

Type locality
Bond zone
  1. Oka
  2. Deux-Montagnes RCM
  3. Laurentides
  4. Québec
  5. Canada

45.5000°, -74.0469°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Lemon-yellow · colourless in transmitted light
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
3.32 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 56° · 2V calc = 64 – 66°
Refractive index
1.7 – 1.73
Surface relief
High
Principal indices
nα 1.700 – 1.701 · nβ 1.714 – 1.721 · nγ 1.72 – 1.73
Dispersion
r > v strong
Michel-Lévy diagramhighlighted lineδ = 0.0245
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]245 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation245 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.863(3) Å · b = 10.431(3) Å · c = 7.370(2) Å
Cell angles
β = 110.1(1) °
Ratio a:b:c
1 : 0.960 : 0.678
Z
2
Morphology

Crystals prismatic with square cross sections and curved faces. Larger crystals are tapered at both ends.

Twinning

Twinning fine, with (001) as the composition plane.

Type-locality form

Coarse-grained strontian carbonatite.

Comment

Space Group: Pa:

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium740.078280.546
36.12%
8OOxygenOxygen1715.999271.983
35.01%
14SiSiliconSilicon428.085112.340
14.46%
41NbNiobiumNiobium192.90692.906
11.96%
9FFluorineFluorine118.99818.998
2.45%
Total776.773100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Zr
  • Al
  • Y
  • Fe
  • Ta
  • Mn
  • MgNa
  • K
  • P
  • H2O

In other languages

German
Niocalit
Italian
Niocalite

Classification

Strunz
10th ed.

9.BE.17

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.17NiocaliteSpecies
Dana
8th ed.

56.02.04.06

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.04Cuspidine - Wohlerite groupGroup
  • 56.02.04.06NiocaliteSpecies
CIM

17.8.4

  • 17Silicates Containing other AnionsClass
  • 17.8Silicates with niobate or tantalateGroup
  • 17.8.4NiocaliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1956Nickel, E. H. (1956) Niocalite; a new calcium niobium silicate mineral. American Mineralogist, 41 (9-10). 785-786
  2. 1958Nickel, E. H., Rowland, J. F., Maxwell, J. A. (1958) The composition and crystallography of niocalite. The Canadian Mineralogist, 6 (2) 264-272
  3. 1982Mellini, M. (1982) Niocalite revised: Twinning and crystal structure. TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, 30 (4). 249-266 doi:10.1007/bf01087171DOI: 10.1007/bf01087171
  4. 2001(2001) Niocalite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2004Mitchell, R. H., Belton, F. (2004) Niocalite-cuspidine solid solution and manganoan monticellite from natrocarbonatite, Oldoinyo Lengai, Tanzania. Mineralogical Magazine, 68 (5) 787-799 doi:10.1180/0026461046850219DOI: 10.1180/0026461046850219
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Niocalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/niocalite-2913},
  note      = {Accessed 2026-05-11}
}