Plumbojarosite

Pb0.5Fe3+3(SO4)2(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pjrs
Discovered
1902
Also known as
  • Lead Jarosite
  • Pb-Jarosite
  • Plumbojarosiet
  • +1 more

Where it forms, where it's found

Geological setting

A secondary mineral found in the oxidized zones of lead mineral deposits, particularly in arid regions.

Type locality
Cookes Peak Mining District
  1. Luna County
  2. New Mexico
  3. USA
512recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Golden-brown to dark-brown · dark brown-red · blackish
Streak
Pale yellow
Tenacity
fragile
Cleavage
Imperfect/Fair

Fair on (1014).

Fracture
Micaceous
Density
3.665 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.783 – 1.878
Surface relief
Very high
Principal indices
nω 1.878 · nε 1.783
Pleochroism

Dichroic: O = Yellow-brown E = Nearly colourless

Michel-Lévy diagramhighlighted lineδ = 0.0950
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]950 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation950 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 7.305 Å · c = 33.675 Å
Z
3
Morphology

crusts, lumps or compact masses composed of microscopic hexagonal plates; may be pulverant, earthy, or ocherous. The presence of Pb2+ results in the "c" axis of the hexagonal cell being doubled in comparison to jarosite, with half the Pb sites vacant in an orderly arrangement; and this also results in other minor compensating differences from the jarosite structure.

Comment

c may be halved due to impurity contents

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
39.62%
26FeIronIron355.845167.535
29.64%
82PbLeadLead0.5207.200103.600
18.33%
16SSulfurSulfur232.06064.120
11.34%
1HHydrogenHydrogen61.0086.048
1.07%
Total565.289100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Lead Jarosite
  • Pb-Jarosite
  • Plumbojarosiet
  • Vegasite

In other languages

German
Plumbojarosit
Italian
Plumbojarosite

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10PlumbojarositeSpecies
Dana
8th ed.

30.02.05.06

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.05Alunite Group (Jarosite Subgroup)Group
  • 30.02.05.06PlumbojarositeSpecies
CIM

25.7.13

  • 25SulphatesClass
  • 25.7Sulphates of PbGroup
  • 25.7.13PlumbojarositeSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1902Hillebrand, W.F., Penfield, S.L. (1902) Some additions to the alunite-jarosite group of minerals. American Journal of Science: 164: 211-220.
  2. 1910Hillebrand, W.F., Wright, F.E. (1910) A new occurrence of plumbojarosite. American Journal of Science: 30: 191-192.
  3. 1911Butler, B.S., Schaller, W.T. (1911) Some minerals from Beaver County, Utah. American Journal of Science: 32: 418-424.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1937Hendricks, Sterling B. (1937) The crystal structure of alunite and the jarosites. American Mineralogist, 22 (6) 773-784
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Plumbojarosite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/plumbojarosite-3248},
  note      = {Accessed 2026-05-11}
}