Wairakite

Ca(Si4Al2)O12 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wrk
Discovered
1955
Also known as
  • Calcium-Analcime
  • Wairakiet

Where it forms, where it's found

Geological setting

rocks in geothermal areas

Type locality
Wairakei geothermal area (Craters of the Moon)
  1. Wairakei
  2. Taupo District
  3. Waikato Region
  4. New Zealand

-38.6435°, 176.0690°

69recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless to white
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on the (100)

Fracture
Conchoidal
Density
2.26 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 70 – 105°
Refractive index
1.498 – 1.502
Surface relief
Moderate
Principal indices
nα 1.498 · nγ 1.502
Dispersion
very weak
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#11
Cell parameters
a = 13.692(3) Å · b = 13.643(3) Å · c = 13.560(3) Å
Cell angles
β = 90.5(1) °
Ratio a:b:c
1 : 0.996 : 0.990
Z
8
Twinning

Lamellar on (110), common

Parting
Two sets of possible partings intersecting at 90 degrees
Comment

Space-group setting I2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
51.56%
14SiSiliconSilicon428.085112.340
25.86%
13AlAluminiumAluminium226.98253.964
12.42%
20CaCalciumCalcium140.07840.078
9.23%
1HHydrogenHydrogen41.0084.032
0.93%
Total434.400100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mg
  • Sr
  • Na
  • K
  • Cs

Synonyms

  • Calcium-Analcime
  • Wairakiet

In other languages

German
Wairakit
Spanish
Wairakita
Italian
Wairakite

Classification

Strunz
10th ed.

9.GB.05

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GBChains of single connected 4-membered ringsGroup
  • 9.GB.05WairakiteSpecies
Dana
8th ed.

77.01.01.03

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.01Analcime and related speciesGroup
  • 77.01.01.03WairakiteSpecies
CIM

16.9.20

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.9Aluminosilicates of CaGroup
  • 16.9.20WairakiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1955Steiner, A. (1955) Wairakite, the calcium analogue of analcime, a new zeolite mineral. Mineralogical Magazine and Journal of the Mineralogical Society, 30 (230) 691-698 doi:10.1180/minmag.1955.030.230.02 DOI: 10.1180/minmag.1955.030.230.02
  2. 1969Kiss, Klara, Page, Harold T. (1969) Electron Microscopic Identification of Single Crystals of Wairakite, a Rare Component in Clays. Clays and Clay Minerals, 17 (1) 31-35 doi:10.1346/ccmn.1969.0170106DOI: 10.1346/ccmn.1969.0170106
  3. 1979Takéuchi, Yoshio, Mazzi, Fiorenzo, Haga, Nobuhiko, Galli, Ermano (1979) The crystal structure of wairakite. American Mineralogist, 64 (9-10) 993-1001
  4. 1996Goryainov, S.V., Fursenko, B.A., Belitsky, I.A. (1996) Phase transitions in analcime and wairakite at low-high temperatures and high pressure. Physics and Chemistry of Minerals, 23 (4-5). 297-308 doi:10.1007/bf00207776DOI: 10.1007/bf00207776
  5. 1998Henderson, C. M. B., Bell, A. M. T., Kohn, S. C., Page, C. S. (1998) Leucite-pollucite structure-type variability and the structure of a synthetic end-member calcium wairakite (CaAl2Si4O12·2H2O) Mineralogical Magazine, 62 (2) 165-178 doi:10.1180/002646198547558 DOI: 10.1180/002646198547558
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wairakite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wairakite-4230},
  note      = {Accessed 2026-05-11}
}