Witherite

Ba(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wth
Discovered
1789
Also known as
  • Aerated barytes
  • Barolit
  • Barolita
  • +8 more

Where it forms, where it's found

Geological setting

Low-temperature hydrothermal veins.

Type locality
Anglezarke Mines
  1. Anglezarke
  2. Chorley
  3. Lancashire
  4. England
  5. UK

53.6454°, -2.5592°

274recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Resinous
Transparency
Transparent · Translucent
Colour
Colourless · white · greyish · light yellow · colourless in transmitted light.
Streak
White
Cleavage
Distinct/Good

On (010) distinct; on (110) imperfect. Possibly also on (110) and (112).

Fracture
Irregular/Uneven
Density
4.289 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 16° · 2V calc = 8°
Refractive index
1.529 – 1.677
Surface relief
Moderate
Principal indices
nα 1.529 · nβ 1.676 · nγ 1.677
Dispersion
relatively weak
Michel-Lévy diagramhighlighted lineδ = 0.1480
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1480 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1480 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 5.314 Å · b = 8.904 Å · c = 6.430 Å
Ratio a:b:c
1 : 1.676 : 1.210
Z
4
Morphology

Crystals universally twinned on (110), yielding pseudo-hexagonal dipyramids; also short prismatic [001] or tabular to lenticular with a convex base. Faces commonly rough and horizontally striated. Globular, tuberose, and botryoidal; structure columnar, granular, or coarse fibrous.

Twinning

On (110), universal.

Epitaxy

Witherites in parallel growth on Barytocalcite (Blagill). Baryte on witherite, with baryte [010](102) parallel with witherite [100](011) and (031); also otherwise oriented.

Comment

Space Group: Pmcn (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium1137.327137.327
69.59%
8OOxygenOxygen315.99947.997
24.32%
6CCarbonCarbon112.01112.011
6.09%
Total197.335100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • Sr

Synonyms

  • Aerated barytes
  • Barolit
  • Barolita
  • Barolite
  • Barolite (of Kirwan)
  • Baryte carbonatée
  • Kohlensaurer Baryt
  • Sulphato-Carbonate of Baryta
  • Terra ponderosa aerata
  • Viterita
  • Viterite

In other languages

French
14941-39-0 · 513-77-9 · BaCO3 · Withérite
German
Witherit
Spanish
witherita
Italian
witherite
Portuguese
witherita · Witherite
Japanese
毒重土石 · 毒重石
Chinese
毒重石
Russian
витерит

Classification

Strunz
10th ed.

5.AB.15

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.15WitheriteSpecies
Dana
8th ed.

14.01.03.02

  • 14Anhydrous Normal CarbonatesClass
  • 14.01A(XO3)Type
  • 14.01.03Aragonite Group (Orthorhombic: Pmcn)Group
  • 14.01.03.02WitheriteSpecies
CIM

11.5.2

  • 11CarbonatesClass
  • 11.5Carbonates of Sr and BaGroup
  • 11.5.2WitheriteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
6 minerals

Literature, links & citation

Citations
  1. Cotterell, T.F. (2022). Pondering the discovery of aerated ponderous spar: The type locality and early history of witherite. Journal of the Russell Society, 25, 10-56.
  2. 1784Withering, W. (1784) Experiments and observations on the Terra Ponderosa, &c. Philosophical Transactions of the Royal Society: 293-311 (as Terra ponderosa aerata).
  3. 1784Withering, W. (1784) Experiments and observations on the Terra Ponderosa, &c. Philosophical Transactions of the Royal Society: 293-311
  4. 1790Watt (1790) Mem. Manchester Society: 3: 599 (as Aerated Barytes).
  5. 1790Werner (1790) Bergmaaennusches Journal, Freiberg (Neues Bergmannische Journal): 2: 225 (as Witherit).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Witherite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/witherite-4299},
  note      = {Accessed 2026-05-11}
}