Wöhlerite

Na2Ca4Zr(Nb,Ti)(Si2O7)2(O,F)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wöh
Discovered
1843
Also known as
  • Marianoite
  • woehlerite
  • Wöhleriet

Where it forms, where it's found

Geological setting

Syenite pegmatite

Late phase of alkalid pegmatites, nepheline syenites, fenites, carbonatites.

Type locality
Løvøya
  1. Porsgrunn
  2. Telemark
  3. Norway

59.0578°, 9.7389°

99recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Honey-yellow · wine-yellow to sulfur-yellow · light to dark yellow · brown · gray
Streak
Yellowish white; pale yellow
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (010) Poor on (100)(110)

Fracture
Irregular/Uneven · Splintery
Density
3.40 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70 – 77° · 2V calc = 70 – 76°
Refractive index
1.7 – 1.728
Surface relief
High
Principal indices
nα 1.700 – 1.705 · nβ 1.716 – 1.720 · nγ 1.726 – 1.728
Pleochroism
Weak

X=Y= nearly colorless to pale yellow Z= wine-yellow

Dispersion
r > v weak
Extinction
Z = b; X ∧ c = 45°.
Michel-Lévy diagramhighlighted lineδ = 0.0245
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]245 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation245 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21
Cell parameters
a = 10.824(1) Å · b = 10.249(1) Å · c = 7.2673(8) Å
Cell angles
β = 109.343(4) °
Ratio a:b:c
1 : 0.947 : 0.671
Z
4
Morphology

Prismatic crystals to 3 cm, granular. Thick tabular on (100). Brøgger (1890) list these forms as the more frequent ones (100), (110), (210), (120), (130), (001), (101), (101), (111) and (011). Other forms observed are (010), (720), (012), (021), (111), (121), (311), (201), (212), (121), (211), (221) and (161).

Twinning

Twin plane (010) common; may be complex, lamellar. reflection twinning on (100)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
31.49%
20CaCalciumCalcium440.078160.312
17.53%
14SiSiliconSilicon428.085112.340
12.28%
41NbNiobiumNiobium192.90692.906
10.16%
40ZrZirconiumZirconium191.22491.224
9.97%
9FFluorineFluorine418.99875.992
8.31%
22TiTitaniumTitanium147.86747.867
5.23%
11NaSodiumSodium222.99045.980
5.03%
Total914.603100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Hf
  • Al
  • Y
  • Ce
  • La
  • Fe
  • Ta
  • Mn
  • Mg
  • Sr

Synonyms

  • Marianoite
  • woehlerite
  • Wöhleriet

In other languages

French
Wöhlerite
German
Wöhlerit
Spanish
Wohlerita
Italian
Wöhlerite

Classification

Strunz
10th ed.

9.BE.17

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.17WöhleriteSpecies
Dana
8th ed.

56.02.04.05

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.04Cuspidine - Wohlerite groupGroup
  • 56.02.04.05WöhleriteSpecies
CIM

17.8.10

  • 17Silicates Containing other AnionsClass
  • 17.8Silicates with niobate or tantalateGroup
  • 17.8.10WöhleriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Handbook of Mineralogy.
  2. 1843Scheerer, Th. (1843) Ueber den Wöhlerit, eine neue Mineralspecies. Annalen der Physik und Chemie, 135. 327-336 doi:10.1002/andp.18431350611DOI: 10.1002/andp.18431350611
  3. 1854Dauber, H. (1854) Untersuchungen an Mineralien der Sammlung des Hrn. Dr. Krantz in Bonn. Annalen der Physik und Chemie, 168. 237-251 doi:10.1002/andp.18541680604DOI: 10.1002/andp.18541680604
  4. 1890Brøgger, Waldemar Christofer (1890) Die Mineralien der Syenitpegmatitgänge der südnorwegischen Augit- und Nephelinsyenite. Zeitschrift für Krystallographie und Mineralogie, 16 (1). 1-893
  5. 1973Golyshev, M., Otroshchenko, L.P., Simonov, V.I., Belov, N.V. (1973) Refining the atomic structure of wöhlerite, NaCa2(Zr,Nb)[Si2O7](F,O)2. Soviet Physics - Doklady: 18: 287-289.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wöhlerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wohlerite-4303},
  note      = {Accessed 2026-05-11}
}