Allophane

Al2O3(SiO2)1.3-2.0 · 2.5-3.0H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Alp
Discovered
1816
Also known as
  • Allophaan
  • Allophanit
  • Allophanite
  • +13 more

Where it forms, where it's found

Geological setting

A weathering product of volcanic ash. In hydrothermally altered igneous rocks, from the breakdown of feldspars, and in hydrothermal veins, typically related to copper deposits. In sedimentary rocks, including chalk and coal beds.

Type locality
Gräfenthal
  1. Saalfeld-Rudolstadt District
  2. Thuringia
  3. Germany
470recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · sub-resinous · waxy
Transparency
Transparent · Translucent
Colour
White · pale blue to sky-blue · green · brown
Streak
White
Tenacity
brittle
Cleavage
None Observed

None

Fracture
Conchoidal
Density
2.75 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.468 – 1.512
Luminescence
None
Notes

RI from air dried sample

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.490

Crystallography

Crystal system
Amorphous
Morphology

Rarely observed as ring-shaped particles, with diameters of 50 Å, which in three dimensions may represent sections through hollow spherules or polyhedra. As hyaline crusts and masses; stalactites and flowstones.

Type-locality form

hyaline crusts and masses; stalactites and flowstones.

Comment

Amorphous

Chemical composition

Impurities
  • Ti
  • Fe
  • Mg
  • Ca
  • Na
  • K

Synonyms

  • Allophaan
  • Allophanit
  • Allophanite
  • Elhuyarit
  • Elhuyarita
  • Elhuyarite
  • Ilbait
  • Ilbaite
  • Razoumofskyn
  • Razumofskin
  • Razumowskin
  • Riemanit
  • Riemanite
  • Riemannit
  • Riemannita
  • Riemannite

In other languages

French
Allophane · Allophanite · Carolathine · Collyrite · Dillnite · Elhuyarite · Ferriallophane · Ilbaite · Phosphate-allophane · Plumboallophane · Protoallophane · Riemanit · Riemanite · Samoïte · Scarbroïte · Schöttérite · Schröttérite
German
Allophan · Elhuyarit · Ilbait · Riemannit
Spanish
Allofanita
Italian
allofane · allophane
Portuguese
Alofana · alofânio
Japanese
アロフェン
Russian
Аллофан

Classification

Strunz
10th ed.

9.ED.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EDPhyllosilicates with kaolinite layers composed of tetrahedral and octahedral netsGroup
  • 9.ED.20AllophaneSpecies
Dana
8th ed.

71.01.05.01

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.01Sheets of 6-membered rings with 1:1 layersType
  • 71.01.05— unnamed intermediate level —Group
  • 71.01.05.01AllophaneSpecies
CIM

15.11

  • 15Silicates of AluminumClass
  • 15.11— unnamed intermediate level —Group
  • 15.11AllophaneSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1816Hausmann, J.F.L. and Stromeyer, F. (1816) Über Silberkupferglanz und Allophan. Göttingische Gelehrte Anzeigen 2, 1251-1253.
  2. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  3. 1934Ross, C., Kerr, P. (1934) Halloysite and allophane. U.S. Geological Survey Professional Paper, 185G, 135.
  4. 1967Snetsinger, Kenneth G. (1967) High-alumina allophane as a weathering product of plagioclase. American Mineralogist, 52 (1-2) 254-262
  5. 1974Kitagawa, Yasuo (1974) Dehydration of allophane and its structural formula. American Mineralogist, 59 (9-10) 1094-1098
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Allophane — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/allophane-139},
  note      = {Accessed 2026-05-11}
}