Alumohydrocalcite

CaAl2(CO3)2(OH)4 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ahcal
Discovered
1926
Also known as
  • Aluminohydrocalcit
  • Aluminohydrocalcita
  • Aluminohydrocalcite
  • +6 more

Where it forms, where it's found

Geological setting

Limestone and siliceous rock.

Formed at low temperature by the action of carbonated waters on allophane or dickite in dolomites and limestones; chromian varieties are typically formed near altering chromite from serpentinites.

Type locality
Potekhina Village
  1. Sorsk
  2. Khakassia (Republic of Khakassia)
  3. Russia
39recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Chalky white to pale blue · pale yellow · cream · gray · pale rose or brownish pink to dark violet in Cr-bearing varieties

colourless in transmitted light

Tenacity
brittle
Cleavage
Perfect

On (100); on (010) imperfect.

Density
2.21 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 64° · 2V calc = 50 – 60°
Refractive index
1.485 – 1.585
Surface relief
Moderate
Principal indices
nα 1.485 – 1.502 · nβ 1.553 – 1.562 · nγ 1.570 – 1.585
Dispersion
r > v strong
Extinction
X = b; Extinction inclined 6°–10°.
Michel-Lévy diagramhighlighted lineδ = 0.0840
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]840 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation840 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.71(5) Å · b = 6.54(4) Å · c = 14.6(2) Å
Cell angles
α = 81.8(3) ° · β = 83.9(3) ° · γ = 86.5(7) °
Ratio a:b:c
1 : 1.145 : 2.557
Unit cell volume
537 ų
Morphology

As fibers and needles, to 2.5 mm; commonly in radial aggregates and spherulites, feltlike crystal linings, and powdery to chalky masses.

Type-locality form

Finely porous, chalk-like masses.

Comment

Space Group: P_1 or P1 (chromian).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
63.25%
13AlAluminiumAluminium226.98253.964
15.24%
20CaCalciumCalcium140.07840.078
11.32%
6CCarbonCarbon212.01124.022
6.78%
1HHydrogenHydrogen121.00812.096
3.41%
Total354.146100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cr

Synonyms

  • Aluminohydrocalcit
  • Aluminohydrocalcita
  • Aluminohydrocalcite
  • Alumohydrocalciet
  • Alumohydrocalcita
  • Alumohydrokalsitt
  • Khakassit
  • Khakassita
  • Khakassite

In other languages

German
Alumohydrocalcit
Spanish
Alumohidrocalcita
Italian
allumoidrocalcite · alumohydrocalcite · Alumoidrocalcite

Classification

Strunz
10th ed.

5.DB.05

  • 5CarbonatesClass
  • 5.DCarbonates with additional anions, with H2ODivision
  • 5.DBWith large and medium-sized cationsGroup
  • 5.DB.05AlumohydrocalciteSpecies
Dana
8th ed.

16b.02.03.01

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.02AmBn(XO3)pZqxH2O & with (m+n):p = 3:2Type
  • 16b.02.03— unnamed intermediate level —Group
  • 16b.02.03.01AlumohydrocalciteSpecies
CIM

11.7.7

  • 11CarbonatesClass
  • 11.7Carbonates of AlGroup
  • 11.7.7AlumohydrocalciteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1926Bilibine, G. (1926) Alumohydrocalcite - a new species. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 55: 243-258.
  2. 1926Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A) Bilibine, G. (1926) Alumohydrocalcite - a new species. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva: 55: 243-258.
  3. 1928Foshag, W.F. (1928) New mineral names. American Mineralogist, 13 (12). 592-593
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1969Kautz, K. (1969) Elektronenbeugung und Infrarot-Untersuchungen an Alumohydrocalcit. Neues Jahrbuch für Mineralogie, Monatshefte: 1969: 130-137.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alumohydrocalcite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alumohydrocalcite-157},
  note      = {Accessed 2026-05-11}
}