Anatase

TiO2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ant
Discovered
1801
Also known as
  • Dauphinite
  • Hydrotitanite
  • Octaèdrit
  • +12 more

History

Anatase wears a name built from a Greek word for stretching. The mineral's crystals end in two steep, narrow pyramids — sharper and taller than the flatter pyramids most tetragonal minerals show — and that elongation is what early observers noticed first.

The modern name was given in 1801 by the French crystallographer René Just Haüy. He drew on the Greek anatasis, meaning extension or stretching out. The allusion is to the unusual length of the pyramidal faces relative to their bases. The mineral was already known to mineralogists before Haüy fixed the name. The Swiss naturalist Horace Bénédict de Saussure had earlier called the same species octahedrite, after the acute octahedron its crystals appear to form. Two other older names — oisanite and dauphinite — refer to the district of Le Bourg-d'Oisans in the French Dauphiné, the locality from which the species takes its type description.

Anatase is one of three natural forms — or polymorphs — of titanium dioxide (TiO₂), alongside rutile and brookite. The three share a chemical formula but crystallise differently. Anatase occurs as hard, brilliant tetragonal crystals in vein deposits of the Alps. It also turns up as a detrital mineral in placer deposits, notably in Minas Gerais and Bahia in Brazil.

Industrial & practical applications

Anatase the mineral has almost no direct industrial role. The titanium dioxide (TiO₂) that fills paint cans, sunscreens and food coatings is produced synthetically from rutile or ilmenite ores. Anatase as a polymorph — a distinct crystal form of TiO₂ — still matters to industry. But the form is made in a reactor, not mined.

In pigment manufacture, the anatase form serves a narrower role than its sibling rutile. Anatase is softer than rutile and is used in fibre and paper applications, where the lower abrasiveness is an advantage. The mineral is metastable: heat above roughly 600 to 800 °C and the anatase phase converts irreversibly to rutile. That conversion is why most outdoor and high-durability pigments use the rutile form directly.

Anatase has found a second life in photocatalysis — the use of a solid to drive a chemical reaction under light. Nanosized titanium dioxide in the anatase form shows photocatalytic activity under ultraviolet light. The most active surface of the crystal, the (001) plane, is where the reactive chemistry concentrates. Films of anatase deposited on glass become self-cleaning and anti-fogging when exposed to sunlight. The effect was first identified by Fujishima and colleagues in 1995. The same photoactive form is also used in dye-sensitized solar cells, where it carries photo-excited electrons from the dye to the external circuit.

Synthetic anatase is typically prepared by controlled hydrolysis of titanium tetrachloride (TiCl₄) or titanium ethoxide. Dopants are added to tune the surface chemistry and electronic structure for the target application.

Where it forms, where it's found

Geological setting

Alpine veins, derived from the enclosing gneisses or schists by hydrothermal solutions.

Usually secondary, derived from other titanium-bearing minerals. In alpine veins, derived from the enclosing gneisses or schists by hydrothermal solutions. In igneous and metamorphic rocks; in pegmatites; from a carbonatite. A common detrital mineral.

Type locality
Saint-Christophe-en-Oisans
  1. Grenoble
  2. Isère
  3. Auvergne-Rhône-Alpes
  4. France
2,289recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine to metallic-adamantine in darker colored specimens.
Transparency
Transparent · Translucent
Colour
Brown · pale yellow or reddish brown · indigo · black · pale green · pale lilac · grey · rarely nearly colourless · brown · yellow-brown · pale green · blue in transmitted light.

Transparent when light coloured, to nearly opaque when deeply colored. Pyramidal crystals may appear opaque because of total reflection.

Streak
White to pale yellow
Tenacity
brittle
Cleavage
Perfect

on (001) and (011)

Fracture
Sub-Conchoidal
Density
3.79 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.488 – 2.5612
Surface relief
Very high
Principal indices
nω 2.5612 · nε 2.488
Pleochroism
Weak

stronger in deeply coloured crystals

Reflectance R%
(23.7, 23.8) 400 nm, (22.4, 22.5) 420 nm, (21.7, 21.6) 440 nm, (21.1, 21.0) 460 nm, (20.7, 20.4) 480 nm, (20.2, 20.0) 500 nm, (19.9, 19.6) 520 nm, (19.6, 19.3) 540 nm, (19.4, 19.0) 560 nm, (19.2, 18.8) 580 nm, (19.0, 18.5) 600 nm, (18.8, 18.4) 620 nm, (18.7, 18.2) 640 nm, (18.6, 18.1) 660 nm, (18.5, 18.0) 680 nm, (18.4, 17.8) 700 nm
Luminescence
None
UV response
Not fluorescent.
Notes

Deeply coloured crystals may be anomalously biaxial

Reflected-light panel
20.0 %anisotropic · dual curve
Specimen sRGB 160, 113, 65
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Tetragonal
Space group
#178
Cell parameters
a = 3.7845 Å · c = 9.5143 Å
Z
4
Morphology

Crystals typically acute dipyramidal (011), often highly modified; obtuse pyramidal or tabular on (001); less commonly prismatic on [001], with (110), (010)

Twinning

Rare, on (112)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
22TiTitaniumTitanium147.86747.867
59.93%
8OOxygenOxygen215.99931.998
40.07%
Total79.865100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Sn
  • V
  • Nb

Synonyms

  • Dauphinite
  • Hydrotitanite
  • Octaèdrit
  • Octaèdrita
  • Octaèdrite
  • Octahedrit
  • Octahedrita
  • Octahedrite (of Werner)
  • Oisanite
  • Oktaedrit
  • Schorl bleu indigo
  • Schorl octaedre rectanglaire
  • Wiserine
  • Xanthotitane
  • Xanthotitanit

In other languages

French
Anatase · Dauphinite · Hydrotitanite · Schorl bleu indigo · Schorl octaédre rectanglaire · Schorl octaédre rectangulaire · Wisérine · Xanthitane · Xanthotitane
German
Anatas · oktaedrischer Schörl · Oktaedrit
Spanish
Anatasa · Octaedrita · Octahedrita
Italian
anatase · anatasio
Portuguese
anatase · Anatásio
Japanese
アナタース · アナテース · 鋭錐石
Chinese
锐钛矿
Simplified Chinese
锐钛矿
Traditional Chinese
銳鈦礦
Russian
анатаз
Arabic
أناتاز

Classification

Strunz
10th ed.

4.DD.05

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DDWith medium-sized cations; frameworks of edge-sharing octahedraGroup
  • 4.DD.05AnataseSpecies
Dana
8th ed.

04.04.04.01

  • 04Simple OxidesClass
  • 04.04AX2Type
  • 04.04.04— unnamed intermediate level —Group
  • 04.04.04.01AnataseSpecies
CIM

7.9.3

  • 7Oxides and HydroxidesClass
  • 7.9Oxides of TiGroup
  • 7.9.3AnataseSpecies

Group, growth & confusion

Commonly confused with
4 minerals

Literature, links & citation

Citations
  1. 1801Haüy, René Just (1801) Traité de Minéralogie (1st ed.) Vol. 3. Chez Louis, Paris.
  2. 1852Brooke, Henry J., Phillips, William (1852) An Elementary Introduction to Mineralogy (6th ed.)
  3. 1872Brezina, A. (1872) Mineralogische Mittheilungen, 2, 7.
  4. 1906Palache, C. (1906) On actahedrite, brookite, and titanite from Somerville, Massachusetts, U.S.A.. Festchrift Harry Rosenbusch, 311-321. (as octahedrite)
  5. 1911Warren, C.H., Palache, C. (1911) The Pegmatites of the Riebeckite-Aegirite Granite of Quincy, Mass., U.S.A.; Their Structure, Minerals, and Origin. Proceedings of the American Academy of Arts and Sciences, 47(4), 125-168. (as octahedrite)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Anatase — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/anatase-213},
  note      = {Accessed 2026-05-11}
}