Braithwaiteite

NaCu2+5(Sb5+Ti4+)O2(AsO4)4[AsO3(OH)]2 · 8H2O
IMA status
  • Approved
IMA symbol
Bwt
IMA approved
2006
Also known as
  • Braithwaiteiet
  • IMA2006-050

Where it forms, where it's found

Geological setting

Oxidized portion of an epithermal vein deposit.

Type locality
Laurani Mine
  1. Sica Sica Municipality
  2. Aroma Province
  3. La Paz
  4. Bolivia

-17.3808°, -67.7750°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Blue
Streak
Very pale blue
Tenacity
brittle
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
3.442 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 59° · 2V calc = 65°
Refractive index
1.6982 – 1.7835
Surface relief
High
Principal indices
nα 1.6982 · nβ 1.7575 · nγ 1.7835
Birefringence
0.085
Pleochroism
Visible

X = Y = pale blue, Z = greenish blue.

Extinction
X ∧ a = 20.5°, X ∧ b = 109.2°, X ∧ c = 110.8°. Y ∧ a = 69.5°, Y ∧ b = 42.3°, Y ∧ c = 79.9°. Z ∧ a = 88.4°, Z ∧ b = 125.9°, Z ∧ c = 23.4°.
UV response
Not fluorescent in UV.
Notes

Absorption: X = Y < Z.

Michel-Lévy diagramhighlighted lineδ = 0.0850
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]850 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation850 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 7.0308 Å · b = 9.8823 Å · c = 10.6754 Å
Cell angles
α = 106.973 ° · β = 104.274 ° · γ = 93.839 °
Ratio a:b:c
1 : 1.406 : 1.518
Z
1
Morphology

Lath-like. Forms include (100), (103), (001), (203).

Type-locality form

Small dark sky-blue bladed crystals or masses.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3415.999543.966
35.74%
33AsArsenicArsenic674.922449.532
29.54%
29CuCopperCopper563.546317.730
20.88%
51SbAntimonyAntimony1121.760121.760
8.00%
22TiTitaniumTitanium147.86747.867
3.14%
11NaSodiumSodium122.99022.990
1.51%
1HHydrogenHydrogen181.00818.144
1.19%
Total1521.989100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Braithwaiteiet
  • IMA2006-050

In other languages

German
Braithwaiteit · IMA 2006-050
Italian
braithwaiteite

Classification

Strunz
10th ed.

8.DB.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.75BraithwaiteiteSpecies
Dana
8th ed.

39.03.16

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.03MiscellaneousType
  • 39.03.16— unnamed intermediate level —Group
  • 39.03.16BraithwaiteiteSpecies

Group, growth & confusion

Often grow together
9 minerals

Literature, links & citation

Citations
  1. 2008Hawthorne, F.C., Cooper, M.A. & Paar, W.H. (2008): The crystal structure of braithwaiteite. Journal of Coordination Chemistry, 61, 15-29.
  2. 2009Paar, W. H., Cooper, M. A., Hawthorne, F. C., Moffatt, E., Gunter, M. E., Roberts, A. C., Dunn, P. J. (2009) Braithwaiteite, NaCu5(TiSb)O2(AsO4)4[AsO3(OH)]2(H2O)8, a new mineral species from Laurani, Bolivia. The Canadian Mineralogist, 47 (4) 947-952 doi:10.3749/canmin.47.4.947 DOI: 10.3749/canmin.47.4.947
  3. 2011(2011) Braithwaiteite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Braithwaiteite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/braithwaiteite-31499},
  note      = {Accessed 2026-05-11}
}