Benyacarite

(H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O
IMA status
  • Approved
IMA symbol
Byc
Discovered
1993
Also known as
  • Benyacariet
  • IMA1995-002

Where it forms, where it's found

Geological setting

Late stage phosphate mineralization in a granite pegmatite.

Late stage phosphate mineralization in a granite pegmatite

Type locality
El Criollo Mine
  1. Cerro Blanco pegmatite district
  2. Tanti
  3. San Roque District
  4. Punilla Department
  5. Córdoba Province
  6. Argentina

-31.3578°, -64.6525°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Light greenish yellow to light brown
Streak
White
Tenacity
very brittle
Cleavage
Perfect

(010) perfect

Fracture
Irregular/Uneven
Density
2.37 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60° · 2V calc = 60°
Refractive index
1.612 – 1.649
Surface relief
Moderate
Principal indices
nα 1.612 · nβ 1.621 · nγ 1.649
Birefringence
0.037
Pleochroism
Non-pleochroic
Dispersion
none
Extinction
Parallel. XYZ = bca
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0370
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]370 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation370 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbca
Cell parameters
a = 10.561(5) Å · b = 20.585(8) Å · c = 12.516(2) Å
Ratio a:b:c
1 : 1.949 : 1.185
Z
4
Morphology

Tabular to equidimensional. Forms (010), (111), (001), and (100).

Type-locality form

Small (0.2 -0.3 mm) nearly light greenish yellow to light brown crystals with (010), (111), (001), and (100).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3315.999527.967
54.74%
15PPhosphorusPhosphorus430.974123.896
12.84%
25MnManganeseManganese254.938109.876
11.39%
22TiTitaniumTitanium247.86795.734
9.93%
26FeIronIron155.84555.845
5.79%
1HHydrogenHydrogen321.00832.256
3.34%
9FFluorineFluorine118.99818.998
1.97%
Total964.572100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Benyacariet
  • IMA1995-002

In other languages

German
Benyacarit · IMA 1995-002
Italian
benyacarite · IMA1995-002
Chinese
水磷锰铁钛石

Classification

Strunz
10th ed.

8.DH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.35BenyacariteSpecies
Dana
8th ed.

42.11.21.04

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.21Paulkerrite GroupGroup
  • 42.11.21.04BenyacariteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1993Demartin, F., Pilati, T., Gay, H. D., Gramaccioli, C. M. (1993) The crystal structure of a mineral related to paulkerrite. Zeitschrift für Kristallographie, 208 (1-2). 57-72 doi:10.1524/zkri.1993.208.12.57 DOI: 10.1524/zkri.1993.208.12.57
  2. 1997Demartin, F., Gay, H. D., Gramaccioli, C. M., Pilati, T. (1997) Benyacarite, a new titanium-bearing phosphate mineral species from Cerro Blanco, Argentina. The Canadian Mineralogist, 35 (3) 707-712
  3. 1998Mandarino, Joseph A. (1998) Abstracts of New Mineral Descriptions. The Mineralogical Record, 29 (3) 233-237
  4. 1998Jambor, John L., Roberts, Andrew C. (1998) New mineral names. American Mineralogist, 83 (3-4) 400-403
  5. 1998Keck, E., Witzke, T., Pöllmann, H., and Friese, K. (1998) Benyacarit aus ostbayerischen und portugiesischen Pegmatiten. Aufschluss: 49: 281-285.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Benyacarite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/benyacarite-6823},
  note      = {Accessed 2026-05-11}
}