Where it forms, where it's found
- Geological setting
occurs in corrosion cavities in the triplite in a granite pegmatite
- Type locality
- El Criollo Mine
- Cerro Blanco pegmatite district
- Tanti
- San Roque District
- Punilla Department
- Córdoba Province
- Argentina
-31.3578°, -64.6525°
2recorded occurrences
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 88° · 2V calc = 87.5°
- Refractive index
- 1.608 – 1.642
- Surface relief
- Moderate
- Principal indices
- nα 1.608 · nβ 1.624 · nγ 1.642
- Pleochroism
- Non-pleochroic
- Dispersion
- Dispersion is moderate with r < v
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour
Crystallography
- Space group
- Pbca
- Cell parameters
- a = 10.5500(3) Å · b = 20.7248(5) Å · c = 12.5023(3) Å
- Ratio a:b:c
- 1 : 1.964 : 1.185
- Z
- 4
- Type-locality form
rhombic tablets with dimensions of typically 20 to 50 µm, occasionally to 400 µm
Crystal structure
Chemical composition
Synonyms
- Hydroxylbenyacariet
In other languages
- German
- Hydroxylbenyacarit
- Italian
- idrossilbenyacarite · IMA2023-079
Classification
Strunz
10th ed.8.DH.35
- 8Phosphates, Arsenates, VanadatesClass
- 8.DPhosphates, etc. with additional anions, with H2ODivision
- 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
- 8.DH.35HydroxylbenyacariteSpecies
Group, growth & confusion
Benyacarite(H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2OMineral—- Bergbauerite(H2O)2Mn2(Fe2Ti)(PO4)4(OH)2(H2O)10·4H2OMineral—
Fluor-rewitzerite[(H2O)K]Mn2(Al2Ti)(PO4)4(OF)(H2O)10·4H2OMineral—
Fluormacraeite [(H2O)K]Mn2(Fe2Ti)(PO4)4(OF)(H2O)10·4H2OMineral—
HochleitneriteMn2Ti3(PO4)4O2(H2O)2 · 14H2OMineral—
MacraeiteK(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10·4H2OMineral—
MantienneiteKMg2Al2Ti(PO4)4(OH)3 · 15H2OMineral—
PaulkerriteKMg2TiFe3+2(PO4)4(OH)3 · 15H2OMineral—
Pleysteinite[(H2O)0.5K0.5]2Mn2Al3(PO4)4F2 · 4H2OMineral—
Rewitzerite[K(H2O)]Mn2Al3(PO4)4(OH)2 · 14H2OMineral—
Literature, links & citation
Citations
- 2023Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2023) Newsletter 76. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2023.89 DOI: 10.1180/mgm.2023.89
- 2024Hochleitner, Rupert; Rewitzer, Christian; Grey, Ian E.; Kampf, Anthony R.; MacRae, Colin M.; Gable, Robert W.; Mumme, William G. (2024) Hydroxylbenyacarite, (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O, a new paulkerrite-group mineral, from the El Criollo mine, Cordoba Province, Argentina. Mineralogical Magazine, 88 (3). 327-334 doi:10.1180/mgm.2024.16DOI: 10.1180/mgm.2024.16
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Hydroxylbenyacarite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/hydroxylbenyacarite-470925},
note = {Accessed 2026-05-11}
}