Hydroxylbenyacarite

(H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10·4H2O
IMA status
  • Approved
IMA symbol
Hbyc
Also known as
  • Hydroxylbenyacariet

Where it forms, where it's found

Geological setting

occurs in corrosion cavities in the triplite in a granite pegmatite

Type locality
El Criollo Mine
  1. Cerro Blanco pegmatite district
  2. Tanti
  3. San Roque District
  4. Punilla Department
  5. Córdoba Province
  6. Argentina

-31.3578°, -64.6525°

2recorded occurrences
Source · OpenStreetMap

Physical

Colour
light greenish-yellow
Density
2.32 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 88° · 2V calc = 87.5°
Refractive index
1.608 – 1.642
Surface relief
Moderate
Principal indices
nα 1.608 · nβ 1.624 · nγ 1.642
Pleochroism
Non-pleochroic
Dispersion
Dispersion is moderate with r < v
Michel-Lévy diagramhighlighted lineδ = 0.0340
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]340 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbca
Cell parameters
a = 10.5500(3) Å · b = 20.7248(5) Å · c = 12.5023(3) Å
Ratio a:b:c
1 : 1.964 : 1.185
Z
4
Type-locality form

rhombic tablets with dimensions of typically 20 to 50 µm, occasionally to 400 µm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3415.999543.966
56.51%
15PPhosphorusPhosphorus430.974123.896
12.87%
25MnManganeseManganese254.938109.876
11.41%
22TiTitaniumTitanium247.86795.734
9.95%
26FeIronIron155.84555.845
5.80%
1HHydrogenHydrogen331.00833.264
3.46%
Total962.581100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Hydroxylbenyacariet

In other languages

German
Hydroxylbenyacarit
Italian
idrossilbenyacarite · IMA2023-079

Classification

Strunz
10th ed.

8.DH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.35HydroxylbenyacariteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2023) Newsletter 76. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2023.89 DOI: 10.1180/mgm.2023.89
  2. 2024Hochleitner, Rupert; Rewitzer, Christian; Grey, Ian E.; Kampf, Anthony R.; MacRae, Colin M.; Gable, Robert W.; Mumme, William G. (2024) Hydroxylbenyacarite, (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O, a new paulkerrite-group mineral, from the El Criollo mine, Cordoba Province, Argentina. Mineralogical Magazine, 88 (3). 327-334 doi:10.1180/mgm.2024.16DOI: 10.1180/mgm.2024.16
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydroxylbenyacarite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydroxylbenyacarite-470925},
  note      = {Accessed 2026-05-11}
}