Macraeite

K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10·4H2O
IMA status
  • Approved
IMA symbol
Macr
IMA approved
2023
Also known as
  • Macraeiet

Where it forms, where it's found

Geological setting

pegmatite formation, is an important locality for secondary phosphate minerals.

Type locality
Chão do Castanheiro
  1. Cubos-Mesquitela-Mangualde area
  2. Mangualde (Mesquitela e Cunha Alta)
  3. Mangualde
  4. Viseu
  5. Portugal

40.5868°, -7.7515°

2recorded occurrences
Source · OpenStreetMap

Physical

Colour
light-greenish-yellow
Density
2.39 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 45° · 2V calc = 25.8°
Refractive index
1.605 – 1.646
Surface relief
Moderate
Principal indices
nα 1.605 · nβ 1.611 · nγ 1.646
Dispersion
strong with r<v
Michel-Lévy diagramhighlighted lineδ = 0.0410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]410 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation410 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10.562(2) Å · b = 20.725(4) Å · c = 12.416(2) Å
Cell angles
β = 90.09(3) °
Ratio a:b:c
1 : 1.962 : 1.176
Z
4
Type-locality form

equant euhedral crystals with relatively uniform sizes from sub-100 to ∼ 150 µm. Individual crystals have a pseudo-rhombic dodecahedral shape although the crystals are more commonly aggregated and form complex intergrowths with dimensions of up to 0.5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3315.999527.967
53.24%
15PPhosphorusPhosphorus430.974123.896
12.50%
26FeIronIron255.845111.690
11.26%
25MnManganeseManganese254.938109.876
11.08%
22TiTitaniumTitanium147.86747.867
4.83%
19KPotassiumPotassium139.09839.098
3.94%
1HHydrogenHydrogen311.00831.248
3.15%
Total991.642100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Macraeiet

In other languages

German
Macraeit
Italian
IMA2023-065 · macraeite

Classification

Strunz
10th ed.

8.DH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.35MacraeiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2023) Newsletter 76. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2023.89 DOI: 10.1180/mgm.2023.89
  2. 2024Grey, Ian E.; Rewitzer, Christian; Hochleitner, Rupert; Kampf, Anthony R.; Boer, Stephanie; Mumme, William G.; Wilson, Nicholas C. (2024) Macraeite, [(H2O)K]Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10  ⋅  4H2O, a new monoclinic paulkerrite-group mineral, from the Cubos–Mesquitela–Mangualde pegmatite, Portugal. European Journal of Mineralogy, 36 (2). 267-278 doi:10.5194/ejm-36-267-2024 DOI: 10.5194/ejm-36-267-2024
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Macraeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/macraeite-470938},
  note      = {Accessed 2026-05-11}
}