Paulkerrite

KMg2TiFe3+2(PO4)4(OH)3 · 15H2O
IMA status
  • Approved
IMA symbol
Pke
Discovered
1984
IMA approved
1984
Also known as
  • IMA1983-014
  • Paulkerriet

Where it forms, where it's found

Geological setting

Secondary phosphate mineralization in a granite pegmatite.

Granite pegmatite

Type locality
7U7 Ranch (7-U-7 Ranch)
  1. Bagdad Mine area
  2. Hillside
  3. Eureka Mining District
  4. Yavapai County
  5. Arizona
  6. USA
7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless to very light yellow-brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

(100) perfect

Fracture
Sub-Conchoidal
Density
2.36 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80° · 2V calc = 78 – 88°
Refractive index
1.591 – 1.643
Surface relief
Moderate
Principal indices
nα 1.591 – 1.598 · nβ 1.615 – 1.624 · nγ 1.639 – 1.643
Birefringence
0.045
Pleochroism
Non-pleochroic
Dispersion
r > v strong
Extinction
Parallel, XYZ = cba
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.569(2) Å · b = 20.590(4) Å · c = 12.413(2) Å
Cell angles
β = 90.33(3) °
Ratio a:b:c
1 : 1.948 : 1.174
Z
4
Morphology

Nearly colorless equant to nearly equant flattened crystals with simple forms: (010), (100), and (111).

Type-locality form

Flattened to equant transparent nearly colorless to very light yellowish brown 0.2 mm crystals.

Comment

p21/c

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3415.999543.966
57.36%
15PPhosphorusPhosphorus430.974123.896
13.06%
26FeIronIron255.845111.690
11.78%
12MgMagnesiumMagnesium224.30548.610
5.12%
22TiTitaniumTitanium147.86747.867
5.05%
19KPotassiumPotassium139.09839.098
4.12%
1HHydrogenHydrogen331.00833.264
3.51%
Total948.391100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1983-014
  • Paulkerriet

In other languages

German
Paulkerrit
Italian
IMA1983-014 · paulkerrite

Classification

Strunz
10th ed.

8.DH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.35PaulkerriteSpecies
Dana
8th ed.

42.11.21.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.21Paulkerrite GroupGroup
  • 42.11.21.01PaulkerriteSpecies
CIM

19.8.24

  • 19PhosphatesClass
  • 19.8Phosphates of Al and other metalsGroup
  • 19.8.24PaulkerriteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1984Dunn, Pete J., Simmons, William B., Peacor, Donald R. (1984) Paulkerrite, a new titanium phosphate from Arizona. The Mineralogical Record, 15 (5) 303-306
  2. 1985Dunn, Pete J., Fleischer, Michael, Langley, Richard H., Shigley, James E., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (7-8) 871-881
  3. 1997Demartin, F., Gay, H. D., Gramaccioli, C. M., Pilati, T. (1997) Benyacarite, a new titanium-bearing phosphate mineral species from Cerro Blanco, Argentina. The Canadian Mineralogist, 35 (3) 707-712
  4. 2005Schnorrer, G., Tetzer, G. (2005) Paulkerrite, K(Mg,Mn)2Fe2Ti[(OH)3|(PO4)4]·15H2O from Folgosinho quarry in Portugal, an additional locality for this rare compound. Aufschluss: 56: 258-260. (in German).
  5. 2005(2005) Paulkerrite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Paulkerrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/paulkerrite-3134},
  note      = {Accessed 2026-05-11}
}