Bermanite

Mn2+Mn3+2(PO4)2(OH)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Brm
Discovered
1936
Also known as
  • Bermaniet
  • Vierlingite

Where it forms, where it's found

Geological setting

In granite pegmatite.

In late-stages of phosphate mineralization in complex granite pegmatites.

Type locality
7U7 Ranch (7-U-7 Ranch)
  1. Bagdad Mine area
  2. Hillside
  3. Eureka Mining District
  4. Yavapai County
  5. Arizona
  6. USA
51recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · resinous.
Transparency
Transparent · Translucent
Colour
Reddish-brown · yellowish brown to brownish red with red internal reflections in transmitted light

Colour darkens on exposure.

Streak
Light red brown
Tenacity
brittle
Cleavage
Perfect

On (001), perfect; on (110), imperfect.

Density
2.84 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 72 – 75° · 2V calc = 74°
Refractive index
1.685 – 1.751
Surface relief
High
Principal indices
nα 1.685 – 1.690 · nβ 1.725 – 1.729 · nγ 1.748 – 1.751
Birefringence
0.062
Pleochroism
Visible

X = Light red Y = Pale yellow Z = Deep red

Dispersion
r > v weak
Extinction
Y ∧ a = 32.5°, Y ∧ c = -36.5°, X = b.
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0620
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]620 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation620 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#12
Cell parameters
a = 5.425 Å · b = 19.206 Å · c = 5.425 Å
Cell angles
β = 110.29 °
Ratio a:b:c
1 : 3.540 : 1.000
Z
2
Morphology

Crystals tabular (010). Sheaflike aggregates and rosettes commonly as thin films or druses on fractures.

Twinning

Polysynthetic about [101] with composition plane (101) or about [_101] with composition plane (101), common. As reflection twins on (001) about [100], or with two or more individuals twinned on (301) about [100], producing composite fourlings.

Type-locality form

Narrow veinlets and in drusy cavities in triplite.

Comment

Pseudo-orthorhombic; Space group: P21

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
48.61%
25MnManganeseManganese354.938164.814
35.76%
15PPhosphorusPhosphorus230.97461.948
13.44%
1HHydrogenHydrogen101.00810.080
2.19%
Total460.828100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bermaniet
  • Vierlingite

In other languages

German
Bermanit
Spanish
bermanita
Italian
Bermanite
Chinese
板磷锰矿

Classification

Strunz
10th ed.

8.DC.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.20BermaniteSpecies
Dana
8th ed.

42.11.17.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.17Bermanite GroupGroup
  • 42.11.17.01BermaniteSpecies
CIM

19.12.2

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.2BermaniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1936Hurlbut, Cornelius S. (1936) A new phosphate, bermanite, occurring with triplite in Arizona. American Mineralogist, 21 (10) 656-661
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1967Leavens, Peter B. (1967) Reexamination of bermanite. American Mineralogist, 52 (7-8) 1060-1066
  4. 1968Hurlbut, C. S. Jr., Aristarain, and L. F. (1968) Bermanite and its occurrence in Córdoba, Argentina. American Mineralogist, 53 (3-4) 416-431
  5. 1976Kampf, Anthony R., Moore, Paul B. (1976) The crystal structure of bermanite, a hydrated manganese phosphate. American Mineralogist, 61 (11-12) 1241-1248
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bermanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bermanite-634},
  note      = {Accessed 2026-05-11}
}