Leucophosphite

KFe3+2(PO4)2(OH) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lpp
Discovered
1932
Also known as
  • Leucophosphiet
  • Leucophosphit
  • Leucophosphita

Where it forms, where it's found

Geological setting

Guano deposits forming veins in serpentinite.

Cave deposits resulting from bird or bat guano reactions with earlier iron-bearing minerals; hydrothermally altered iron-rich phosphates in pegmatites; phosphate rock deposits; crosscutting fluorapatite nodules.

Type locality
Ninghanboun Hills serpentinite
  1. Weelhamby Lake
  2. Perenjori Shire
  3. Western Australia
  4. Australia

-29.1899°, 116.4604°

117recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White to greenish · buff · yellow-brown · orange-brown · pink · greenish brown · brownish purple
Streak
White
Tenacity
fragile
Cleavage
Perfect

On (100), perfect.

Density
2.948 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 84°
Refractive index
1.707 – 1.739
Surface relief
High
Principal indices
nα 1.707 · nβ 1.721 · nγ 1.739
Birefringence
0.032
Pleochroism
Non-pleochroic
Dispersion
r > v
Extinction
X = b, Z ∧ c = 26°
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0320
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]320 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation320 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 9.76 Å · b = 9.65 Å · c = 9.74 Å
Cell angles
β = 102.44 °
Ratio a:b:c
1 : 0.989 : 0.998
Morphology

Pseudo-orthorhombic. Crystals rhombic-shaped, exhibiting (100), (210), (111), and (111). Fine-grained, chalk-like masses. Amorphous in part.

Type-locality form

Chalk like mass.

Comment

P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
44.69%
26FeIronIron255.845111.690
28.37%
15PPhosphorusPhosphorus230.97461.948
15.73%
19KPotassiumPotassium139.09839.098
9.93%
1HHydrogenHydrogen51.0085.040
1.28%
Total393.765100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Leucophosphiet
  • Leucophosphit
  • Leucophosphita

In other languages

French
Leucophosphite
German
Leukophosphit
Italian
leucofosfite

Classification

Strunz
10th ed.

8.DH.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.10LeucophosphiteSpecies
Dana
8th ed.

42.11.06.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.06Leucophosphite GroupGroup
  • 42.11.06.01LeucophosphiteSpecies
CIM

19.14.7

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.7LeucophosphiteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1932Simpson, E.S. (1932) Contributions to the mineralogy of Western Australia, (7) Variscite (redondite) and leucophosphite (Sp. nov.), Ninghanboun Hills, S.W.. Journal of the Royal Society of Western Australia: 18: 69-74.
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1957Lindberg, Marie Louise (1957) Leucophosphite from the Sapucaia pegmatite mine, Minas Gerais, Brazil. American Mineralogist, 42 (3-4) 214-221
  4. 1966Bhaskara Rao, A., Adusumilli, Maria S. (1966) Leucophosphite and barbosalite from north-east Brazil. Mineralogical Magazine and Journal of the Mineralogical Society, 35 (273) 784-785 doi:10.1180/minmag.1966.035.273.17 DOI: 10.1180/minmag.1966.035.273.17
  5. 1972Moore, Paul Brian (1972) Octahedral tetramer in the crystal structure of leucophosphite, K2[Fe3+4(OH)2(H2O)2(PO4)4]·2H2O. American Mineralogist, 57 (3-4) 397-410
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Leucophosphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/leucophosphite-2385},
  note      = {Accessed 2026-05-11}
}