Botallackite

Cu2Cl(OH)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Blk
Discovered
1865
Also known as
  • Botallackiet

Where it forms, where it's found

Geological setting

In a copper deposit, in areas weathered while exposed to sea water.

In copper-bearing deposits, in areas with high chloride concentrations or weathered while exposed to sea water; a reaction product of slags immersed in sea water; a weathering product of sulphides in subsea black smoker deposits.

Type locality
Wheal Cock
  1. Botallack Mine
  2. Botallack
  3. St Just
  4. Cornwall
  5. England
  6. UK

50.1458°, -5.6915°

57recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Transparency
Transparent · Translucent
Colour
Mountain-green · bluish green to green · pale bluish green in transmitted light
Cleavage
Distinct/Good

In one direction perpendicular to Z axis

Density
3.6 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.775 – 1.846
Surface relief
Very high
Principal indices
nα 1.775 · nβ 1.8 · nγ 1.846
Pleochroism
Weak

in shades of bluish green

Dispersion
r > v, strong
Michel-Lévy diagramhighlighted lineδ = 0.0710
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]710 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation710 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 5.717 Å · b = 6.126 Å · c = 5.636 Å
Cell angles
β = 93.07 °
Ratio a:b:c
1 : 1.072 : 0.986
Z
2
Morphology

Elongate tabular indistinct crystals; also blocky-prismatic crystals.

Type-locality form

Crusts of minute platy interlaced crystals.

Comment

Krause (2006) gives a 5.7155(5), b 6.1255(6), c 5.6336(4) A, beta 93.090(8)°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
59.51%
8OOxygenOxygen315.99947.997
22.47%
17ClChlorineChlorine135.45035.450
16.60%
1HHydrogenHydrogen31.0083.024
1.42%
Total213.563100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Botallackiet

In other languages

French
Botallackite
German
Botallackit
Spanish
Botallackita
Italian
Botallackite
Japanese
ボタラック石
Chinese
斜氯銅礦
Russian
Боталлакит · Боталлактит

Classification

Strunz
10th ed.

3.DA.10b

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10bBotallackiteSpecies
Dana
8th ed.

10.01.03.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.01A2(O,OH)3XqType
  • 10.01.03— unnamed intermediate level —Group
  • 10.01.03.01BotallackiteSpecies
CIM

8.2.6

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.6BotallackiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1865Church, A. H. (1865) Notes on a Cornish mineral of the atacamite group. Journal of the Chemical Society, 18. 212-214 doi:10.1039/js8651800212DOI: 10.1039/js8651800212
  2. 1865Maskelyne, N. S. (1865) On new Cornish minerals of the brochantite group. Proceedings of the Royal Society of London, 14. 392-400 doi:10.1098/rspl.1865.0074DOI: 10.1098/rspl.1865.0074
  3. 1873Zepharovich (1873) Konigliche Akademie der Wissenschaften, Vienna, Sitzber.: 68: 130.
  4. 1950Frondel, Clifford (1950) On paratacamite and some related copper chlorides. Mineralogical Magazine and Journal of the Mineralogical Society, 29 (208) 34-45 doi:10.1180/minmag.1950.029.208.06 DOI: 10.1180/minmag.1950.029.208.06
  5. 1951Fleischer, M. (1951) New mineral names. American Mineralogist, 36 (3-4). 381-384
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Botallackite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/botallackite-732},
  note      = {Accessed 2026-05-11}
}