Atacamite

Cu2Cl(OH)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ata
Discovered
1801
Also known as
  • Alacamita
  • Alacamite
  • Arsenillo
  • +16 more

History

The name points straight to a place rather than a person. Atacamite takes it from the Atacama Desert of northern Chile, the hyperarid landscape where the first specimens were gathered.

Those specimens were collected in 1801. The following year the mineral was formally described and named by Dmitri Alekseyevich Golitsyn, a Russian diplomat and naturalist. He chose the desert that had yielded it — the type locality — as its namesake.

The bright green of atacamite found a use in art long before chemists pinned down its formula. It has been identified as a pigment on sculpture, manuscripts, maps, and frescoes across Asia, Russia, Persia, and Europe.

The mineral also turns up where no human put it. In 2002, researchers reported it as the first copper biomineral known in a living animal — the crystalline mineral that hardens the jaw tips of the marine bloodworm Glycera dibranchiata. The worm builds those jaws from roughly ten parts protein to one part mineral, yet they resist wear about as well as the toughest materials made by hand.

Industrial & practical applications

Atacamite is a copper mineral, so where it gathers in quantity it can be mined for the metal it holds. It is only ever a minor, secondary ore, though. It forms in the weathered upper layers of copper deposits rather than in the rich primary rock below, and it is far too scarce to rival the sulfide and oxide ores that supply most of the world's copper.

Beyond that limited role, the mineral has little modern industrial use. Its sharp green crystals are prized mainly by collectors and museums as well-formed examples of a copper chloride.

The mineral also draws scientific interest of its own. The copper biomineral that hardens the jaw tips of bloodworms — atacamite — is studied as a design prototype for tough, lightweight, durable materials.

Where it forms, where it's found

Geological setting

An oxidation product of other copper minerals under arid conditions

An oxidation product of other copper minerals, especially under arid, saline conditions; in fumarolic deposits; a weathering product of sulphides in submarine black smoker deposits; an alteration product of bronze and copper objects of antiquity.

Type locality
Atacama
  1. Chile
523recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine to Vitreous
Transparency
Transparent · Translucent
Colour
Bright green · dark emerald-green to blackish green · shades of green in transmitted light.
Streak
Apple-green.
Tenacity
brittle
Cleavage
Perfect

On (010), fair on (101).

Fracture
Conchoidal
Density
3.745 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 74°
Refractive index
1.831 – 1.88
Surface relief
Very high
Principal indices
nα 1.831 · nβ 1.861 · nγ 1.88
Pleochroism
Weak

X = pale green, Y = yellow-green, Z = grass-green; Orientation: X = b, Y = a, Z = c.

Dispersion
r < v, strong
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0490
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]490 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation490 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 6.03 Å · b = 9.12 Å · c = 6.865 Å
Ratio a:b:c
1 : 1.512 : 1.138
Z
4
Morphology

Slender crystals, to 10 cm, prismatic along [001]; striated parallel to [001], on (010) parallel to [1_10]; commonly tabular perpendicular to (010) or pseudo-octahedral with (110) and (011). Also fibrous, sandy granular to compact, massive.

Twinning

Rare, with twin and composition plane (110); more common about [544]. Doublets, triplets, both contact and penetration, and complex groups result from twinning.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
59.51%
8OOxygenOxygen315.99947.997
22.47%
17ClChlorineChlorine135.45035.450
16.60%
1HHydrogenHydrogen31.0083.024
1.42%
Total213.563100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • Co

Synonyms

  • Alacamita
  • Alacamite
  • Arsenillo
  • Atakamite
  • Chlorochalcit
  • Cuivre Muriaté
  • Hal-Chalzit
  • Halochalcit
  • Halochalcita
  • Halochalcite
  • Halochalzit
  • Kupferhornerz
  • Kupfersand
  • Marcylite
  • Muriate of copper
  • Remolinite
  • Salzkupfererz
  • Salzsaures Kupfer
  • Smaragdochalcit (of Hausmann)

In other languages

French
alacamite · atacamite · Cu2Cl(OH)3 · cuivre muriaté · halochalcite · marcylite · rémolinite
German
Atacamit · Atakamit
Spanish
atacamita · remolinita
Italian
Atacamite
Portuguese
atacamita · Atacamite
Japanese
アタカマ石
Chinese
氯銅礦
Russian
атакамит
Arabic
أتاكاميت

Classification

Strunz
10th ed.

3.DA.10a

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10aAtacamiteSpecies
Dana
8th ed.

10.01.01.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.01A2(O,OH)3XqType
  • 10.01.01Atacamite groupGroup
  • 10.01.01.01AtacamiteSpecies
CIM

8.2.4

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.4AtacamiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. Hannington, Mark D. (1993): The formation of atacamite during weathering of sulfides on the modern seafloor. Canadian Mineralogist 31 (4), 945-956.
  2. 1786Rochefoucauld, Baumé, and Fourcroy (1786)[published 1788] Mémoires de l'Académie des Sciences de l'Institut de France, Paris.
  3. 1788Berthollet (1788) Mémoires de l'Académie des Sciences de l'Institut de France, Paris.
  4. 1800Karsten, D.L.G. (1800) Mineralogische Tabellen, Berlin. First edition: 46, 76. [as Kupfersand and salzsaures Kupfer].
  5. 1801Haüy, René Just (1801) Traité de Minéralogie (1st ed.) Vol. 3. Chez Louis, Paris.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Atacamite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/atacamite-406},
  note      = {Accessed 2026-05-11}
}