Herbertsmithite

Cu3Zn(OH)6Cl2
IMA status
  • Approved
IMA symbol
Her
Discovered
1972
IMA approved
2003
Also known as
  • Anarakit
  • Anarakite
  • Herbertsmithiet
  • +1 more

Where it forms, where it's found

Geological setting

Copper mineralizations in syenitic porphyries and granites, hosted by triassic dolomites (Anarak, Iran)

Type locality
Los Tres Presidentes Mine
  1. Caracoles
  2. Caracoles mining district
  3. Sierra Gorda
  4. Antofagasta Province
  5. Antofagasta
  6. Chile
27recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
light green · blue-green · emerald green
Streak
light green
Tenacity
brittle
Cleavage
Distinct/Good

on (1011)

Density
3.85 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.815 – 1.849
Surface relief
Very high
Principal indices
nω 1.825 – 1.849 · nε 1.815 – 1.842
Pleochroism
Weak

O > E; green to greenish blue

UV response
none
Notes

Indices gradually increase with increasing Cu/Zn. Anomalous birefringence in greenish-blue to dark blue.

Michel-Lévy diagramhighlighted lineδ = 0.0085
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]85 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation85 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 6.834 Å · c = 14.075 Å
Unit cell volume
569.28 ų
Z
3
Morphology

Platy, pseudohexagonal crystals to 0.5 mm (Iran); rhombohedrons and pseudo-octahedra to 1.5 mm (Chile).

Type-locality form

Rhombohedrons to 1.5 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
44.44%
8OOxygenOxygen615.99995.994
22.38%
17ClChlorineChlorine235.45070.900
16.53%
30ZnZincZinc165.38065.380
15.24%
1HHydrogenHydrogen61.0086.048
1.41%
Total428.960100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Anarakit
  • Anarakite
  • Herbertsmithiet
  • IMA2003-041

In other languages

French
Herbertsmithite
German
Anarakit · Herbertsmithit · IMA 2003-041
Spanish
Herbertsmithita
Italian
Herbertsmithite
Japanese
ハーバートスミス石
Chinese
氯羟锌铜石 · 赫伯特史密斯石
Russian
Гербертсмитит
Arabic
هربرت سميثايت

Classification

Strunz
10th ed.

3.DA.10c

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10cHerbertsmithiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2004Weiß, S. (2004) Lapis: 29(12): 38-39.
  2. 2004Braithwaite, R. S. W., Mereiter, K., Paar, W. H., Clark, A. M. (2004) Herbertsmithite, Cu3Zn(OH)6Cl2, a new species, and the definition of paratacamite. Mineralogical Magazine, 68 (3) 527-539 doi:10.1180/0026461046830204 DOI: 10.1180/0026461046830204
  3. 2004Mandarino, Joseph A. (2004) New minerals. The Canadian Mineralogist, 42 (6) 1901-1927 doi:10.2113/gscanmin.42.6.1901 DOI: 10.2113/gscanmin.42.6.1901
  4. 2005Jambor, J.L., Grew, E.S., Roberts, A.C. (2005) New mineral names. American Mineralogist, 90, 518-522.
  5. 2007www.newscientist.com (2007) http://www.newscientist.com/article/mg19325954.200
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Herbertsmithite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/herbertsmithite-26600},
  note      = {Accessed 2026-05-11}
}