Hibbingite

Fe2+2(OH)3Cl
IMA status
  • Approved
IMA symbol
Hib
Discovered
1991
IMA approved
1991
Also known as
  • Hibbingiet
  • IMA1991-036

Where it forms, where it's found

Geological setting

Partially serpentized trocolitic rocks.

Weathering product of iron meteorites

Type locality
Hibbingite occurrences
  1. Lake County
  2. Minnesota
  3. USA

47.7181°, -91.7924°

27recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colorless to pale green · becoming more yellow on oxidation
Cleavage
Distinct/Good

One direction, good, perhaps a parting.

Density
3.04 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.6 – 1.7
Surface relief
High
Principal indices
nβ 1.6 – 1.7
Pleochroism
Weak
Dispersion
Relatively strong
Extinction
Approximately parallel, length-fast.
Bireflectance
Observable
Internal reflections
Green, becoming red with oxidation
Notes

n = 1.6-1.7

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 6.3373(2) Å · b = 6.9892(2) Å · c = 9.3457(3) Å
Ratio a:b:c
1 : 1.103 : 1.475
Z
4
Morphology

platy habit

Type-locality form

Grains

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
56.36%
8OOxygenOxygen315.99947.997
24.22%
17ClChlorineChlorine135.45035.450
17.89%
1HHydrogenHydrogen31.0083.024
1.53%
Total198.161100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Si
  • Mg

Synonyms

  • Hibbingiet
  • IMA1991-036

In other languages

German
Hibbingit · IMA 1991-036
Italian
Hibbingite

Classification

Strunz
10th ed.

3.DA.10a

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10aHibbingiteSpecies
Dana
8th ed.

10.01.01.02

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.01A2(O,OH)3XqType
  • 10.01.01Atacamite groupGroup
  • 10.01.01.02HibbingiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1994Saini-eidukat, Bernhardt, Kucha, Henryk, Keppler, Hans (1994) Hibbingite, γ-Fe2(OH)3Cl, a new mineral from the Duluth Complex, Minnesota, with implications for the oxidation of Fe-bearing compounds and the transport of metals. American Mineralogist, 79 (5-6) 555-561
  2. 1995Buchwald, V.F., and Koch, C.B. (1995) Hibbingite (β-Fe2(OH)3Cl), a chlorine-rich corrosion product in meteorites and ancient iron objects. Meteoritics, 30(5), 493-493.
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 1998Saini-Eidukat, Bernhardt, Rudashevsky, Nikolai S., Polozov, Alexander G. (1998) Evidence for hibbingite–kempite solid solution. Mineralogical Magazine, 62 (2) 251-255 doi:10.1180/002646198547602 DOI: 10.1180/002646198547602
  5. 2007(2007) Hibbingite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hibbingite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hibbingite-1896},
  note      = {Accessed 2026-05-11}
}