Kempite

Mn2+2Cl(OH)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kp
Discovered
1924
Also known as
  • Kempiet

Where it forms, where it's found

Geological setting

Erratic boulder

Type locality
Mn occurrence
  1. East Foothills
  2. Black Wonder Mining District
  3. Santa Clara County
  4. California
  5. USA

37.3978°, -121.7986°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Emerald-green · brownish-orange

green in transmitted light; semitransparent

Density
~2.94 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 54°
Refractive index
1.684 – 1.698
Surface relief
High
Principal indices
nα 1.684 · nβ 1.695 · nγ 1.698
Dispersion
r > v
Notes

2V: 54o52'

Michel-Lévy diagramhighlighted lineδ = 0.0140
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]140 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation140 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 6.49 Å · b = 9.52 Å · c = 7.12 Å
Ratio a:b:c
1 : 1.467 : 1.097
Z
4
Morphology

Crystals prismatic [001]; (110), (011), and (121) forms observed; (100) and (010) are usually absent or inconspicuous.

Type-locality form

fine, powdery, emerald-green to brownish-orange encrustations on manganese-stained rock, coating fracture faces and veins in altered serpentinized rock and chert breccia

Comment

Cu2Cl(OH)3 type

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese254.938109.876
55.96%
8OOxygenOxygen315.99947.997
24.45%
17ClChlorineChlorine135.45035.450
18.05%
1HHydrogenHydrogen31.0083.024
1.54%
Total196.347100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kempiet

In other languages

German
Kempit
Italian
Kempite

Classification

Strunz
10th ed.

3.DA.10a

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10aKempiteSpecies
Dana
8th ed.

10.01.04.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.01A2(O,OH)3XqType
  • 10.01.04— unnamed intermediate level —Group
  • 10.01.04.01KempiteSpecies
CIM

8.10.2

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.10Halides of MnGroup
  • 8.10.2KempiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Villars, P. Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland (ed.), Springer Materials.
  2. 1924Rogers, Austin Flint (1924): Kempite, a new manganese mineral from Santa Clara County, California. American Journal of Science, 5th. Series: 8: 145-150.
  3. 1949Rogers (1949) Bulletin of the Geological Society of America: 60, no. 12, part 2: 1944.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1998Saini-Eidukat, Bernhardt, Rudashevsky, Nikolai S., Polozov, Alexander G. (1998) Evidence for hibbingite–kempite solid solution. Mineralogical Magazine, 62 (2) 251-255 doi:10.1180/002646198547602 DOI: 10.1180/002646198547602
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kempite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kempite-2183},
  note      = {Accessed 2026-05-11}
}