Gillardite

Cu3NiCl2(OH)6
IMA status
  • Approved
IMA symbol
Gla
IMA approved
2007
Also known as
  • Gillardiet
  • IMA2006-041

Where it forms, where it's found

Geological setting

Silicified ferruginous gossan.

Type locality
132 North Ni Mine
  1. Widgiemooltha
  2. Coolgardie Shire
  3. Western Australia
  4. Australia

-31.4569°, 121.5382°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark green

Larger crystals are nearly black.

Streak
Green
Tenacity
brittle
Cleavage
Distinct/Good

On (101).

Fracture
Irregular/Uneven · Splintery
Density
3.76 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.836 – 1.838
Surface relief
Very high
Principal indices
nω 1.836 · nε 1.838
Pleochroism
Not Visible
Dispersion
None observed.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 6.8364 Å · c = 13.8459 Å
Morphology

Equant, rhombohedral crystals showing the forms (101), (021), (001) and (100) (probable).

Twinning

None observed.

Parting
None observed.
Type-locality form

Aggregates of equant, rhombohedral crystals up to 0.5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
45.15%
8OOxygenOxygen615.99995.994
22.73%
17ClChlorineChlorine235.45070.900
16.79%
28NiNickelNickel158.69358.693
13.90%
1HHydrogenHydrogen61.0086.048
1.43%
Total422.273100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gillardiet
  • IMA2006-041

In other languages

German
Gillardit · IMA 2006-041
Italian
gillardite

Classification

Strunz
10th ed.

3.DA.10c

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.10cGillarditeSpecies
Dana
8th ed.

10.01.02.04

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.01A2(O,OH)3XqType
  • 10.01.02Paratacamite GroupGroup
  • 10.01.02.04GillarditeSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2007Colchester, D.M., Leverett, P., Clissold, M.E., Williams, P.A., Hibbs, D.E., Nickel, E.H. (2007) Gillardite, Cu3NiCl2(OH)6, a new mineral from the 132 North deposit, Widgiemooltha, Western Australia. Australian Journal of Mineralogy: 13(1): 15-18. https://rruff.info/uploads/AJM13_15.pdf
  2. 2007Clissold, M. E., Leverett, P., Williams, P. A., Hibbs, D. E., Nickel, E. H. (2007) The structure of gillardite, the Ni-analog of herbertsmithite, from Widgiemooltha, Western Australia. The Canadian Mineralogist, 45 (2). 317-320 doi:10.2113/gscanmin.45.2.317 DOI: 10.2113/gscanmin.45.2.317
  3. 2013Li, Yue-sheng, Zhang, Qing-ming (2013) Structure and magnetism of S = 1/2 kagome antiferromagnets NiCu3(OH)6Cl2 and CoCu3(OH)6Cl2. Journal of Physics: Condensed Matter, 25 (2). 26003 doi:10.1088/0953-8984/25/2/026003DOI: 10.1088/0953-8984/25/2/026003
  4. 2017Sciberras, Matthew J., Leverett, Peter, Williams, Peter A., Schlüter, Jochen, Malcherek, Thomas, Welch, Mark D., Downes, Peter J., Hibbs, David E., Kampf, Anthony R. (2017) Structural and compositional variations of basic Cu(II) chlorides in the herbertsmithite and gillardite structure field. Mineralogical Magazine, 81 (1) 123-134 doi:10.1180/minmag.2016.080.079DOI: 10.1180/minmag.2016.080.079
  5. 2022(2022) Gillardite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gillardite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gillardite-31405},
  note      = {Accessed 2026-05-11}
}