Brochantite

Cu4(SO4)(OH)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bct
Discovered
1824
Also known as
  • Blanchardit
  • Blanchardite
  • Brogniartine (of Huot)
  • +12 more

History

The name brochantite honours a French geologist most readers will never have heard of. In 1824, the crystallographer Serve-Dieu Abailard "Armand" Lévy described this green copper sulfate. He named it after his fellow Frenchman André-Jean-François-Marie Brochant de Villiers (1772–1840), a mineralogist and geologist active in early nineteenth-century Paris.

The mineral itself has no ancient story. It slipped into the mineralogical record only when chemistry had developed enough to tell one green copper crust from another — there are several, and the unaided eye cannot reliably separate them. Brochantite's discovery belongs entirely to the modern era of systematic mineral description.

Industrial & practical applications

Brochantite has almost no industrial role of its own. Where it matters today is on the surface of old bronze.

A copper or bronze statue left outdoors slowly grows a green crust. That crust is rarely one substance. In urban air loaded with sulfur dioxide — the pollutant released by coal smoke and diesel exhaust — brochantite is often the dominant green layer. It shares the surface with related basic copper sulfates and chlorides. Conservators of outdoor monuments therefore identify brochantite routinely when they analyse a patina. The mineral has become, in that work, a diagnostic label for one specific kind of weathered copper surface.

Beyond the patina story, brochantite is a collector and reference mineral. Specimens with crisp emerald-green crystals are valued by amateur mineralogists, and the mineral appears in research literature on copper corrosion and on the secondary mineralogy of oxidised copper deposits.

Where it forms, where it's found

Geological setting

In arid climates or in rapidly oxidizing copper sulfide deposits under low acid conditions.

Type locality
Mednorudyanskoye Cu Deposit
  1. Nizhnii Tagil
  2. Sverdlovsk Oblast
  3. Russia
1,693recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Pearly
Transparency
Transparent · Translucent
Colour
Green · emerald green · green-black · light green · bluish green in transmitted light.
Streak
Pale green
Cleavage
Perfect

On (100) perfect.

Fracture
Irregular/Uneven · Conchoidal
Density
3.97 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 72° · 2V calc = 76°
Refractive index
1.728 – 1.8
Surface relief
High
Principal indices
nα 1.728 · nβ 1.771 · nγ 1.8
Pleochroism
Weak

Slight in shades of bluish green.

Dispersion
medium r < v
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0720
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]720 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation720 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 13.08 Å · b = 9.85 Å · c = 6.02 Å
Cell angles
β = 103.35 °
Ratio a:b:c
1 : 0.753 : 0.460
Z
4
Morphology

Crystals stout prismatic to acicular [001], elongated [010] at times, or, [100] more rarely; also tabular (001). Loosely coherent aggregates of acicular crystals; groups and drusy crusts; massive, granular.

Twinning

On (100) with composition surface (100), common. The twinned crystals are often symmetrical and pseudo-orthorhombic in appearance. When X-rayed using single-crystal methods, twins may yield an orthorhombic unit cell solution with cell metrics of a = ~3.0, b = ~9.8, c = ~12.7 Å.

Comment

OD structure. The MDO1 polytype (P21/a; cell given above) corresponds to "normal" brochantite. The MDO2 polytype has space group P21/n and a = 12.776, b = 9.869, c = 6.026 A, beta = 90.15 (Merlino et al., 2003).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
56.20%
8OOxygenOxygen1015.999159.990
35.37%
16SSulfurSulfur132.06032.060
7.09%
1HHydrogenHydrogen61.0086.048
1.34%
Total452.282100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Blanchardit
  • Blanchardite
  • Brogniartine (of Huot)
  • IMA1980-s.p.
  • Kamarezit
  • Kamarezite
  • Koenigine
  • Königine
  • Konigit
  • Konigite
  • Krisuvigit
  • Krisuvigite
  • Waringtonit
  • Waringtonite
  • Warringtonite

In other languages

French
Brochantite
German
Brochantit
Spanish
Brocancita · Brochantita
Italian
Brochantite
Japanese
ブロシャン銅鉱
Chinese
水膽礬
Russian
Брошантит

Classification

Strunz
10th ed.

7.BB.25

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BBWith medium-sized cationsGroup
  • 7.BB.25BrochantiteSpecies
Dana
8th ed.

30.01.03.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.01(AB)m(XO4)pZq, where m:p>2:1Type
  • 30.01.03— unnamed intermediate level —Group
  • 30.01.03.01BrochantiteSpecies
CIM

25.2.7

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.7BrochantiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Die metallenen Grabplatten im Kreuzgang des Erfurter Doms: Bestandsaufnahme und Erarbeitung eines präventiven Konservierungskonzeptes (https://www.uni-bamberg.de/restwiss/forschung/interdisziplinaere-forschung/dom-erfurt-grabplatten/)
  2. 1824Lévy, A. (1824) On a new mineral substance. Annals of Philosophy, London: 8: 241.
  3. 1826Lévy, A. (1826) Annals of Philosophy, London: 11: 194 (as Königine).
  4. 1841Huot, J.J. (1841) Manuel de Minéralogie. 2 volumes, Paris: 1: 331 (as Brongniartine).
  5. 1842Forchhammer (1842) Skand. Nat. Stockholm, Arsb. 192, 1843 (as Krisuvigite).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Brochantite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/brochantite-779},
  note      = {Accessed 2026-05-11}
}