Cordierite

Mg2Al4Si5O18
IMA status
  • Approved
  • Grandfathered
IMA symbol
Crd
Discovered
1813
Also known as
  • Dichroit
  • Dichroita
  • Dichroite
  • +20 more

Where it forms, where it's found

Geological setting

Thermally metamorphosed argillaceous sedimentary rocks; high-grade regionally metamorphosed schists, gneisses, and granulites; also in mafic igneous rocks and granites.

Type locality
Großer Arber
  1. Bayerisch Eisenstein
  2. Regen District
  3. Lower Bavaria
  4. Bavaria
  5. Germany

49.1125°, 13.1353°

1,016recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789107 – 7.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous to glassy
Transparency
Transparent · Translucent
Colour
Grey · blue · blue-violet · greenish · yellowish brown · colourless to very light blue in transmitted light.

Charles and others have explained the coloration mechanism of cordierite, stating that its blue color originates from the charge transfer between Fe2+ in the octahedral sites and Fe3+ in the T11 tetrahedral sites. Dudka et al. conducted precise X-ray diffraction analysis on cordierite, identifying the locations of metal cations Na+, H2O, and CO2 within the channels of cordierite. Pollak explained the sites of charge transfer in cordierite by examining the differences between infrared absorption bands along different crystallographic axes, providing a deeper explanation for its polychroism. However, specific studies on the spectral differences between different crystal axes are lacking. Duncan et al. measured the Mössbauer spectra of cordierite single crystals in different directions, determining the positions and occupancy rates of Fe2+ and Fe3+ ions, suggesting that the exchange interaction between Fe3+ ions on the T1 sites and the six-fold sites is the source of cordierite’s polychroism. Raphaël et al. evaluated the spectroscopic properties of cordierite through TD-DFT, assessing the simulation of polychroism and the variation of color with different light sources. However, studies on the spectral differences along different crystallographic axes of cordierite and the content ratio of Fe2+ to Fe3+ are still lacking. The sample’s refractive index and relative density are lower compared to iron cordierite, with an XMg range between 0.79 and 0.96. The Raman spectral characteristics are closer to those of pure Mg-cordierite, indicating that the samples are Mg-cordierite. The cordierite samples contain both Fe2+ and Fe3+ valence states, with an average ratio of 25.55% to 74.45%. The ultraviolet spectral characteristics of cordierite indicate that the difference in the broad absorption band at 584 nm is the key to cordierite’s strong pleochroism (deep purple/light purple/light yellow), caused by charge transfer between Fe2+ in the octahedron and Fe3+ in the tetrahedron. Infrared and Raman spectroscopy results reveal that differences in the Si-O group density in different directions cause variations in the spectral characteristics among the three optical principal axis directions of cordierite, with the greatest difference along the parallel b-axis, while the spectral characteristics of the other two directions are similar. Both infrared and Raman spectroscopy also prove the presence of a certain amount of Type I H2O and a small amount of Type II H2O in Mg-cordierite, with the band intensity of Type II H2O being directly proportional to the sample’s Na content.[[1]]

Tenacity
brittle
Cleavage
Imperfect/Fair

On (100), fair; On (001) and (010), poor.

Fracture
Sub-Conchoidal
Density
2.6 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75 – 89° · 2V calc = 54 – 86°
Refractive index
1.527 – 1.578
Surface relief
Moderate
Principal indices
nα 1.527 – 1.56 · nβ 1.532 – 1.574 · nγ 1.538 – 1.578
Pleochroism
Strong

X = Pale yellow, green; Y = Violet, blue-violet; Z = Light blue.

Dispersion
r < v, weak to marked
Extinction
X = c; Y = a; Z = b.
Notes

Absorption: Z > Y > X.

Michel-Lévy diagramhighlighted lineδ = 0.0145
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]145 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation145 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Cccm
Cell parameters
a = 17.079(3) Å · b = 9.730(2) Å · c = 9.356(2) Å
Ratio a:b:c
1 : 0.570 : 0.548
Z
4
Morphology

Crystals short prismatic, striated parallel to [001]. Commonly granular to compact, massive.

Twinning

Common on (110) and (130), simple, lamellar, and cyclical.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
49.23%
14SiSiliconSilicon528.085140.425
24.01%
13AlAluminiumAluminium426.982107.928
18.45%
12MgMagnesiumMagnesium224.30548.610
8.31%
Total584.945100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Fe
  • Ti
  • Ca
  • Na
  • K

Synonyms

  • Dichroit
  • Dichroita
  • Dichroite
  • Esmarkite (of Berzelius)
  • Hard Fahlunite
  • Iolit
  • Iolita
  • Iolith
  • Jolit
  • Jolita
  • Jolite
  • Lazulith (of van Schlotheim)
  • Lazulith (of von Schlotheim)
  • Luchsapphir
  • Luchssaphir
  • Peliom
  • Spanish Lazulite
  • Steinheilit
  • Steinheilita
  • Steinheilite
  • Tanolite
  • Wassersaphir
  • Water Sapphire

In other languages

French
Cordiérite · Dichroïte · Indialite · Iolite · Quartz bleu de la Nouvelle-Finlande · Saphir d'eau · Steinheilite · Yolithe
German
Cordierit · Dichroit · Iolith
Spanish
cordierita
Italian
cordierite · diocrite · iolite · zaffiro d'acqua · zaffiro di lince
Portuguese
cordierita · cordierite
Japanese
きん青石 · コーディエライト · 菫青石
Chinese
堇青石
Simplified Chinese
堇青石
Traditional Chinese
堇青石
Russian
Дихроит · Иолит · Кордиерит · Штейнгейлит
Arabic
كورديريت

Classification

Strunz
10th ed.

9.CJ.10

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CJ[Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anionsGroup
  • 9.CJ.10CordieriteSpecies
Dana
8th ed.

61.02.01.01

  • 61Cyclosilicates Six-membered RingsClass
  • 61.02Six-Membered Rings with Al substituted ringsType
  • 61.02.01Cordierite groupGroup
  • 61.02.01.01CordieriteSpecies
CIM

16.19.2

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.19Aluminosilicates of Fe and MgGroup
  • 16.19.2CordieriteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1933Rutherford, Ralph L. (1933) Optically positive cordierite from the Northwest Territories, Canada. American Mineralogist, 18 (5) 216
  2. 1935Conant, L. C. (1935) Optically positive cordierite from New Hampshire. American Mineralogist, 20 (4) 310
  3. 1936Rutherford, Ralph L. (1936) Optically positive cordierite in the Kisseyenew gneiss at Sherridon, Manitoba. American Mineralogist, 21 (6) 386-387
  4. 1941Folinsbee, Robert E. (1941) Optic properties of cordierite in relation to alkalies in the cordierite-beryl structure. American Mineralogist, 26 (8) 485-500
  5. 1943Shand, S. J. (1943) Notes on cordierite: (A) Cordierite crystals from a glass furnace; (B) Cordierite from Horns Nek, Transvaal. American Mineralogist, 28 (6) 391-395
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cordierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cordierite-1128},
  note      = {Accessed 2026-05-11}
}