Lithiophosphate

Li3(PO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lip
Discovered
1957
Also known as
  • Lithiophosphatit

Where it forms, where it's found

Geological setting

Granite pegmatite

Granite pegmatite

Type locality
Okhmyl'k Mt
  1. Voron'i Tundry
  2. Murmansk Oblast
  3. Russia

68.4394°, 35.6056°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
White · light pink · colourless
Streak
White
Tenacity
brittle
Cleavage
Perfect
Density
2.46 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 69 – 80° · 2V calc = 74 – 84°
Refractive index
1.55 – 1.567
Surface relief
Moderate
Principal indices
nα 1.550 – 1.553 · nβ 1.557 – 1.558 · nγ 1.566 – 1.567
Birefringence
0.015
Pleochroism
Non-pleochroic
Dispersion
r > v weak
Extinction
XYZ = cab
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pmn21
Cell parameters
a = 6.115 Å · b = 5.234 Å · c = 4.845 Å
Ratio a:b:c
1 : 0.856 : 0.792
Z
2
Morphology

Elongated crystals with striations || to elongation, also massive granular

Type-locality form

White to pale pink grains in aggregates to 9 x 5 x 4 cm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
55.27%
15PPhosphorusPhosphorus130.97430.974
26.75%
3LiLithiumLithium36.94020.820
17.98%
Total115.790100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Lithiophosphatit

In other languages

German
Lithiophosphat
Italian
Lithiophosphate · Litiofosfato
Japanese
リチオフォスフェイト

Classification

Strunz
10th ed.

8.AA.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.AAWith small cations (some also with larger ones)Group
  • 8.AA.20LithiophosphateSpecies
Dana
8th ed.

38.04.10.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.04AXO4Type
  • 38.04.10Lithiophosphate GroupGroup
  • 38.04.10.01LithiophosphateSpecies
CIM

19.1.1

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.1LithiophosphateSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Matias, V.V.; Bondareva, A.M. (1957) Lithiophosphate - a new mineral. Doklady Akademii Nauk SSSR 112 (1), 124-126.
  2. Bondareva, O.S.; Simonov, M.A.; Belov, N.V. (1978) The crystal structure of the synthetic analogue of the lithiophospate γ-Li3PO4. Doklady Akademii Nauk SSSR 240, 75-77.
  3. Swanson H E, Morris M C, Evans E H (1965) Lithium Phosphate, low form (lithiophosphate), Li3PO4 (orthorhombic) revised. Standard X-ray diffraction powder patterns. U.S. National Bureau of Standards Monograph 25, Sec 4, 21-22
  4. Yakubovich, O.V.; Urosova, V.S. (1997) Electron density distribution in lithiophosphatite Li3PO4: Crystallochemical features of orthophosphates with hexagonal close packing. Crystallography Reports 42, 261-268.
  5. 1932Zambonini, F.; Laves, F. (1932) Über die Kristallstruktur des Li3PO4 und seine Beziehung zum Strukturtyp des Olivin. Zeitschrift für Kristallographie, 83 (1-6). 26-28 doi:10.1524/zkri.1932.83.1.26DOI: 10.1524/zkri.1932.83.1.26
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lithiophosphate — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lithiophosphate-2420},
  note      = {Accessed 2026-05-11}
}