Where it forms, where it's found
- Geological setting
Granite pegmatite
Granite pegmatite
- Type locality
- Okhmyl'k Mt
- Voron'i Tundry
- Murmansk Oblast
- Russia
68.4394°, 35.6056°
7recorded occurrences
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 69 – 80° · 2V calc = 74 – 84°
- Refractive index
- 1.55 – 1.567
- Surface relief
- Moderate
- Principal indices
- nα 1.550 – 1.553 · nβ 1.557 – 1.558 · nγ 1.566 – 1.567
- Birefringence
- 0.015
- Pleochroism
- Non-pleochroic
- Dispersion
- r > v weak
- Extinction
- XYZ = cab
- UV response
- Not fluorescent in UV
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour
Crystallography
- Space group
- Pmn21
- Cell parameters
- a = 6.115 Å · b = 5.234 Å · c = 4.845 Å
- Ratio a:b:c
- 1 : 0.856 : 0.792
- Z
- 2
- Morphology
Elongated crystals with striations || to elongation, also massive granular
- Type-locality form
White to pale pink grains in aggregates to 9 x 5 x 4 cm
Crystal structure
Chemical composition
Synonyms
- Lithiophosphatit
In other languages
- German
- Lithiophosphat
- Italian
- Lithiophosphate · Litiofosfato
- Japanese
- リチオフォスフェイト
Classification
Strunz
10th ed.8.AA.20
- 8Phosphates, Arsenates, VanadatesClass
- 8.APhosphates, etc. without additional anions, without H2ODivision
- 8.AAWith small cations (some also with larger ones)Group
- 8.AA.20LithiophosphateSpecies
Dana
8th ed.38.04.10.01
- 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
- 38.04AXO4Type
- 38.04.10Lithiophosphate GroupGroup
- 38.04.10.01LithiophosphateSpecies
CIM
—19.1.1
- 19PhosphatesClass
- 19.1Phosphates of the alkali metalsGroup
- 19.1.1LithiophosphateSpecies
Group, growth & confusion
AlbiteNa(AlSi3O8)Mineral—
BerylBe3Al2Si6O18Mineral—
CassiteriteSnO2Mineral—
ElbaiteNa(Al1.5Li1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Mineral—
FluorapatiteCa5(PO4)3FMineral—
HureauliteMn2+5(PO3OH)2(PO4)2 · 4H2OMineral—
MontebrasiteLiAl(PO4)(OH)Mineral—
PolluciteCs(Si2Al)O6 · nH2OMineral—
QuartzSiO2Mineral—
Rockbridgeite(Fe2+0.5Fe3+0.5)2Fe3+3(PO4)3(OH)5Mineral—
Literature, links & citation
Citations
- —Matias, V.V.; Bondareva, A.M. (1957) Lithiophosphate - a new mineral. Doklady Akademii Nauk SSSR 112 (1), 124-126.
- —Bondareva, O.S.; Simonov, M.A.; Belov, N.V. (1978) The crystal structure of the synthetic analogue of the lithiophospate γ-Li3PO4. Doklady Akademii Nauk SSSR 240, 75-77.
- —Swanson H E, Morris M C, Evans E H (1965) Lithium Phosphate, low form (lithiophosphate), Li3PO4 (orthorhombic) revised. Standard X-ray diffraction powder patterns. U.S. National Bureau of Standards Monograph 25, Sec 4, 21-22
- —Yakubovich, O.V.; Urosova, V.S. (1997) Electron density distribution in lithiophosphatite Li3PO4: Crystallochemical features of orthophosphates with hexagonal close packing. Crystallography Reports 42, 261-268.
- 1932Zambonini, F.; Laves, F. (1932) Über die Kristallstruktur des Li3PO4 und seine Beziehung zum Strukturtyp des Olivin. Zeitschrift für Kristallographie, 83 (1-6). 26-28 doi:10.1524/zkri.1932.83.1.26DOI: 10.1524/zkri.1932.83.1.26
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Lithiophosphate — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/lithiophosphate-2420},
note = {Accessed 2026-05-11}
}